1. Gapless Spin Liquid Ground State in the S = 1/2 Vanadium Oxyfluoride Kagome Antiferromagnet [NH4]2[C7H14N][V7O6F18].
- Author
-
Clark, L., Orain, J. C., Bert, F., De Vries, M. A., Aidoudi, F. H., Morris, R. E., Lightfoot, P., Lord, J. S., Telling, M. T. F., Bonville, P., Attfield, J. P., Mendels, P., and Harrison, A.
- Subjects
- *
NARROW gap semiconductors , *VANADIUM oxide , *MUON spin rotation , *EXCHANGE interactions (Magnetism) , *ANTIFERROMAGNETIC materials , *OXYFLUORIDES , *HEAT capacity - Abstract
The vanadium oxyfluoride [NH4]2[C7H14N][V7O6F18] (DQVOF) is a geometrically frustrated magnetic bilayer material. The structure consists of S = 1/2 kagome planes of V4+ d¹ ions with S = 1 V3+ d² ions located between the kagome layers. Muon spin relaxation measurements demonstrate the absence of spin freezing down to 40 mK despite an energy scale of 60 K for antiferromagnetic exchange interactions. From magnetization and heat capacity measurements we conclude that the S = 1 spins of the interplane V3+ ions are weakly coupled to the kagome layers, such that DQVOF can be viewed as an experimental model for S = 1/2 kagome physics, and that it displays a gapless spin liquid ground state. [ABSTRACT FROM AUTHOR]
- Published
- 2013
- Full Text
- View/download PDF