1. Enhanced thermoelectricity by controlled local structure in bismuth-chalcogenides.
- Author
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Terashima, K., Yano, Y., Paris, E., Goto, Y., Mizuguchi, Y., Kamihara, Y., Wakita, T., Muraoka, Y., Saini, N. L., and Yokoya, T.
- Subjects
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THERMOELECTRICITY , *BISMUTH compounds , *CHALCOGENIDES , *SPECTRUM analysis , *PHOTOELECTRON spectroscopy , *X-ray absorption , *ELECTRONIC structure , *CRYSTAL structure - Abstract
Spectroscopic techniques, including photoelectron spectroscopy, diffuse reflectance, and x-ray absorption, are used to investigate the electronic structure and the local structure of LaOBiS 2 − x Se x thermoelectric material. It is found that Se substitution effectively suppresses local distortion that can be responsible for the increased carrier mobility together with a change in the electronic structure. The results suggest a possible way to control thermoelectric properties by tuning of the local crystal structure of these materials. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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