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Photoelectric properties of the F8BT polymer are investigated by the Constant photocurrent method (CPM) based on the photocurrent spectra Δjph(hν) and absorption spectra αCPM(hν). The negligibly weak dependence of charge carriers lifetime on the photon energy is found for hν = 2.2–2.7 eV. The peculiarities of the absorption spectra and the photoconductivity spectra are revealed to be determined mainly by the Gaussian distribution of the density of states (DOS). The density of trap states in the F8BT polymer thin films in the exponential DOS is estimated to be 103 times higher than in the Gaussian DOS. [ABSTRACT FROM AUTHOR]

Tunable interactions between colloidal particles, governed by external rotating electric or magnetic fields, yield rich capabilities for prospective self-assembly technologies of materials and fundamental particle-resolved studies of phase transitions and transport phenomena in soft matter. However, the role of the internal structure of colloidal particles in the tunable interactions has never been systematically investigated. Here, we study the tunable interactions between composite particles with core–shell structure in a rotating electric field and show that the engineering of their internal structure provides an effective tool for designing the interactions. We generalized an integral theory and studied the tunable interactions between core–shell particles with homogeneous cores (layered particles) and cores with nano-inclusions to reveal the main trends in the interactions influenced by the structure. We found that depending on the materials of the core, shell, and solvent, the interactions with the attractive pairwise part and positive or negative three-body part can be obtained, as well as pairwise repulsion with attractive three-body interactions (for triangular triplets). The latter case is observed for the first time, being unattainable for homogeneous particles but feasible with core–shell particles: Qualitatively similar interactions are inherent to charged colloids (repulsive pairwise and attractive three-body energies), known as a model system of globular proteins. The methods and conclusions of our paper can be generalized for magnetic and 3D colloidal systems. The results make a significant advance in the analysis of tunable interactions in colloidal systems, which are of broad interest in condensed matter, chemical physics, physical chemistry, materials science, and soft matter. [ABSTRACT FROM AUTHOR]