1. Switching of Radiation Force on Optically Trapped Microparticles through Photochromic Reactions of Pyranoquinazoline Derivatives
- Author
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Hiroshi Miyasaka, Yuki Inagaki, Kenji Setoura, Katsuya Mutoh, Ahsan Memon, Jiro Abe, and Syoji Ito
- Subjects
chemistry.chemical_classification ,Mesoscopic physics ,02 engineering and technology ,Polymer ,021001 nanoscience & nanotechnology ,Photochemistry ,01 natural sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Photochromism ,General Energy ,chemistry ,Optical tweezers ,0103 physical sciences ,Molecule ,Irradiation ,Physical and Theoretical Chemistry ,Microparticle ,010306 general physics ,0210 nano-technology ,Visible spectrum - Abstract
Photocontrol of mechanical motions of small objects has attracted much attention to develop mesoscopic remote actuators. For this purpose, photoinduced morphological changes of molecules, molecular aggregates, and crystals have been extensively studied in the field of chemistry and materials science. Here, we propose direct use of momenta of light (i.e. radiation force) to control the motion of small objects, through photochromic reactions of pyranoquinazoline (PQ) derivatives. PQ is colorless in visible wavelength region while it is in closed form and undergoes photochemical ring-opening reactions to form colored isomers upon UV light irradiation; the open-ring isomers return to the colorless closed isomers mainly through the thermal back reaction. In the experiment, individual polymer microparticles with diameters of 7 μm incorporating PQ were trapped by optical tweezers. When the trapped microparticle was irradiated with UV light, the microparticle was pushed along the axis of light propagation about a...
- Published
- 2018