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Endothelin receptor A (ET

The formation of ordered magnetic domains in thin films is important for the magnetic microdevices in spin-electronics, magneto-optics, and magnetic microelectromechanical systems. Although inducing anisotropic stress in magnetostrictive materials can achieve the domain assembly, controlling magnetic anisotropy over microscale areas is challenging. In this work, we realized the microscopic patterning of magnetic domains by engineering stress distribution. Deposition of ferromagnetic thin films on nanotrenched polymeric layers induced tensile stress at the interfaces, giving rise to the directional magnetoelastic coupling to form ordered domains spontaneously. By changing the periodicity and shape of nanotrenches, we spatially tuned the geometric configuration of domains by design. Theoretical analysis and micromagnetic characterization confirmed that the local stress distribution by the topographic confinement dominates the forming mechanism of the directed magnetization.

Radio frequency (RF) magnetron-sputtered TiO2 (RS-TiO2) is investigated as a hole-blocking layer for perovskite solar cells. RS-TiO2 shows conformal, dense, and efficiently electron transferable pr...

This Perspective focuses on the design of hierarchical structures in deformable thin materials by patterning mechanical instabilities. Fabrication of three-dimensional (3D) structures with multiple length scales-starting at the nanoscale-can result in on-demand surface functionalities from the modification of the mechanical, chemical, and optical properties of materials. Conventional top-down lithography, however, cannot achieve 3D patterns over large areas (cm

This paper investigates the correlation between the random lasing properties of organic waveguides made by poly-(9-9dioctylfluorene) (PFO) thin films and the morphology of wrinkled corrugated substrates. The capability to individually control the wrinkle wavelength, shape, and height allows us to separately investigate their role on the sample emission properties. We demonstrate that the main parameter determining the presence of coherent random lasing is the substrate roughness and that, contrary to what could be qualitatively expected, as the roughness increases, coherent random lasing is progressively reduced. Coherent random lasing is observed only for a substrate roughness below 33 nm, while higher roughness leads to amplified spontaneous emission (up to 70 nm) or to the absence of light amplification in the film (above 70 nm). We demonstrate that this result is due to a progressive reduction of the light amplification efficiency in the PFO film, evidencing that coherent random lasing can be obtained only with a right interplay between light amplification and scattering. Besides clarifying the basic aspects of random lasing in organic waveguides, our work opens the way to the realization of organic random lasers with predictable emission properties, thanks to the high control level of the scattering properties of the wrinkled corrugated surfaces.

One of the most interesting topics in physical science and materials science is the creation of complex wrinkled structures on thin-film surfaces because of their several advantages of high surface area, localized strain, and stress tolerance. In this study, a significant step was taken toward solving limitations imposed by the fabrication of previous artificial wrinkles. A universal method for preparing hierarchical three-dimensional wrinkle structures of thin films on a multiple scale (e.g., nanometers to micrometers) by sequential wrinkling with different skin layers was developed. Notably, this method was not limited to specific materials, and it was applicable to fabricating hierarchical wrinkles on all of the thin-film surfaces tested thus far, including those of metals, two-dimensional and one-dimensional materials, and polymers. The hierarchical wrinkles with multiscale structures were prepared by sequential wrinkling, in which a sacrificial layer was used as the additional skin layer between sequences. For example, a hierarchical MoS2 wrinkle exhibited highly enhanced catalytic behavior because of the superaerophobicity and effective surface area, which are related to topological effects. As the developed method can be adopted to a majority of thin films, it is thought to be a universal method for enhancing the physical properties of various materials.

We characterize wrinkling on the surfaces of prestrained polystyrene sheets coated with thin polytetrafluoroethylene skins using a combination of mechanical strain measurements and 3D finite element simulations. The simulations show that wrinkle wavelength increases with skin thickness, in agreement with a well-known continuum model and recent experiments. The wrinkle amplitudes also increase with strain. Nanoinclusions, such as holes and patterned lines, influence wrinkle patterns over limited distances, and these distances are shown to scale with the wrinkle wavelengths. Good agreement between experimental and simulated influence distances is observed. The inclusions provide strain relief, and they behave as if they are attracting adjacent material when the sheets are under strain. The wrinkles have stiffnesses in much the same way as do polymers (but at different length scales), a property that is quantified for polymers using persistence lengths. We show that the concept of persistence length can be useful in characterizing the wrinkle properties that we have observed. However, the calculated persistence lengths do not vary systematically with thickness and strain, as interactions between neighboring wrinkles produce confinement that is analogous to the kinetic confinement of polymers.

This paper describes how delamination-free, hierarchical patterning of graphene can be achieved on prestrained thermoplastic sheets by surface wrinkling. Conformal contact between graphene and the substrate during strain relief was maintained by the presence of a soft skin layer, resulting in the uniform patterning of three-dimensional wrinkles over large areas (>cm2). The graphene wrinkle wavelength was tuned from the microscale to the nanoscale by controlling the thickness of the skin layer with 1 nm accuracy to realize a degree of control not possible by crumpling, which relies on delamination. Hierarchical patterning of the skin layers with varying thicknesses enabled multiscale graphene wrinkles with predetermined orientations to be formed. Significantly, hierarchical graphene wrinkles exhibited tunable mechanical stiffness at the nanoscale without compromising the macroscale electrical conductivity.

Nanoscale wrinkling on the surfaces of polymer-based materials can be precisely controlled by depositing thin metal films of varying thicknesses. The deposition of these films fundamentally alters the mechanical properties of the substrates in ways that are not simply described using traditional continuum mechanical frameworks. In particular, we find, by modeling within a finite element analysis approach, that the very act of depositing a metal film may alter the Young's modulus of the polymer substrate to depths of up to a few hundred nanometers, creating a modified interfacial skin layer. We find that simulated wrinkle patterns reproduce the experimentally observed features only when the modulus of this surface layer varies by more than ∼500 nm and is described using a sigmoidal gradient multiplier.

This paper describes how a memory-based, sequential wrinkling process can transform flat polystyrene sheets into multiscale, three-dimensional hierarchical textures. Multiple cycles of plasma-mediated skin growth followed by directional strain relief of the substrate resulted in hierarchical architectures with characteristic generational (G) features. Independent control over wrinkle wavelength and wrinkle orientation for each G was achieved by tuning plasma treatment time and strain-relief direction for each cycle. Lotus-type superhydrophobicity was demonstrated on three-dimensional G1-G2-G3 hierarchical wrinkles as well as tunable superhydrophilicity on these same substrates after oxygen plasma. This materials system provides a general approach for nanomanufacturing based on bottom-up sequential wrinkling that will benefit a diverse range of applications and especially those that require large area (cm(2)), multiscale, three-dimensional patterns.

Thermodynamic analysis of inclusion complexation between α-cyclodextrin-based molecular tube (MT) and poly(ethylene oxide)-block-poly(tetrahydrofuran)-block-poly(ethylene oxide) triblock copolymer (PEO-b-PTHF-b-PEO) was carried out in terms of isothermal titration calorimetry. As for the titration of MT to PEO in aqueous solution, no strong exothermic peak was observed. On the contrary, strong exothermic peaks were observed for the titration of MT to PEO-b-PTHF-b-PEO in aqueous solution, which is attributable to inclusion complexation between MT and the triblock copolymer. Thermodynamic parameters were obtained for the process of inclusion complexation between MT and PEO-b-PTHF-b-PEO by changing the molecular weight of MT and the temperature. The stoichiometry of inclusion complexation changes in relation to the molecular weight of MT. Interestingly, it was found that MT with a large molecular weight behaves as the host molecule having multibinding sites. Thermodynamic parameters suggested that van der Wa...

Supramolecular-structured hydrogels were prepared on basis of the inclusion complexation between poly(ethylene glycol) grafted dextrans and α-cyclodextrins (α-CDs) in aqueous media. The inclusion complexes from the PEG grafted dextrans showed a unique gel−sol phase transition which cannot be obtained from usual polymer inclusion complexes that form crystalline precipitates. The gel−sol transition was based on the supramolecular assembly and dissociation, and the transition was reversible with hysteresis. The transition temperature was controllable by variation in the polymer concentration and the PEG content in the graft copolymers as well as the stoichiometric ratio between the guest and host molecules. The properties of the hydrogel were characterized by DSC, X-ray diffraction, and 13C CP/MAS NMR. The X-ray diffraction data indicated that the gel contains a channel-type crystalline structure, demonstrated by a strong reflection at 2θ = 20° (d = 4.44 A). It was confirmed from the DSC and 13C CP/MAS NMR m...