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Your search keyword '"Shi-Hong Lin"' showing total 2 results
Start Over Author "Shi-Hong Lin" Publisher american chemical society (acs)
2 results on '"Shi-Hong Lin"'

1. In Situ Formed Guanidinium Cations as Templates To Direct Fabrication of Honeycomb-like CuCN Networks

Author

Xiao-Ping Zhou, Shi-Hong Lin, Dan Li, and Seik Weng Ng

Subjects
Inorganic chemistry, Solvothermal synthesis, Guanidinium Cation, General Chemistry, Crystal structure, Condensed Matter Physics, Hexane, Template reaction, chemistry.chemical_compound, Template, chemistry, Polymer chemistry, General Materials Science, Methanol, Acetonitrile
Abstract

The solvothermal reaction of CuSCN and 1,2-bis(diphenylphosphino)ethane (dppe) in mixed solvents acetonitrile/n-hexane/(methanol or ethanol) gave a honeycomb-like guanidinium cyanocuprate [C(NH2)3)]·[Cu2(CN)3]. The in situ formed cations C(NH2)3+ act as templates to direct the formation of the CuCN network in which multiple weak N−H····N/C hydrogen interactions potentially exist between the cations C(NH2)3+ and the {CuCN}6 rings.

Published
2008

2. Anion−π-Interaction-Directed Self-Assembly of Ag(I) Coordination Networks

Author

Xiao-Ping Zhou, Shi-Hong Lin, Xuanjun Zhang, and Dan Li

Subjects
chemistry.chemical_classification, Ligand, Stereochemistry, Dimer, General Chemistry, Crystal structure, Polymer, Condensed Matter Physics, chemistry.chemical_compound, Crystallography, chemistry, Molecule, General Materials Science, Self-assembly, Isostructural, Group 2 organometallic chemistry
Abstract

Reactions of AgX with 2,4,6-tri(2-pyridyl)-1,3,5-trazine (tpt) yielded three 3D highly symmetric isostructural coordination polymers (X = ClO4-, BF4-, and PF6-) and a dimer (X = CF3COO-), respectively. In the coordination polymers, anion−π interactions are found between the multiatomic anions and tpt ligands. Systematic variation including synthetic methods, ratios of reactants, and solvents provides synthetic evidence proving that anion−π interactions play a decisive role in assembly of the coordination polymers.

Published
2007

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