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Start Over Author "S. V. Kirpichenko" Publisher american chemical society (acs)
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1. Sila-Pummerer Rearrangement of Cyclic Sulfoxides: Computational Study of the Mechanism

Author

S. V. Kirpichenko, Bagrat A. Shainyan, and Fillmore Freeman

Subjects
chemistry.chemical_classification, Chemistry, Stereochemistry, Pummerer rearrangement, General Chemistry, Biochemistry, Catalysis, Carroll rearrangement, Transition state, chemistry.chemical_compound, Colloid and Surface Chemistry, Ylide, Reagent, Reaction path, Cope rearrangement, Organosilicon
Abstract

The sila-Pummerer rearrangement of organosilicon cyclic sulfoxides proceeds via the two transition states, the first one with pentacoordinated Si that connects the reagent and the intermediate ylide and the second one that connects the ylide and the product of rearrangement.

Published
2004
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