1. Pragmatic Approach to Design Silicon Alloy Anode by the Equilibrium Method
- Author
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Hyang-Yeon Kim, Nurzhan Umirov, Deok-Ho Seo, and Sung-Soo Kim
- Subjects
Materials science ,Silicon ,020209 energy ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Anode ,Silicon alloy ,chemistry ,Amorphous matrix ,0202 electrical engineering, electronic engineering, information engineering ,Energy density ,General Materials Science ,Graphite ,Melt spinning ,Composite material ,0210 nano-technology ,Nano silicon - Abstract
Silicon fascinates with incredibly high theoretical energy density as an anode material and considered as a primary candidate to replace well-established graphite. However, further commercialization is hindered by the abnormal volume changes of Si in every single cycle. Silicon embedded in a buffer matrix using the melt-spinning process is a promising approach; however, its metastable nature significantly reduces the microstructure homogeneity, the quality of the composition, and, therefore, the electrochemical performances. Herein, we developed a new approach to design a high-performance Si-alloy with improved microstructure uniformity and electrochemical properties. Namely, annealing at a certain temperature of the melt-spun amorphous alloy ribbon allowed us to evenly distribute Si nanocrystallites in the microstructure with control of average grain size. As a result, the Si-alloy electrode delivers an initial discharge capacity of 900 mAh g
- Published
- 2020
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