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Start Over Author "Brosge, Felix" Publisher american chemical society (acs)
3 results on '"Brosge, Felix"'

2. 5-Carbonyl-1,3-oxazine-2,4-diones from N-Cyanosulfoximines and Meldrum’s Acid Derivatives

Author

Brosge, Felix, Kochs, Johanne,s Florian, Bregu, Mariela, Truong, Khai-Nghi, Rissanen, Kari, and Bolm, Carsten

Subjects
crystal structure, kemiallinen synteesi, cyclization, addition reactions, kemialliset reaktiot, reaction products, rikkiyhdisteet, chemical reactions, typpiyhdisteet, orgaaniset yhdisteet
Abstract

At elevated temperatures, N-cyanosulfoximines react with Meldrum’s acid derivatives to give sulfoximines with N-bound 5-carbonyl-1,3-oxazine-2,4-dione groups. A representative product was characterized by single-crystal X-ray structure analysis. The product formation involves an unexpected molecular reorientation requiring several sequential bond-forming and -cleaving processes. peerReviewed

Published
2020

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