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Transpiration is the process by which water is carried in plants from the roots to the leaves where evaporation takes place. Here, we report a transpiration driven electrokinetic power generator (TEPG) that exploits capillary flow of water in an asymmetrically wetted cotton fabric coated with carbon black. Accumulation of protons induced by the electrical double layer formed at the solid (carbon black)/liquid (water) interface gives rise to potential difference between the wet and dry sides. The conductive carbon black coating channels electrical current driven by the pseudostreaming mechanism. A TEPG of 90 mm × 30 mm × 0.12 mm yields a maximum voltage of 0.53 V, maximum current of 3.91 μA, and maximum energy density of 1.14 mWh cm -3 , depending on the loading of the carbon black. Multiple TEPGs generate enough power to light up a light-emitting diode (20 mA × 2.2 V) or charge a 1 F supercapacitor.

Flexible and stretchable electrochromic supercapacitor systems are widely considered as promising multifunctional energy storage devices that eliminate the need for an external power source. Nevertheless, the performance of conventional designs deteriorates significantly as a result of electrode/electrolyte exposure to atmosphere as well as mechanical deformations for the case of flexible systems. In this study, we suggest an all-transparent stretchable electrochromic supercapacitor device with ultrastable performance, which consists of Au/Ag core-shell nanowire-embedded polydimethylsiloxane (PDMS), bistacked WO 3 nanotube/PEDOT:PSS, and polyacrylamide (PAAm)-based hydrogel electrolyte. Au/Ag core-shell nanowire-embedded PDMS integrated with PAAm-based hydrogel electrolyte prevents Ag oxidation and dehydration while maintaining ionic and electrical conductivity at high voltage even after 16 days of exposure to ambient conditions and under application of mechanical strains in both tensile and bending conditions. WO 3 nanotube/PEDOT:PSS bistacked active materials maintain high electrochemical-electrochromic performance even under mechanical deformations. Maximum specific capacitance of 471.0 F g -1 was obtained with a 92.9% capacity retention even after 50 000 charge-discharge cycles. In addition, high coloration efficiency of 83.9 cm 2 C -1 was shown to be due to the dual coloration and pseudocapacitor characteristics of the WO 3 nanotube and PEDOT:PSS thin layer.

Lithium-oxygen batteries have been considered as one of the most viable energy source options for electric vehicles due to their high energy density. However, they are still faced with technical challenges, such as low round-trip efficiency and short cycle life, which mainly originate from the cathode part of the battery. In this work, we designed a three-dimensional nanofibrous air electrode consisted of hierarchically structured carbon nanotube-bridged hollow Fe 2 O 3 nanoparticles (H-Fe 2 O 3 /CNT NFs). Composite nanofibers consisted of hollow Fe 2 O 3 NPs anchored by multiple CNTs offered enhanced catalytic sites (interconnected hollow Fe 2 O 3 NPs) and fast charge-transport highway (bridged CNTs) for facile formation and decomposition of Li 2 O 2 , leading to outstanding cell performance: (1) Swagelok cell exhibited highly reversible cycling characteristics for 250 cycles with a fixed capacity of 1000 mAh g -1 at a current density of 500 mA g -1 . (2) A module composed of two pouch-type cells stably powered an light-emitting diode lamp operated at 5.0 V.

Carbon-nanotube (CNT)-based textile supercapacitors with MnO2 nanoparticles have excellent power and energy densities, but MnO2 nanoparticles can be delaminated during charge-discharge cycles, which results in significant degradation in capacitance. In this study, polypyrrole conductive polymer was coated on top of MnO2 nanoparticles that are deposited on CNT textile supercapacitor to prevent delamination of MnO2 nanoparticles. An increase of 38% in electrochemical energy capacity to 461 F/g was observed, while cyclic reliability also improved, as 93.8% of energy capacity was retained over 10 000 cycles. Energy density and power density were measured to be 31.1 Wh/kg and 22.1 kW/kg, respectively. An in situ electrochemical-mechanical study revealed that polypyrrole-MnO2-coated CNT textile supercapacitor can retain 98.5% of its initial energy capacity upon application of 21% tensile strain and showed no observable energy storage capacity change upon application of 13% bending strain. After imposing cyclic bending of 750 000 cycles, the capacitance was retained to 96.3%. Therefore, the results from this study confirmed for the first time that the polypyrrole-MnO2-coated CNT textile can reliably operate with high energy and power densities with in situ application of both tensile and bending strains.