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Dynamically responsive materials with chromotropic properties have received increasing attention in flexible pressure sensing due to their intuitive nature in the information transfer process. Here, inspired by the biological dynamic regulation of structural color in nature, a robust biomimetic mechanochromic photonic ionogel is ingeniously constructed. The photonic ionogel undergoes continuous and regular structural color changes under compression and outputs stable optical signals, possessing excellent linear pressure responsiveness and stability. The photonic ionogel exhibits sensitive changes in structural color and reflection wavelength via adjusting the lattice spacing of the 3D photonic crystal (mechanochromic sensitivity: 2.21 nm per %, Δλ > 150 nm). Furthermore, the good compatibility between ionogel and PC microspheres endows photonic ionogel with good linear pressure responsiveness (R2 ≈ 0.984). Meanwhile, ionic liquid (IL) and the covalent cross-linking network of robust polyurethane elastomer provide photonic ionogel with a wide temperature tolerance range (Tg ≈ −49.5 °C, initial decomposition temperature of 301 °C) and mechanical durability (5000 cycles of compression). This work demonstrates promising applications not only in flexible pressure sensing but also in advanced visual interaction devices. [ABSTRACT FROM AUTHOR]

The stimuli-responsive textiles, especially water-responsive textiles, have garnered attention owing to their environmental compatibility. Inspired by the hydrochromic behavior of Diphylleia grayi , water-rewritable structural color (WRSC) textiles exhibiting fast response speed and antispreading capability were fabricated by spraying hollow SiO 2 (H-SiO 2 ) microspheres and poly(trifluoroethyl methacrylate-butyl acrylate) [P(TFEMA-BA)]. The water-written textiles exhibited structural color changes in 0.6 s via an increase in the refractive index, driven by water penetrating the gaps between H-SiO 2 microspheres. The structural color was restored to the initial state after the water evaporated, allowing multiple cycles of the write-erase-write mode. The hydrophobic P(TFEMA-BA) adhesive was used to construct a stable chromogenic array and endow WRSC textiles with antispreading properties, thereby improving structural stability and achieving clear writing patterns. The prepared WRSC textiles demonstrated high flexibility, structural stability, and water-rewritable properties, providing advanced bionic inspiration and valuable design ideas for rewritable materials and smart textiles.

Biological skin systems can perceive various external stimuli through ion transduction. Especially, the skin of some advanced organisms such as cephalopods can further promptly change body color by manipulating photonic nanostructures. However, the current skin-inspired soft iontronics lack the rapid full-color switching ability to respond to multiple stimuli including tension, pressure, and temperature. Here, an intelligent chromotropic iontronics with these fascinating functions is developed by constructing a biomimetic ultrastructure with anisotropic electrostatic repulsion. This skin-like chromotropic iontronics can synchronously realize electrical response and optical visualization to mechanical strain and tactile sensation by adjusting the ultrastructure in cooperation with ionic mechanotransduction. Notably, it can perform instantaneous geometric changes to thermal stimuli via an anisotropic electrostatic repulsion interior. Such a capability allows bionic skin to transduce temperature or infrared light into ionic signals and color changes in real time. The design of anisotropic photonic nanostructures expands the intelligent application for soft iontronics at higher levels, providing a concise, multifunctional, interactive sensing platform that dynamically displays stimuli information on its body.

Utilizing photonic crystals to fabricate information encryption materials has attracted widespread interest due to their tunable optical properties and responsiveness to external stimuli. In most of the previously reported systems, the information is hidden at a specific angle and the angle-dependent invisibility is a limitation. Meanwhile, poor structural stability is still a key issue that needs to be solved for potential applications. In this paper, a bilayer heterostructure photonic crystal containing ordered hollow silica inverse opal arrays, amorphous silica opal arrays, and poly(vinyl alcohol) (adhesive) is successfully constructed. It makes the information highly invisible at any angle and also achieves information encryption. With this strategy, the information can be hidden by the noniridescent structural color derived from the strong scattering effect of light from the top layer of amorphous silica sphere arrays. After wiping with ethanol or a refractive-index-matching solvent, the scattering effect vanishes and the amorphous silica sphere arrays become transparent. The reflected light of the bottom layer caused by the increasing refractive index contrast between the inside and outside of the hollow silica spheres could rapidly reveal the hidden information. The bilayer photonic crystal exhibits robust structural stability, and the hiding/revealing process is completely reversible, which shows great potential applications in steganography and information encryption.

Stretchable strain sensors offer great potential for diverse applications in modern electronics. However, it is still difficult to fabricate strain sensors with extreme stretchability, high stability, and superior durability because of the challenge in elastic matrix. In this work, the first example of extremely stretchable and highly stable double-networks ethylene glycol (EG) organogel is developed for the fabrication of wearable strain sensors with high performances. It is shown that the formation of hybrid physically and chemically cross-linked double-networks endows the EG organogel with an extraordinarily stretchability as high as 21 000%, which is the highest value for gels reported in the literature. Meanwhile, the low vapor pressure of EG gives the organogel high ambient stability. Benefiting from the intrinsic stretchability and stability of EG organogel, the strain sensors are fabricated easily by incorporating graphene as electrically conductive filler, which display extremely wide strain-sensing range (>10 500% fracture strain) with a gauge factor of 2.3. More importantly, the sensor can withstand >50 000 loading-unloading cycles in air, exhibiting high stability and superior durability. It is demonstrated that these sensors can track joint movements and muscle vibrations (such as human joint motions, drinking, saying, breathing, and slight cough) of human body and even distinguish the deformations of different directions and the touches of a hair. This work not only provided a new elastic matrix platform for the fabrication of extremely stretchable, stable, and durable strain sensors but also demonstrates their applications as wearable electronic devices for tracking both large and tiny motions of human body, which could be further extended to the practical applications in electronic skin, human-machine interactions, and personalized health monitoring.