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1. A diversity-oriented synthesis of bicyclic cis-dihydroarenediols, cis-4-hydroxyscytalones, and bicyclic conduritol analogues.

Author

Mukherjee P, Roy SJ, and Sarkar TK

Subjects
Alcohols chemistry, Bridged Bicyclo Compounds chemistry, Cyclization, Molecular Structure, Oxidation-Reduction, Stereoisomerism, Alcohols chemical synthesis, Bridged Bicyclo Compounds chemical synthesis, Cycloparaffins chemistry
Abstract

A common-intermediate-based enantioselective strategy has been developed aiming at bicyclic arene cis-dihydrodiols, cis-4-hydroxyscytalones, and bicyclic mimics of conduritol. Key features of this protocol include Barrett's asymmetric hydroxyallylation, ring-closing metathesis (RCM), and completely regioselective Wacker oxidation of internal cyclic olefins.

Published
2010
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