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Start Over Author "Matsumura, Shuji" Publisher american chemical society
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1. One-pot synthesis of adamantane derivatives by domino Michael reactions from ethyl 2,4-dioxocyclohexanecarboxylate

Author

Takagi, Ryukichi, Miwa, Yukiko, Matsumura, Shuji, and Ohkata, Katsuo

Subjects
Cyclohexane -- Chemical properties, Acrylates -- Chemical properties, Biological sciences, Chemistry
Abstract

A method for the one-pot construction of the bicyclo[3,3,1]nonanone core by successive Michael reactions of 2-cyclohexenone derivatives and acrylates is developed. Results reveal that when ethyl 2,4-dioxocyclohexanecarboxylate is used as the susbtrate, adamantane derivatives are formed by four-bond formation in one-pot through domino Michael reactions and a Dieckmann condensation or an aldol-type addition.

Published
2005

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