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The photovoltaic effect driven by ferroelectric polarization shows great application potential in photovoltaic devices. Two-dimensional (2D) Ruddlesden–Popper perovskite molecular ferroelectric materials, which combine adjustable structure, polarization, and low band gap properties, occupy a promising position in this field. However, most of the studies on molecular ferroelectrics reported in the literature focus on single crystals, while there are few reports on thin film devices. In this paper, 2D EA2MA2Pb3Br10 (EA = ethylammonium, MA = methylammonium) molecular ferroelectric materials are used to prepare molecular ferroelectric photovoltaic devices, and polarization-driven controllable photovoltaic devices are successfully realized. Under the irradiation of standard sunlight, the device exhibits a significant photovoltaic effect, and its short-circuit current density reaches the order of mA/cm2, which is much higher than that of ordinary inorganic ferroelectrics. In addition, by applying an external electric field, the photovoltaic performance of the device can be significantly improved, and multilevel regulation can be achieved. The results provide a viable method for developing polarization-driven tunable photovoltaic devices based on 2D molecular ferroelectrics. [ABSTRACT FROM AUTHOR]

Discriminating appropriate two-dimensional (2D) photocatalysts for hydrogen generation is among the most prospective schemes to tackle with environmental contaminations. Unfortunately, the inferior capability to harvest solar light together with fast recombination of photoexcited carriers can severely reduce the catalytic ability with consequent limited commercial applications. In this work, a series of single-layer MXY (M = Ge, Sn; X, Y = S, Se, and Te) containing T- and H-phases about photocatalytic capabilities are systematically explored by first-principles calculations. First, the T- and H-MXY monolayers possess transformable band gaps of 0–2.37 and 0–1.49 eV, respectively. Astonishingly, the values of T-GeS2, T-SnS2, T-SnSe2, T-SnSSe, and H-SnS2 monolayers are higher than the threshold of redox potential difference (1.23 eV). Also, importantly, the carrier mobilities of anisotropic T-MXY monolayers can reach ∼1 × 104 cm2 V–1 s–1, which can rapidly transfer and accelerate the separation of the photoexcited carriers during photocatalytic reactions. Inspired by these significant benefits, the T-MXY monolayers have been built for photocatalytic water-splitting. Significantly, the driving force of photoexcited carriers in T-SnX2 and Janus T-SnSSe monolayers can greatly promote during the redox reactions. Furthermore, the hydrogen reduction and water oxidation reactions of T-SnX2 and T-SnXY monolayers can proceed spontaneously under irradiation. In addition, the few-layer and even monolayer T-SnS2 and T-SnSe2 have been experimentally synthesized in the literature. The potential photocatalysts of single-layer T-MXY have the 0.25–0.29 J m–2 cleavage energies, and ab initio molecular dynamics simulations further validate their stability. Our results provide support for 2D group-IV–VI chalcogenides for photocatalytic water splitting. [ABSTRACT FROM AUTHOR]