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Start Over Author "Fa LU" Publisher american chemical society
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2. Magnetic Properties of 3D Heptanuclear Lanthanide Frameworks Supported by Mixed Ligands.

Author

Fa-Lu Hu, Fei-Long Jiang, Jun Zheng, Ming-Yan Wu, Jian-Dong Pang, and Mao-Chun Hong

Subjects
*RARE earth metals, *LIGANDS (Chemistry), *MAGNETIC properties of metals, *ANTIFERROMAGNETISM, *MAGNETOCALORIC effects
Abstract

Two 3D lanthanide frameworks, [Ln7(DPA)5(NA)3(μ3-OH)8(H2O)3]·2.5H2O [H2DPA = diphenic acid; HNA = nicotinic acid; Ln = Gd (1), Dy (2)], were synthesized and structurally characterized. They were rarely seen examples of 3D frameworks constructed from heptanuclear trigonal-antiprismatic lanthanide clusters with mixed H2DPA and HNA ligands. Both 1 and 2 show typical antiferromagnetic interactions. Additionally, complex 1 possesses a large magnetocaloric effect of 34.15 J kg-1 K-1. [ABSTRACT FROM AUTHOR]

Published
2015
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3. Magnetic Properties of 3D Heptanuclear Lanthanide Frameworks Supported by Mixed Ligands.

Author

Hu FL, Jiang FL, Zheng J, Wu MY, Pang JD, and Hong MC

Abstract

Two 3D lanthanide frameworks, [Ln7(DPA)5(NA)3(μ3-OH)8(H2O)3]·2.5H2O [H2DPA = diphenic acid; HNA = nicotinic acid; Ln = Gd (1), Dy (2)], were synthesized and structurally characterized. They were rarely seen examples of 3D frameworks constructed from heptanuclear trigonal-antiprismatic lanthanide clusters with mixed H2DPA and HNA ligands. Both 1 and 2 show typical antiferromagnetic interactions. Additionally, complex 1 possesses a large magnetocaloric effect of 34.15 J kg(-1) K(-1).

Published
2015
Full Text
View/download PDF

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