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Particulate matter (PM) in air has seriously endangered human health. Especially, PM0.3 can easily enter the lungs and blood through breathing. Herein, an air filter with a three-dimensional (3D) network consisting of core-shell structured fibers was designed by in situ growth of zeolitic imidazolate framework-8 on tunicate nanocellulose/glass fiber composite filter media (ZIF-8@TNC/GF). The filtration performance of the obtained ZIF-8@TNC/GF membranes against sodium chloride particles with the MPPS (most penetrating particle size) was investigated. The air filter media at the optimal ratio of ZIF-8 exhibited an ultrahigh efficiency of 99.998% and a quality factor of 0.0308 Pa -1 for PM0.3. Further characterizations showed that the ZIF-8@TNC/GF air filter had a hierarchical and rich pore structure, showing a large specific surface area (50.3 m 2 g -1 ). More significantly, compared with the TNC/GF prepared by the dipping method, TNCs changed from the original two-dimensional (2D) nonuniform network to a uniform 3D network after the ZIF-8 was introduced. Moreover, the ZIF-8@TNC fibers with a core-shell structure inhibited the aggregation of nanocellulose. This study will shed light on the fabrication of high-efficiency TNC composite air filter media with fluffy 3D networks.

Polypyrrole (PPy) is a good candidate material for piezoresistive pressure sensors owing to its excellent electrical conductivity and good biocompatibility. However, it remains challenging to fabricate PPy-based flexible piezoresistive pressure sensors with high sensitivity because of the intrinsic rigidity and brittleness of the film composed of dense PPy particles. Here, a rational structure, that is, 3D-conductive and elastic topological film composed of coaxial nanofiber networks, is reported to dramatically improve the sensitivity of flexible PPy-based sensors. The film is prepared through surface modification of electrospun polyvinylidene fluoride (PVDF) nanofibers by polydopamine (PDA), in order to homogeneously deposit PPy particles on the nanofiber networks with strong interfacial adhesion (PVDF/PDA/PPy, PPP). This unique structure has a high surface area and abundant contact sites, leading to superb sensitivity against a subtle pressure. The as-developed piezoresistive pressure sensor delivers a low limit of detection (0.9 Pa), high sensitivity (139.9 kPa -1 ), fast response (22 ms), good cycling stability (over 10,000 cycles), and reliability, thereby showing a promising value for applications in the fields of health monitoring and artificial intelligence.

Reasonable design and synthesis of Fe/N/C-based catalysts is one of the most promising way for developing precious metal-free oxygen reduction reaction (ORR) catalysts in acidic mediums. Herein, we developed a highly active metal-organic framework-derived S-doped Fe/N/C catalyst [S-Fe/Z8/2-aminothiazole (2-AT)] prepared by thermal treatment. The S-Fe/Z8/2-AT catalyst with uniform S-doping possesses a three-dimensional macro-meso-micro hierarchically porous structure. Moreover, the chemical composition and structural features have been well-optimized and characterized for such S-Fe/Z8/2-AT catalysts; and their formation mechanism was also revealed. Significantly, applying the optimal S-Fe/Z8/2-AT catalysts into electrocatalytic test exhibits remarkable ORR catalytic activity with a half-wave potential of 0.82 V (vs reversible hydrogen electrode) and a mass activity of 18.3 A g -1 at 0.8 V in 0.1 M H 2 SO 4 solution; the polymer electrolyte membrane fuel cell test also confirmed their excellent catalytic activity, which gives a maximal power density as high as 800 mW cm -2 at 1 bar. A series of designed experiments disclosed that the favorable structural merits and desirable chemical compositions of S-Fe/Z8/2-AT catalysts are critical factors for efficient electrocatalytic performance. The work provides a new approach to open an avenue for accurately controlling the composition and structure of Fe/N/C catalysts with highly activity for ORR.

Synthesizing kinetically stable coordination polymers (CPs) through ligand functionalization can effectively improve their supercapacitive performances. Herein, we have successfully synthesized three novel and topological Co-CPs by varying the flexible N-donor ligand and inorganic anions, namely, interpenetrated [Co(HTATB)( o-bib)]·H 2 O, extended two-dimensional (2D) layered Co(HTATB)( m-bib)·2H 2 O, and three-dimensional (3D) Co(HTATB)( m-bib), where bib is the flexible N-donor bis((1 H-imidazol-1-yl)methyl)benzene linker (where o- and m- refer to ortho and meta positions, respectively) ligand and HTATB is the partial deprotonation mode from 4,4',4″- s-triazine-2,4,6-triyl-tribenzoic acid. Various Co-CPs have been directly applied in the field of supercapacitors. All these framework materials exhibit high capacitance, excellent energy delivery efficiency, and good cycling performance. For instance, the maximum specific capacitance for penetrated 3D networks is 2572 F g -1 at 2.0 A g -1 , and the mean energy delivery efficiency is up to 92.7% based on the tested current densities. Compared with extensional 2D layered and 3D networks, the 3D interpenetrated and polythreaded architectures could provide more active sites and thus promote fast charging and discharging processes. Furthermore, the Li + uptake-release abilities of the Co-based CPs are also investigated, and the initial discharge capacity value for the 3D interpenetrated structures can reach up to 1792 mA h g -1 at a current density of 50 mA g -1 .

Low-cost microfluidic devices are desirable for many chemical processes; however, access to robust, inert, and appropriately structured materials for the inner channel wall is severely limited. Here, the shear force within confined microchannels was tuned through control of reactant solution fluid-flow and shown to dramatically impact nano- through microstructure growth. Combined use of experimental results and simulations allowed controlled growth of 3D networked Zn(OH)F nanostructures with uniform pore distributions and large fluid contact areas on inner microchannel walls. These attributes facilitated subsequent preparation of uniformly distributed Pd and PdPt networks with high structural and chemical stability using a facile, in situ conversion method. The advantageous properties of the microchannel based catalytic system were demonstrated using microwave-assisted continuous-flow coupling as a representative reaction. High conversion rates and good recyclability were obtained. Controlling materials nanostructure via fluid-flow-enhanced growth affords a general strategy to optimize the structure of an inner microchannel wall for desired attributes. The approach provides a promising pathway toward versatile, high-performance, and low-cost microfluidic devices for continuous-flow chemical processes.