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Start Over Author "Yong, Tian" Topic carbonyl compounds Publisher american chemical society

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1 results on '"Yong, Tian"'

1. Base-Controlled Selective Conversion of Michael Adducts of Malonates with Enones in the Presence of Iodine.

Author

Chun-Bao Miao, Min Zhang, Zong-Yong Tian, Hai-Tao Xi, Xiao-Qiang Sun, and Hai-Tao Yang

Subjects
*MICHAEL reaction, *CARBONYL compounds, *IODINE, *CYCLOPROPANE, *ALICYCLIC compounds
Abstract

An efficient base-controlled selective conversion of the Michael adducts of malonates with enones in the presence of iodine is reported. Highly functionalized cyclopropane, oxetane, and α-hydroxylmalonate derivatives are obtained selectively using DBU, Na2CO3, and NaOAc as the base, respectively. O2 was identified to be crucial to the formation of oxetane and α-hydroxylmalonate derivatives. [ABSTRACT FROM AUTHOR]

Published
2011
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