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Start Over Author "Liu, Saiwen" Search Limiters Peer Reviewed Publisher american chemical society
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3. Palladium-Catalyzed One-Pot Diarylamine Formation from Nitroarenes and Cyclohexanones.

Author

Xie, Yanjun, Liu, Saiwen, Liu, Yong, Wen, Yuqing, and Deng, Guo-Jun

Subjects
*PALLADIUM catalysts, *AROMATIC amines, *NITROAROMATIC compounds, *CYCLOHEXANONES, *CHEMICAL reduction, *CHEMICAL reagents, *OXIDIZING agents
Abstract

The first palladium-catalyzed diarylamine formation from nitroarenes and cyclohexanone derivatives using borrowed hydrogen is described. Various diarylamines were selectively obtained in good to excellent yields. The reaction tolerated a wide range of functionalities. The nitro reduction, cyclohexanone dehydrogenation, and imine formation and reduction were realized in a cascade without an external reducing reagent and oxidant. [ABSTRACT FROM AUTHOR]

Published
2012
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