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The discovery of high concentrations of Ir and other noble metals in K-T boundary sediments (1, 2) led to the hypothesis that the worldwide enrichment of this and some other […]

The Alpha Particle X-ray Spectrometer on the Opportunity rover determined major and minor elements of soils and rocks in Meridiani Planum. Chemical compositions differentiate between basaltic rocks, evaporite-rich rocks, basaltic soils, and hematite-rich soils. Although soils are compositionally similar to those at previous landing sites, differences in iron and some minor element concentrations signify the addition of local components. Rocky outcrops are rich in sulfur and variably enriched in bromine relative to chlorine. The interaction with water in the past is indicated by the chemical features in rocks and soils at this site. [ABSTRACT FROM AUTHOR]

The alpha particle x-ray spectrometer on the Spirit rover determined major and minor elements of soils and rocks in Gusev crater in order to unravel the crustal evolution of planet Mars. The composition of soils is similar to those at previous landing sites, as a result of global mixing and distribution by dust storms. Rocks (fresh surfaces exposed by the rock abrasion tool) resemble volcanic rocks of primitive basaltic composition with low intrinsic potassium contents. High abundance of bromine (up to 170 parts per million) in rocks may indicate the alteration of surfaces formed during a past period of aqueous activity in Gusev crater. [ABSTRACT FROM AUTHOR]

Isotopic analyses of nickel in samples from the differentiated meteorite Chervony Kut revealed the presence of relative excesses of (60)Ni ranging from 2.4 up to 50 parts per 10(4). These isotopic excesses are from the decay of the now extinct short-lived nuclide (60)Fe and provide clear evidence for the existence of (60)Fe over large scales in the early solar system. Not only was (60)Fe present at the time of melting and differentiation (that is, Fe-Ni fractionation) of the parent body of Chervony Kut but also later at the time when basaltic magma solidified at or near the surface of the planetesimal. The inferred abundance of (60)Fe suggests that its decay alone could have provided sufficient heat to melt small (diameters of several hundred kilometers) planetary bodies shortly after their accretion.

Carbon and chromite fractions from the Allende meteorite that contain isotopically anomalous xenon-131 to xenon-136 (carbonaceous chondrite fission or CCF xenon) at up to 5 x 10(11) atoms per gram show no detectable isotopic anomalies in barium-130 to barium-138. This rules out the possibility that the CCF xenon was formed by in situ fission of an extinct superheavy element. Apparently the CCF xenon and its carbonaceous carrier are relics from stellar nucleosynthesis.

A carbon-chromite fraction from the Allende C3V chondrite shows strikingly large isotopic enrichments of neodymium-142 (0.47 percent) and neodymium- 143 (36 percent). Both apparently formed by alpha decay of samarium-146 and samarium-147 (half-lives 1.03 x 10(8) and 1.06 x 10(11) years), but the isotopic enrichment was greatly magnified by recoil of residual nuclei into a carbon film surrounding the samarium-bearing grains. These data provide an improved estimate of the original abundance of extinct samarium-146 in the early solar system [(146)Sm/(144)Sm = (4.5 +/- 0.5) x 10(-3)], higher than predicted by some models of pprocess nucleosynthesis. It may be possible to use this isotopic pair as a chronometer of the early solar system.

The isotopic abundances of the rare gases in the fines are found to be similar to those previously reported for gas-rich meteorites. Relative to the heavy gases, neon and helium are depleted by factors of 2.5 and 10 respectively. Accurate krypton-krypton ages for rocks 10017, 10047, 10057, and 10071 were obtained covering a range of from 47 to 509 x 10(6) years. Varying relative production rates of the krypton and xenon isotopes in these rocks suggest different irradiation conditions and a complex history for at least some of the rocks.