1. A study of2H trapping and release in2H+‐irradiated YBa2Cu3O7−δ /MgO〈100〉
- Author
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P. Przyslupski, T.J. Tate, John A. Kilner, R. E. Somekh, Y. Li, M.J. Lee, and Y. H. Li
- Subjects
Materials science ,Ion implantation ,Deuterium ,Sputtering ,Annealing (metallurgy) ,Analytical chemistry ,General Physics and Astronomy ,Activation energy ,Irradiation ,Thin film ,Thermal diffusivity - Abstract
A thin‐film sample of YBa2Cu3O7−δ on MgO was irradiated at room temperature with 50‐keV 2H+ (deuterium) to a dose of 1×1016 ions cm−2. The film was mainly c‐axis textured film, ∼360–420 nm thick, deposited by sputtering on 〈100〉 MgO substrate. The as‐implanted sample was divided into several pieces and annealed in a flowing oxygen ambient using (i) a rapid thermal annealing oven, at various temperatures between 450 and 940 °C, and (ii) a conventional annealing furnace, at various temperatures between 100 and 350 °C. Analysis by secondary‐ion mass spectroscopy shows that the implanted 2H is a fast diffuser in the 123 phase. The apparent activation temperature (energy) for 2H release from the initial traps within the YBCO film during the anneal is estimated to be ∼175 °C (∼0.97 eV), which is obviously lower than the apparent activation temperature (energy) for 2H release from the initial traps within the MgO substrate (∼550 °C, i.e., ∼1.78 eV). At 200 °C the diffusivity of 2H in the YBCO film is estimated t...
- Published
- 1995
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