1. Influence of thermal treatment on structure and properties of RF-Magnetron calcium phosphate coatings deposited on Mg-based alloy
- Author
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Marina V. Chaikina, Yurii P. Sharkeev, Anna A. Bolat-ool, Olga A. Belyavskaya, P. V. Uvarkin, Margarita A. Khimich, A. I. Tolmachev, Vladimir V. Lastovka, Konstantin A. Prosolov, and Valentina V. Chebodaeva
- Subjects
Materials science ,Alloy ,Substrate (electronics) ,Thermal treatment ,engineering.material ,Sputter deposition ,Amorphous solid ,law.invention ,Coating ,Chemical engineering ,law ,engineering ,Crystallization ,Thin film - Abstract
Mg-based alloys became a material of interest for biomedical applications. The major difficulty in the Mg-based alloy application is its rapid corrosion rate. Various coating methods are used to form a barrier layer onto Mg-based materials. In this work, a thin film of calcium phosphate was deposited on an Mg–0.8 at % Ca alloy using RF magnetron sputtering. As-deposited coatings were in an X-ray amorphous state. Post-deposition heat treatment resulted in the coating crystallization, exhibiting the pure HA phase. Heat-treatment at 450°C for 3 hours did not significantly change the coating integrity and adhesion strength to the Mg–0.8 at % Ca substrate. The Ca/P ratio, however, was changed from 1.85 for as-deposited to 2.00 for heat-treated samples. Both coating and substrate material after heat treatment exhibit preferential crystallographic growth in (002) direction with Tc(002) = 2.86 and 5.79, correspondingly.
- Published
- 2020
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