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The surface photovoltage (SPV) effect is key to the development of opto-electronic devices such as solar-cells and photo-detectors. For the prototypical transition metal dichalcogenide WSe2, core level and valence band photoemission measurements show that the surface band bending of pristine cleaved surfaces can be readily modified by adsorption with K (an electron donor) or C60 (an electron acceptor). Time-resolved pump-probe photoemission measurements reveal that the SPV for pristine cleaved surfaces is enhanced by K adsorption, but suppressed by C60 adsorption, and yet the SPV relaxation time is substantially shortened in both cases. Evidently, adsorbate-induced electronic states act as electron-hole recombination centers that shorten the carrier lifetime.

Atomically smooth, single crystalline (Bi1−xSbx)2Te3 films have been grown on SrTiO3(111) substrates by molecular beam epitaxy. A full range of Sb-Bi compositions have been studied in order to obtain the lowest possible bulk conductivity. For the samples with optimized Sb compositions (x=0.5±0.1), the carrier type can be tuned from n-type to p-type across the whole thickness with the help of a back-gate. Linear magnetoresistance has been observed at gate voltages close to the maximum in the longitudinal resistance of a (Bi0.5Sb0.5)2Te3 sample. These highly tunable (Bi1−xSbx)2Te3 thin films provide an excellent platform to explore the intrinsic transport properties of the three-dimensional topological insulators.

The surface plasmon dispersion of Ag(111) tuned by adsorption of F4-TCNQ molecules has been investigated using high resolution electron energy loss spectroscopy. For the pristine Ag(111) film, the surface plasmon energy shows a positive quadratic dispersion. After adsorption of F4-TCNQ, the plasmon energy of Ag decreases significantly and the dispersion switches sign at small q||. The deviation systematically increases with the coverage of F4-TCNQ. These behaviors are explained by charge transfer between the Ag substrate and the molecular gas layer.