1. Rare-earth garnets and perovskites for space-based ADR cooling at high T and low H
- Author
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Peter Shirron, R. A. Fry, Todd King, Edgar Canavan, Mike DiPirro, J. Panek, J. G. Tuttle, R. A. Ramirez, B. A. Rowlett, and Robert D. Shull
- Subjects
chemistry.chemical_compound ,Magnetization ,Materials science ,chemistry ,Condensed matter physics ,Radiative cooling ,Gadolinium ,Magnetic refrigeration ,chemistry.chemical_element ,Gadolinium gallium garnet ,Atmospheric temperature range ,Gallium ,Perovskite (structure) - Abstract
Future NASA satellite detector systems must be cooled to the 0.1 K temperature range to meet the stringent energy resolution and sensitivity requirements demanded by mid-term astronomy missions. The development of adiabatic demagnetization refrigeration (ADR) materials that can efficiently cool from the passive radiative cooling limit of ∼30 K down to sub-Kelvin under low magnetic fields (H⩽3 T) would represent a significant improvement in space-based cooling technology. Governed by these engineering goals, our efforts have focused on quantifying the change in magnetic entropy of rare-earth garnets and perovskites. Various compositions within the gadolinium gallium iron garnet solid solution series (GGIG, Gd3Ga5−XFeXO12, 0.00⩽X⩽5.00) and gadolinium aluminum perovskite (GAP, GdAlO3) have been synthesized via an organometallic complex approach and confirmed with powder x-ray diffraction. The magnetization of the GGIG and GAP materials has been measured as a function of composition (0.00⩽X⩽5.00), temperature...
- Published
- 2002