1. THE PUZZLE OF TWO DIFFERENT SUB-MICROMETER TUNGSTEN-RICH DEPOSITS IN BULK YBCO: ONE ACTS AS PINNING CENTERS AND THE OTHER DOES NOT
- Author
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Ravi-Persad Sawh, Roy Weinstein, Drew Parks, Alberto Gandini, and U. (Balu) Balachandran
- Subjects
Superconductivity ,Number density ,Materials science ,Ferromagnetism ,chemistry ,Inorganic chemistry ,X-ray crystallography ,Doping ,Analytical chemistry ,chemistry.chemical_element ,Cuprate ,Tungsten ,Type-II superconductor - Abstract
Two types of large grain YBCO samples doped with tungsten oxide, one with platinum and the other without, were produced using a slow cooling process. Observations of the trapped magnetic flux density showed that the flux density of the W-doped, Pt-free samples did not change with W doping levels of up to 2.1 mol%. In contrast, the (W+Pt)-doped samples resulted in a monotonic improvement in trapped magnetic flux density as a function of W doping. Microstructure studies indicate that both types of samples contain profuse sub-micrometer deposits of a W-rich compound. The Pt-free samples contain (W{sub 0.4}Y{sub 0.6})BaO{sub 3} deposits while the (W+Pt)-doped samples contain deposits of a (W{sub 0.5}Pt{sub 0.5})YBa{sub 2}O{sub 6} compound. Both types of deposits are of essentially the same size and have comparable number density. The results are strikingly similar to an earlier experiment in which uranium doped, Pt-free, large grain YBCO also did not show any improvement in trapped magnetic flux density. The U-doped, Pt-free samples contain profuse sub-micrometer deposits of a (U{sub 0.4}Y{sub 0.6})BaO{sub 3} compound, which have been shown to be ferromagnetic. The inability of both the (W{sub 0.4}Y{sub 0.6})BaO{sub 3} and (U{sub 0.4}Y{sub 0.6})BaO{sub 3} sub-micrometer deposits to act as pinning centersmore » in self-field, suggest that this behavior is systematic.« less
- Published
- 2010