1. Diffusion Experiment in Lithium Ionic Conductors with the Radiotracer of [sup 8]Li: from Micro- to Nano-diffusion
- Author
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Sun-Chan Jeong, Ichiro Katayama, Hirokane Kawakami, Yutaka Watanabe, Hironobu Ishiyama, Nobuaki Imai, Yoshikazu Hirayama, Hiroari Miyatake, Masao Sataka, Hiroyuki Sugai, Satoru Okayasu, Shin-Ichi Ichikawa, Katsuhisa Nishio, Shinichi Mitsuoka, Takamitsu Nakanoya, Takashi Hashimoto, Takanori Hashimoto, Masahito Yahagi, Yutaka Utsuno, Tohru Motobayashi, and Angela Bracco
- Subjects
Nanostructure ,Ion implantation ,Chemistry ,Nano ,Analytical chemistry ,Ionic conductivity ,chemistry.chemical_element ,Ionic bonding ,Lithium ,Diffusion (business) ,Ion - Abstract
We have developed a radiotracer method for diffusion studies in lithium ionic conductors, by using, as the tracer, the short‐lived α‐emitting radioisotope of 8Li from TRIAC (Tokai Radioactive Ion Accelerator Complex). In the method, we measured α‐particles coming out of the sample of interest and have found that the time‐dependent yields of α‐particle from the diffusing 8Li primarily implanted is a good measure of the Li diffusion in the sample. The method has been successfully applied to measure the lithium diffusion coefficients in a typical defect‐mediated lithium ionic conductor of LiGa, well demonstrating that the method is very efficient to measure the diffusion in the micro‐meter regime per second. Further development, as an extension of the present method, was proposed to measure the diffusion on the nanoscale in lithium ionic conductors.
- Published
- 2009
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