1. Diboron-Catalyzed Dehydrative Amidation of Aromatic Carboxylic Acids with Amines
- Author
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Susumu Saito, Dattatraya B. Bagal, Dinesh N. Sawant, K. Selvam, and Saeko Ogawa
- Subjects
chemistry.chemical_compound ,chemistry ,010405 organic chemistry ,Aryl ,Organic Chemistry ,Organic chemistry ,Physical and Theoretical Chemistry ,010402 general chemistry ,01 natural sciences ,Biochemistry ,Stoichiometry ,0104 chemical sciences ,Catalysis - Abstract
Tetrakis(dimethylamido)diboron and tetrahydroxydiboron are herein reported as new catalysts for the synthesis of aryl amides by catalytic condensation of aromatic carboxylic acids with amines. The developed protocol is both simple and highly efficient over a broad range of substrates. This method thus represents an attractive approach for the use of diboron catalysts in the synthesis of amides without having to resort to stoichiometric or additional dehydrating agents., ファイル公開：2019-08-03
- Published
- 2018