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High-resolution spectra of Pluto in the 1.66 μm region, recorded with the VLT/CRIRES instrument in 2008 (2 spectra) and 2012 (5 spectra), are analyzed to constrain the spatial and vertical distribution of methane in Pluto’s atmosphere and to search for mid-term (4 year) variability. A sensitivity study to model assumptions (temperature structure, surface pressure, Pluto’s radius) is performed. Results indicate that (i) no variation of the CH 4 atmospheric content (column-density or mixing ratio) with Pluto rotational phase is present in excess of 20%, (ii) CH 4 column densities show at most marginal variations between 2008 and 2012, with a best guess estimate of a ∼20% decrease over this time frame. As stellar occultations indicate that Pluto’s surface pressure has continued to increase over this period, this implies a concomitant decrease of the methane mixing ratio (iii) the data do not show evidence for an altitude-varying methane distribution; in particular, they imply a roughly uniform mixing ratio in at least the first 22–27 km of the atmosphere, and high concentrations of low-temperature methane near the surface can be ruled out. Our results are also best consistent with a relatively large (>1180 km) Pluto radius. Comparison with predictions from a recently developed global climate model indicates that these features are best explained if the source of methane occurs in regional-scale CH 4 ice deposits, including both low latitudes and high Northern latitudes, evidence for which is present from the rotational and secular evolution of the near-IR features due to CH 4 ice. Our “best guess” predictions for the New Horizons encounter in 2015 are: a 1184 km radius, a 17 μbar surface pressure, and a 0.44% CH 4 mixing ratio with negligible longitudinal variations. [ABSTRACT FROM AUTHOR]

Abstract: New line data describing the absorption of CH4 and CH3D from 1.26 to 1.71μm (Campargue, A., Wang, L., Mondelain, D., Kassi, S., Bézard, B., Lellouch, E., Coustenis, A., de Bergh, C., Hirtzig, M., Drossart, P. [2012]. Icarus 219, 110–128), building upon previous papers by Campargue et al. (Campargue, A., Wang, L., Kassi, S., Masat, M., Votava, O. [2010]. J. Quant. Spectrosc. Radiat. Transfer 111, 1141–1151; Wang, L., Kassi, S., Campargue, A. [2010]. J. Quant. Spectrosc. Radiat. Transfer 111, 1130–1140; Wang, L., Kassi, S., Liu, A.W., Hu, S.M., Campargue, A. [2011]. J. Quant. Spectrosc. Radiat. Transfer 112, 937–951)) have been applied to the analysis of Gemini-N/NIFS observations of Uranus made in 2010 and compared with earlier disc-averaged observations made by KPNO/FTS in 1982. The new line data are found to improve greatly the fit to the observed spectra and present a huge advance over previous methane absorption tables by allowing us to determine the CH3D/CH4 ratio and also start to break the degeneracy between methane abundance and cloud top height. The best fits are obtained if the cloud particles in the main cloud deck at the 2–3bar level become less scattering with wavelength across the 1.4–1.6μm region and we have modelled this variation here by varying the extinction cross-section and single-scattering albedo of the particles. Applying the new line data to the NIFS spectra of Uranus, we determine a new estimate of the CH3D/CH4 ratio of , which is consistent with the estimate of de Bergh et al. (de Bergh, C., Lutz, B.L., Owen, T., Brault, J., Chauville, J. [1986]. Astrophys. J. 311, 501–510) of , made by fitting a disc-averaged KPNO/FTS spectrum measured in 1982, but much better constrained. The NIFS observations made in 2010 have been disc-averaged and compared with the 1982 KPNO/FTS spectrum and found to be in excellent agreement. Using k-tables fitted to the new line data, the central meridian observations of Uranus’ H-band spectrum (1.49–1.64μm) made by Gemini-N/NIFS in 2010 have been reanalyzed. The use of the new methane absorption coefficients and the modified scattering properties of the cloud particles in the main cloud deck appears to break the degeneracy between cloud height and methane abundance immediately above it in this spectral region and we find that both vary with latitude across Uranus’ disc. Overall, we find that the main cloud deck becomes higher, but thinner from equator to poles, with a local maximum in cloud top height in the circumpolar zones at 45°N and 45°S. At the same time, using the ‘D’ temperature pressure profile of Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92, 14987–15001) and a deep methane abundance of 1.6% (Baines, K.H., Mickelson, M.E., Larson, L.E., Ferguson, D.W. [1995]. Icarus 144, 328–340) we find that the relative humidity of methane is high near the equator (∼60%) and decreases sharply towards the poles, except near the circumpolar zone at 45°N, which has brightened steadily since 2007, and where there is a local maximum in methane relative humidity. In tests conducted with the warmer ‘F1’ profile of we find a similar variation of methane abundance above the main cloud, although for this warmer temperature profile this abundance is dependent mostly on the fitted deep methane mole fraction. [Copyright &y& Elsevier]

Highlights: [•] Revised WKMC-80K methane line data give very good fit to Neptune H-band spectra. [•] Reflectivity of particles in main cloud deck is found to decrease with wavelength from 1.4 to 1.6μm. [•] Neptune’s CH3D/CH4 ratio is determined to be . [•] The abundance of CO at the cloud tops (2–3bars) is found to be much less than in the stratosphere. [ABSTRACT FROM AUTHOR]

Abstract: We present new photometric and spectroscopic observations of the Pluto–Charon system carried out at the VLT-ESO (Chile) with two 8-m telescopes equipped with the FORS2, ISAAC and SINFONI instruments. The spectra were obtained in the 0.6–2.45μm range with a spectral resolution from 300 to 1500. The SINFONI data were obtained using adaptive optics, allowing a complete separation of the two bodies. We derive both objects’ magnitudes in the near infrared and convert them into albedo values. These first near infrared photometric data allow to adjust the different parts of Pluto’s spectrum, provided by the three instruments. We run spectral models in order to give chemical and physical constraints on the surface of Pluto and Charon. We discuss the dilution properties of the methane ice and its implications on Pluto’s surface. The heterogeneities of the pure and diluted methane ice on Pluto’s surface is also investigated. The high signal-to-noise level of the data and our analyses may support the presence of ethane ice on the surface of Pluto, which is one of the main products of the methane irradiation and photolysis. The analyses of the spectra of Charon suggest that the water ice is almost completely in its crystalline form and that the ammonia compound is hydrated on the surface of this satellite. [ABSTRACT FROM AUTHOR]

Abstract: Several different trans-neptunian objects have been studied in order to investigate their physical and chemical properties. New observations in the 1.1–1.4μm range, obtained with the ISAAC instrument, are presented in order to complete previous observations carried out with FORS1 in the visible and SINFONI in the near infrared. All of the observations have been performed at the ESO/Very Large Telescope. We analyze the spectra of six different objects (2003 AZ83, Echeclus, Ixion, 2002 AW197, 1999 DE9 and 2003 FY128) in the 0.45–2.3μm range with the model of Hapke (Hapke, B. [1981]. J. Geophys. Res. 86, 4571–4586) and the method of Shkuratov et al. (Shkuratov, Y., Starukhina, L., Hoffmann, H., Arnold, G. [1999]. Icarus 137, 235–246). Water ice is found on two objects, and in particular it is confirmed in its amorphous and crystalline states on 2003 AZ84 surface. Upper limits on the water ice content are given for the other four TNOs investigated, confirming previous results (Barkume, K.M., Brown, M.E., Schaller, E.L. [2008]. Astron. J. 135, 55–67; Guilbert, A., Alvarez-Candal, A., Merlin, F., Barucci, M.A., Dumas, C., de Bergh, C., Delsanti, A. [2009]. Icarus 201, 272–283). Whatever the absorption features in the near infrared, all objects but one exhibit a moderate red slope in the visible, as most TNOs and Centaurs. We discuss the implications of the presence of water ice and the probable sources of the red slope. [Copyright &y& Elsevier]

We present an analysis of the colors available for seven trans-neptunian objects (TNOs) and three centaurs among the reddest known, aimed at characterizing their surface chemical properties. In particular we seek to obtain evidence in support of the proposed correlation between the visible coloration of the surface of TNOs and their surface compositions (Brown, M.E., Schaller, E.L., Fraser, W.C. [2011]. Astrophys. J. 739, L60). The analysis focuses on nine available colors in the visible–near IR (0.3–4.5 μm) spectral range scaled to the V albedo to provide a proxy for the spectral shape of the objects. The colors include Spitzer IRAC data never published before, key in providing an effective constraint in the discrimination of ices contributing to the surface composition of the objects. Compositions are obtained by comparing the data to a grid of radiative transfer models convolved by the filter response functions of the colors adopted in the spectrum-proxies to match the resolution of the observations. We find evidence suggesting the presence of hydrocarbons and/or methanol on the surfaces of most objects in our sample, supporting the hypothesis by Brown et al. (Brown, M.E., Schaller, E.L., Fraser, W.C. [2011]. Astrophys. J. 739, L60) that the coloration of red TNOs could be linked to their methanol content. From our finding of methanol/hydrocarbon ices on the surfaces of the objects in our sample of very red TNOs and centaurs we infer that ultra-red objects in general might contain these ices and therefore might have formed in the outer part of the Solar System. We also deduce that the surfaces of most of the very red TNOs in our dataset are probably still quite pristine, and that their organic materials could have been produced by irradiation of the volatile ices whose traces are still present on their surface. Although our sample is small, we infer that the irradiation process is still in progress, as hinted by the centaurs’ slightly elevated organic amounts at smaller perihelion distances. However, considering the relatively similar amounts of organics found in our data at a wide variety of perihelion distances, we also infer that it could have started before Neptune’s migration. The technique used to constrain the composition described as part of this study introduces a new approach at investigating the surface chemistry of the very small and numerous objects that constitute the bulk of the TNO and centaur populations. This innovative method has the potential to provide constraints for irradiation theories and for models of dynamical and chemical evolution of the Solar System. [ABSTRACT FROM AUTHOR]

Highlights: [•] We analyze Cassini VIMS spectra of Titan using improved methane spectroscopic data. [•] We constrain the aerosol single scattering albedo and derive the surface albedo over specific terrains. [•] Differences in surface albedos can be explained by different amounts of tholins and water ice particles. [•] The surface albedo of the Huygens landing site at 2μm is inconsistent with water ice being a major compound. [•] No reversal of the North-to-South asymmetry in the stratospheric haze is seen till mid-2010. [Copyright &y& Elsevier]

Abstract: A Large Program (LP) has been carried out at ESO–VLT using almost simultaneously the UT1, UT2 and UT4 telescopes (Cerro Paranal, Chile). The aim of this Large Program was to obtain simultaneous visible and near-IR spectroscopic measurements (using FORS, ISAAC and SINFONI instruments) with a S/N ratio as high as possible for almost all objects among different dynamical groups observable within the VLT capability. In this paper we present results on the second half of the Large Program which includes new near-infrared spectroscopy data of 20 objects. For 12 of them for which we had obtained the complete spectral range (V+J+H+K bands), we apply a radiative transfer model to the entire spectral range to constrain their surface composition. We also present an analysis of all near-IR spectral data available on TNOs and Centaurs from both the complete LP and the literature. An overview for a total sample of 75 objects is thus carried out analyzing the ice content with respect to the physical and dynamical characteristics. The major new results are: (i) all objects classified as BB class seem to have icy surfaces; (ii) the possible presence of CH3OH has primarily been detected on very red surfaces (RR class objects) and (iii) the majority of Centaurs observed multiple times have an heterogeneous composition. [Copyright &y& Elsevier]

Abstract: Asteroid dynamical families are supposed to be formed from the collisional disruption of parent bodies. As a consequence, the investigation of the surface properties of small and large family members may give some hints on the nature of the dynamical group, the internal composition of the parent body, and the role played by space weathering processes in modifying the spectral behavior of the members'' surfaces. In this work we present visible–near-infrared observations of 24 Jupiter Trojans belonging to seven dynamical families of both the L4 and L5 swarms. The most important characteristics we found is the uniformity of the Trojans population. All the investigated Trojans have featureless spectra and a spectral behavior typical of the primitive P and D taxonomic classes. In particular, no signatures of water ice have been found on the spectra of these primordial bodies. From our investigation, the L4 and L5 clouds appear to be compositionally indistinguishable. Tentative models of the surface composition, based on the Hapke theory, are presented and discussed. [Copyright &y& Elsevier]

In this paper we present results obtained in the framework of a visible spectroscopic and photometric survey of Trojan asteroids. We concentrated on bodies orbiting at the L5 Lagrangian point of Jupiter that are also members of dynamical families. Spectroscopy is a crucial tool that allows us to characterize the mineralogical composition of families and their parent bodies, gives evidence of ongoing space weathering, and confirms family membership. We have observed 18 objects belonging to the Aneas, Astyanax, Sarpedon, and Phereclos families as defined by Beaugé and Roig (2001, Icarus 53, 391). In addition, we have determined the spectroscopic properties of 8 background Jupiter Trojans. The observed spectra are reddish with a dominance of D-type asteroids. As expected, the spectra of the non-family members are more heterogeneous compared to the spectra of family members, with the exception of the members of the Aneas family. We also confirm the lack of absorption features in the visible region, as already reported by other authors. [Copyright &y& Elsevier]

10199 Chariklo (1997 CU26) is the largest Centaur so far known. We carried out near-infrared observations of this object during two different runs separated by a year. Although no evidence for spectral variations has been found over short time scales, slight differences have been detected between the two observational runs. We interpret these findings as likely due to a heterogeneous composition of the surface of Chariklo. We suggest two different models comprising geographical mixtures of tholins, amorphous carbon, and water ice in slightly different percentages. Our observations confirm the presence of water ice on the surface of this Centaur, as already detected by Brown et al. (1998, Science 280, 1430–1432) and Brown and Koresko (1998, Astrophys. J. 505, L65–67). [Copyright &y& Elsevier]

Transneptunian objects and Centaurs are supposed to be among the most pristine bodies of the Solar System. To investigate their physical properties and their surface composition, an ESO large program at the Very Large Telescope was carried out. In this paper we present photometric and spectroscopic near-infrared data of two Centaurs (1998 SG35 and 2000 QC243) and one transneptunian object (47171 1999 TC36). For 47171 1999 TC36 and 1998 SG35 visible photometry is also presented. Models of the surface composition of these objects are presented and discussed. By including a small percentage of water ice in our geographical mixtures, we obtain a better agreement with the observations in the H and K bands. [Copyright &y& Elsevier]