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Abstract Exploitation of noncovalent interactions for recognition of an organic substrate has received much attention for the design of metal catalysts in organic synthesis. The CH–π interaction is especially of interest for molecular recognition because both the C–H bonds and the π electrons are fundamental properties of organic molecules. However, because of their weak nature, these interactions have been less utilized for the control of organic reactions. We show here that the CH–π interaction can be used to kinetically accelerate catalytic C–H activation of arenes by directly recognizing the π-electrons of the arene substrates with a spirobipyridine ligand. Computation and a ligand kinetic isotope effect study provide evidence for the CH–π interaction between the ligand backbone and the arene substrate. The rational exploitation of weak noncovalent interactions between the ligand and the substrate will open new avenues for ligand design in catalysis.

Using nano-sized energetic materials as fuel additives to hydrocarbon gel fuel has gained in popularity due to the advantages of higher energy density and shorter ignition delay times. Combustion characteristics and application performance of gel fuel containing 16% wt aluminum nanoparticles were investigated on a direct-connect scramjet platform with an inflow Mach number of 2, an inflow total temperature of 1700 K, and a fuel equivalence ratio ranging from 0.6 to 1.0. The gel fuel could be stably injected and atomized efficiently by a nitrogen-assisted injector. The combustion efficiency of JP-10+ Al gel fuel was 4.27% higher than that of JP-10 gel fuel, while the addition of aluminum increased the density specific impulse by 6.34%, indicating that the addition of aluminum nanoparticles indeed presented a positive effect on combustion and engine performance. The wall deposition phenomenon of gel fuel was particularly slight as compared to that of slurry fuel cases. Unlike nanoaluminum-blended slurry fuel, nanoaluminum-blended gel fuel controlled the potential risk of increasing thermal load to the least degree within the scope of existing research, with wall heat flux increasing by 7.43% solely as a result of elevated airflow temperature, indicating its advantageous application prospect. [ABSTRACT FROM AUTHOR]

Constructed wetlands (CWs) primarily achieve efficient wastewater purification through synergistic interactions among substrates, plants, and microorganisms. Serving as the structural foundation of the entire wetland system, substrates not only provide a growth medium for plants, but also serve as adhesive carriers for microorganisms and habitats for animal activities. Research on substrates has attracted considerable attention; however, in practical engineering applications, the selection of substrates often depend on personal experience, which may lead to significant gaps in the effectiveness of wetland systems in treating different characteristic contaminants. Therefore, it is of great significance to investigate the influence of substrates on the removal of contaminants in sewage and identify substrate materials with good physical and chemical properties to optimize the design and operation of CWs-based sewage-treatment systems and improve their purification efficiency. In this review, bibliometric analysis was conducted to using the Web of Science database and VOSviewer_1.6.20 software to assess the progress of research on CWs. This article provides a comprehensive overview of substrate types and characteristics based on recent research advancements in the field. Additionally, it discusses removal methods and the influence of factors related to conventional contaminants (COD, nitrogen, and phosphorus), heavy metals (HMs), fluorinated compounds, pharmaceuticals, personal care products (PPCPs), and microplastics. A thorough evaluation was conducted on the economic costs of various substrates and their ability to remove major contaminants from water bodies, providing a reference for the further development of wetland technology.