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This work presents results on the finiteness, and on the symmetry properties, of various homological dimensions associated to the Jacobson radical and its higher syzygies, of a semiperfect ring. [ABSTRACT FROM AUTHOR]

The academic community has spent a lot of time and effort in recent years discussing the fact that gamification has a significant positive impact on encouraging user engagement behaviour. As the mainstream of current research, gamification affordance refers to the action possibilities provided by the gamified elements and features of gamified systems. However, there is a lack of research on how to improve users’ knowledge sharing behaviour by introducing gamification affordances into the social question and answer (Q&A) community. This study develops a causal relationship model between gamification affordance and knowledge sharing behaviour by utilising the social Q&A community as the research object. The fundamental characteristics of gamification affordance which users value are defined through a semi-structured interview based on a focus group. The results of the structural equation model analysis on Chinese users (n = 310) demonstrate that gamification affordances enhance the gamified experience of users, thus improving user satisfaction, and ultimately affecting users’ knowledge sharing behaviour. Furthermore, this study explored the important role of gamification affordance in the development of the social Q&A community and verified the significant role of gamified experience in enhancing the psychological outcomes of users. The study concludes with a discussion-worthy theoretical and practical significance. [ABSTRACT FROM AUTHOR]

Summary: Numerous guidelines have called for personalized interventions to address childhood obesity. The role of fat mass and obesity‐associated gene (FTO) in the risk of childhood obesity has been summarized. However, it remains unclear whether FTO could influence individual responses to obesity interventions, especially in children. To address this, we systematically reviewed 12,255 records across 10 databases/registers and included 13 lifestyle‐based obesity interventions (3980 children with overweight/obesity) reporting changes in body mass index (BMI) Z‐score, BMI, waist circumference, waist‐to‐hip ratio, and body fat percentage after interventions. These obesity‐related outcomes were first compared between children carrying different FTO genotypes (rs9939609 or its proxy) and then synthesized by random‐effect meta‐analysis models. The results from single‐group interventions showed no evidence of associations between FTO risk allele and changes in obesity‐related outcomes after interventions (e.g., BMI Z‐score: −0.01; 95% CI: −0.04, 0.01). The results from controlled trials showed that associations between the FTO risk allele and changes in obesity‐related outcomes did not differ by intervention/control group. To conclude, the FTO risk allele might play a minor role in the response to obesity interventions among children. Future studies might pay more attention to the accumulation effect of multiple genes in the intervention process among children. [ABSTRACT FROM AUTHOR]

A numerical modeling method to reproduce the structures of needle-punched nonwoven geotextile based on the actual manufacturing process (web formation and web bonding) was developed. The geotextile model was built based on the statistical characteristics of the computed tomography (CT) observations, physical and mechanical properties of fibers, and physical parameters of the geotextile. A combination of the finite element model and pore network model method was proposed to obtain the pore size characteristics. The appearance and pore size characteristics before and under uniaxial tensile strains were investigated. It is shown that the method can simulate the geotextile manufacturing process satisfactorily. The pore size distribution (PSD) curves obtained from the model show good agreement with the CT-based results. Moreover, the method can reasonably simulate the tensile behaviors of geotextile under uniaxial tensile strain. The specimen necking phenomenon during the uniaxial tensile test was well reproduced. The PSD curves moved towards the direction of larger pore size with increasing uniaxial strain, and characteristic pore sizes (O 98 , O 95 , O 50 , O 30 , O 10) all show a relatively steady increasing trend. • The structures of nonwoven geotextiles are reproduced by numerical simulation of the actual preparing process (web formation and web bonding). • A FEM-PNM method was proposed to obtain the pore size characteristics of the geotextile model. • The PSD curves obtained from the numerical model show a good agreement with the experimental results based on CT. • The specimen necking phenomenon during the uniaxial tensile test was well reproduced. • The PSD curves moved towards the direction of larger pore size with uniaxial strain, and characteristic pore sizes all show an increasing trend. [ABSTRACT FROM AUTHOR]

This research introduces the recentering energy dissipation bracing with a pendulum in prefabricated steel frame (REBP-PSF) structures. The primary objective of this study is to mitigate potential severe damage to steel frames during seismic events and to expedite postearthquake rehabilitation. This innovative system harnesses energy dissipation through friction between structural members and facilitates recentering through the cable pretensioning force. Consequently, this may make postearthquake repairs minimal or even unnecessary. Three REBP-PSF structures and a prefabricated steel frame with cantilever beam splices (PSF-CBS) were meticulously modeled using the ABAQUS finite element method to evaluate the seismic performance of this novel system. The study investigated the effects of pretensioning parameters and varied structural morphologies on seismic performance metrics, including failure modes, hysteresis performance, energy dissipation capacity, and residual displacements. This paper introduced a simplified method to simulate the restoring force model of REBP using the connection element method. Subsequently, a model for the REBP-RSF overall structure was established, enabling nonlinear dynamic time-history analysis, which was then compared with the rigid steel frame (RSF) structure. The results showed that the REBP-PSF structure outperformed the PSF-CBS in terms of initial stiffness, yield load, ultimate load, and energy dissipation capability. The bearing and energy dissipation capacities of the REBP-PSF structure were enhanced by augmenting the cable pretensioning force within this structure. The proposed connection element method could accurately simulate the hysteretic behavior of REBP. Compared with the RSF structure, the REBP-RSF demonstrated superior seismic performance, characterized by small story drift and residual displacements during seismic activities. Furthermore, a notable augmentation was observed in the lateral stiffness and torsional rigidity of the proposed structure. • The REBP-PSF structure is proposed and its seismic performance is analyzed. • The REBP-PSF structure dissipates energy through friction between REBP. • The connection element method is proposed and verified. • The REBP-RSF structure based on the connection element method is established. [ABSTRACT FROM AUTHOR]

This paper proposes a phase generated carrier (PGC) demodulation scheme for sinusoidal phase modulation interferometer (SPMI) that does not require a second harmonic carrier signal. In this scheme, an in-phase interference signal component with direct current (DC) bias is obtained by low-pass filtering the original interference signal, and a quadrature interference signal component is obtained by conventional means. The Lissajous figure formed by these two quadrature interference signal components is an ellipse whose center deviates from the origin of the I-Q coordinates. By fitting this ellipse, the major and minor axes and the center coordinates can be obtained. These elliptic parameters are then used to eliminate DC bias and normalize the amplitude of the quadrature signal components. Finally, the phase demodulation of the interference signal can be realized by using arctangent algorithm or differential cross multiplication (DCM) algorithm. The results of simulation and experiment have verified the validity and accuracy of the proposed PGC demodulation scheme, and show that it is insensitive to the phase modulation depth C. Compared with conventional PGC demodulation, this scheme requires lower depth of carrier phase modulation. The vibration measurement results indicate that the average signal-to-noise and distortion Ratio (SINAD) and total harmonic distortion (THD) values of demodulation results in the frequency range of 130 Hz to 250 Hz are 34 dB and -33 dB respectively. The proposed PGC demodulation scheme shows good performance in displacement measurement using SPMI. • A novel PGC demodulation scheme without using a second harmonic carrier signal. • Lissajous ellipse with center deviated from origin in I-Q coordinates. • Demodulation performance comparison, test for the signal-to-noise and distortion ratio and the total harmonic distortion. • PGC demodulation scheme with a low optimal phase modulation depth. [ABSTRACT FROM AUTHOR]

For any finite dimensional algebra Λ given by a quiver with relations, we prove that its dg singularity category is quasi-equivalent to the perfect dg derived category of a dg Leavitt path algebra. The result might be viewed as a deformed version of the known description of the dg singularity category of a radical-square-zero algebra in terms of a Leavitt path algebra with trivial differential. The above result is achieved in two steps. We first introduce the singular Yoneda dg category of Λ, which is quasi-equivalent to the dg singularity category of Λ. The construction of this new dg category follows from a general operation for dg categories, namely an explicit dg localization inverting a natural transformation from the identity functor to a dg endofunctor. This localization turns out to be quasi-equivalent to a dg quotient category. Secondly, we prove that the endomorphism algebra of the quotient of Λ modulo its Jacobson radical in the singular Yoneda dg category is isomorphic to the dg Leavitt path algebra. The appendix is devoted to an alternative proof of the result using Koszul-Moore duality and derived localizations. [ABSTRACT FROM AUTHOR]

Clean energy has become an important component of the transition to a sustainable future, of which offshore wind power is a promising clean energy source. However, there are still gaps in the spatiotemporal data of OWTs with global coverage, precise location, freely available, and with long time series of installation time information. This study proposes a cost-effective method to investigate the global distribution and installation time of offshore wind turbines (OWTs) using remote sensing data and the GEE cloud computing platform. The process includes two parts, the first is OWTs extraction through synthetic SAR images using an adaptive Z-score threshold and morphological operations. The second part is installation time detection through synthetic Landsat optical images using LandTrendr algorithm. A total of 12,412 OWTs have been identified within the offshore Exclusive Economic Zones (EEZ) of countries worldwide, with 5915 in Europe, 6490 in Asia, and only 7 in the United States. Most OWTs are situated in nearshore areas and were constructed in a regular pattern. Installation dates of existing OWTs worldwide reveal an exponential growth trend since the 21st century, with Europe leading the way and Asia catching up rapidly, building two-thirds of its turbines after 2019. This information can be used for subsequent studies on the effectiveness of wind energy in reducing greenhouse gas emissions, the potential for future development and expansion of wind energy infrastructure, as well as to inform policies aimed at promoting the sustainability of the wind energy industry. • We identify 12412 offshore wind turbines worldwide in 2022. • Most turbines are nearshore with a regular pattern. • Exponential growth in installation since the 21st century. • Europe is leading in construction, while Asia is rapidly catching up. • The data guides future energy infrastructure development and sustainable policies. [ABSTRACT FROM AUTHOR]

Incorporating three-dimensional (3D) spatial measurement into the urban expansion measurement system plays an important role in understanding the degree of urban expansion and regulating and governing it. This article proposes an urban concrete forest and constructs an Urban Volume Sprawl Index to quantitatively study the spatiotemporal characteristics of the three-dimensional expansion of Chinese prefecture-level cities. Furthermore, geographic detectors are used to study its influencing factors. The following conclusions are drawn: (1) Between 1990 and 2018, the volume of Chinese cities has increased from 414.67 to 1,406.29 km3, with a growth rate of 239.13%. (2) The overall growth rate of urban volume shows a gradual slowing trend during the research period, from 55.99% to 40.83%. (3) Between 1990 and 2018, the Urban Volume Sprawl Index nationwide gradually slowed down (from 5.18% to 3.90%), with the largest rate reported in the western region (4.1%), the middle in the eastern region (3.46%), and the smallest in the central region (3.28%). (4) Government and economic factors have the greatest impact on the three-dimensional expansion of Chinese cities (over 69%), with social factors in the middle, and natural factors having the weakest explanatory power (less than 15%). (5) There are differences in the degree of urban expansion between two-dimensional and three-dimensional perspectives. A total of 38.1% of cities have a greater degree of urban expansion from a two-dimensional (2D) analysis perspective, which are mainly small cities located in the western and eastern regions. A total of 5.4% of cities (mainly located in the Yangtze River Delta and Pearl River Delta regions) have a greater degree of urban expansion from a 3D perspective. The remaining cities (56.5%) go through the same level of urban expansion in both analysis dimensions. A 3D urban expansion analysis can better explain and reveal the actual production and living space provided by urban expansion than 2D analysis. It can provide temporal data for urban land efficiency evaluation, ghost city identification, etc., and it has good application and promotion prospects. [ABSTRACT FROM AUTHOR]

Frequent spontaneous combustion activities restrict ecological restoration of coal waste dumps after reclamation. Effective monitoring of vegetation restoration is important for ensuring land reclamation success and preserving the ecological environment in mining areas. Development of unmanned aerial vehicle (UAV) technology has enabled fine-scale vegetation monitoring. In this study, we focused on Medicago sativa L. (alfalfa), a representative herbaceous vegetation type, in a coal waste dump after reclamation in Shanxi province, China. The alfalfa aboveground biomass (AGB) was used as an indicator for assessing vegetation restoration. The objective of this study was to evaluate the capacity of UAV-based fusion of RGB, multispectral, and thermal infrared information for estimating alfalfa AGB using various regression models, including random forest regression (RFR), gradient boosting decision tree (GBDT), K-nearest neighbor (KNN), support vector regression (SVR), and stacking models. The main results are as follows: (i) UAV multi-source data fusion improved alfalfa AGB estimation accuracy, although the enhancement diminished with the increasing number of sensor types. (ii) The stacking model consistently outperformed RFR, GBDT, KNN, and SVR regression models across all feature fusion combinations. It achieved high accuracy with R2 of 0.86–0.88, RMSE of 80.06–86.87 g/m2, and MAE of 60.24–62.69 g/m2. Notably, the stacking model based on only RGB imagery features mitigated the accuracy loss from limited types of features, potentially reducing equipment costs. This study demonstrated the potential of UAV in improving vegetation restoration management of coal waste dumps after reclamation. [ABSTRACT FROM AUTHOR]

Epithelioid inflammatory myofibroblastic sarcoma (EIMS) is an aggressive subtype of inflammatory myofibroblastic tumour which rarely affects the chest cavity. We, for the first time, report a case of mediastinal EIMS with the EML4-ALK fusion. A young woman presented to our hospital with cough, chest tightness and shortness of breath. Computed tomography (CT) showed a mixed attenuation soft-tissue mass in the right middle and upper mediastinum. Negative results were obtained from bronchoscopy forceps biopsy and endobronchial ultrasound-guided transbronchial fine needle aspiration. CT-guided percutaneous biopsy was finally performed. However, due to the rapidly progressed EIMS that compressed the trachea and right main bronchus, the patient died of respiratory failure 1 day before diagnosis. EIMS progresses rapidly, and an early diagnosis is important. For mediastinal EIMS, CT-guided percutaneous biopsy may be useful. Next-generation sequencing of blood may be instructive to EIMS patients who are intolerant to invasive biopsy. [ABSTRACT FROM AUTHOR]

As a biodegradable polyester, the commercialized synthesis protocol of poly(ε-caprolactone) (PCL) under mild conditions is of great significance and attractive. Herein, the ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) using FeCl3 catalyst and benzyl alcohol (BnOH) as the initiator was developed. FeCl3 has been proved to be an efficient catalyst for the ROP of ε-CL under mild conditions. The conversion of ε-CL to PCL was 98.8% at 60 °C within 4 h, with number-average molecular weight (Mn) and dispersity (PDI) of 1.65 × 104 g/mol and 1.28, respectively. Moreover, a coordination-insertion ring-opening polymerization mechanism mediated by FeCl3 was proposed. Overall, this work is expected to provide a feasible industrial method for the preparation of PCL from the direct aerobic oxidation of cyclohexanone. [ABSTRACT FROM AUTHOR]

Despite rapid progress and wide applications of room temperature phosphorescence (RTP) materials, it is still a great challenge to optimize the RTP activity through rational structural design at a molecular level. Herein, a successful cationic engineering strategy is demonstrated to modulate the crystal flexibility achieving controllable RTP in a new pair of metal halides [APML]ZnCl4 ([APML] = N‐(3‐Aminopropyl)morpholine) and [AEML]ZnCl4 ([AEML] = N‐(2‐Aminoethyl)morpholine). Both halides display blue fluorescence under 365 nm UV. Comparing with longer [APML]+, shorter [AEML]+ significantly enhances crystal rigidity and restrains non‐radiative scattering, boosting photoluminescence quantum yield (PLQY) from 18.89% to 22.41%. Synchronously, enhanced crystal rigidity significantly promotes the inter‐system crossing from singlet to triplet excited states. As a consequence, [AEML]ZnCl4 displays long‐lived green RTP property with millisecond scale lifetime in contrast to the blank RTP activity of [APML]ZnCl4. Comprehensive investigations demonstrate that the energy transfer between inorganic and organic components greatly changes the redistribution of singlet and triplet excited states, resulting in distinct phosphorescence activity. The different short‐lived blue fluorescence and long‐lived green phosphorescence provide a color‐time‐dual‐resolved luminescent tag with advanced applications in anti‐counterfeiting, etc. This work highlights a new structural engineering strategy to achieve controllable RTP affording a guide to rationally design RTP materials. [ABSTRACT FROM AUTHOR]

Although the luminescent performance of organic–inorganic metal halides (OIMHs) have obtained significant advances, achieving intrinsic water‐stable OIMHs remain a substantial challenge due to the fragile ionic nature of hybrid the halide structure. To overcome these challenges, a structural design strategy is proposed that involves the use of highly hydrophobic cations as a protective layer to improve the water stability of OIMH. Herein, an aprotic trimethylsulfoxonium [TMSO]+ is selected as a hydrophobic cation and successfully assemble two new manganese based OIMHs of (TMSO)MnCl3 and (TMSO)MnBr3 through facile solid and liquid phase reaction methods. Remarkably, these halides exhibit strong red light emissions with high quantum yields recorded at 86.1% and 53.4%, respectively, originating from the octahedral [MnX6]4− based one‐dimensional (1D) [MnX3]− chain. Most significantly, these halides present extraordinary structural and luminescent stabilities toward continuous corrosion by humid air, water, and acid‐aqueous solution for more than one month, suggesting promising application prospects in extreme chemical environments. In‐depth Hirshfeld surface calculations demonstrate that the ultrahigh water‐stability benefits from the abundant hydrogen bonds and strong electrostatic interactions between [TMSO]+ and [MnX3]− ions, which provides an underlying insight into the stability mechanism. This water‐stability enhancement strategy represents a breakthrough structural engineering to rationally design more water‐stable OIMH. [ABSTRACT FROM AUTHOR]

[Display omitted] • A new 3-D bi-metal organic framework was synthesized by hydrothermal method. • After pyrolysis, binary metal oxides were prepared and applied to the anode materials of LIBs. • CeCo-700 has the highest specific capacity of 952 mAh g−1 at 100 mA g−1 after 150 cycles. Precursor method is a well-known technology for preparing certain functional materials. In this work, a novel 3d-4f bimetallic organic framework, denoted as 45MCeCo (45 M representing 4,5-imidazole dicarboxylic acid), was successfully synthesized via a hydrothermal technique. The compound thus obtained has the molecular formula of C 10 H 11 CeCoN 4 O 12. By meticulously controlling the amounts of the experimental materials, it was feasible to prepare flower-like crystals possessing identical single crystal structures and significantly larger specific surface areas. As a precursor for electrode materials, this structure underwent calcination at different temperatures to prepare Co 3 O 4 /CeO 2 composites with in situ composite heterostructures. Post-electrochemical tests revealed that CeO 2 remains unreactive across all potentials, thereby contributing to the stabilization of the electrode material structure. In contrast, Co 3 O 4 participated in redox reactions to provide a specific capacity to the sample. In addition, when comparing the performance of the electrode material under different calcination conditions, it became evident that the material exhibited optimal electrochemical performance when subjected to a temperature of 700 °C for 2 h. [ABSTRACT FROM AUTHOR]

Considering the instability and toxicity of 3D Pb-based perovskite nanocrystals, lead-free low-dimensional organic–inorganic hybrid metal halides have attracted widespread attention as potential substitutes. Herein, two new tin-based 0D halides [H4BAPP]SnBr5·Br and [H4BAPP]SnCl5·Cl·H2O (BAPP = 1,4-bis(3-aminopropyl)piperazine) were synthesized successfully based on [SnX5]3− as an emission center. Typically, [H4BAPP]SnBr5·Br and [H4BAPP]SnCl5·Cl·H2O display broadband yellow and yellow-green light emissions originating from the radiative recombination of self-trapped excitons (STEs). The photoluminescence quantum yields (PLQYs) of the two compounds were calculated to be 19.27% and 2.36%, respectively. Furthermore, the excellent chemical and thermal stability and broadband light emissions reveal their potential application in solid-state white lighting diodes. [ABSTRACT FROM AUTHOR]

Environmentally friendly and highly efficient blue luminescent materials are an unremitting pursuit in the optoelectronic field. Herein, we assembled a new 0D lead-free metal halide of (F-PPA)ZnBr4, which exhibits narrow blue light emission with a remarkable PLQY of 50.15%, high stability and high detection sensitivity toward UV light. These results indicate the potential for the application of low-dimensional zinc-based halides in multiple optoelectronic devices. [ABSTRACT FROM AUTHOR]

Background and Objectives: To evaluate the potential benefits of Bacteroides fragilis 839 (BF839), a next-generation probiotics, in reducing myelosuppression and gastrointestinal toxicity associated with chemotherapy in breast cancer patient. Methods and Study Design: 40 women with early breast cancer were randomly assigned to the BF839 (n=20) or placebo (n=20) during the administration of adjuvant chemotherapy (4 cycles of epirubicin 100mg/m² and cyclophosphamide 600mg/m² ). Myelosuppression and gastrointestinal adverse effects were monitored in both groups. Results: Throughout the four treatment cycles, the percentage of patients experiencing myelosuppression was 42.5% in the BF839 group, significantly lower than the 66.3% observed in the control group (p=0.003). Two patients in the BF839 group and three patients in the placebo group received recombinant human granulocyte colony-stimulating factor (rhG-CSF) due to leukopenia/neutropenia. When considering an ITT analysis, which included all patients regardless of rhG-CSF treatment, the BF839 group exhibited less reduction from baseline in white blood cells (-0.31±1.19 vs -1.15±0.77, p=0.012) and neutrophils (0.06±1.00 vs - 0.84±0.85, p=0.004) compared to the placebo group. The difference became even more significant when excluding the patients who received rhG-CSF injections. Throughout the four treatment cycles, compared to the placebo group, the BF839 group had significantly lower rates of 3-4 grade nausea (35.0% vs 71.3%, p=0.001), vomiting (20.0% vs 45.0%, p=0.001), and diarrhea (15.0% vs 30.0%, p=0.023). Conclusions: These findings suggest that BF839 has the potential to effectively mitigate myelosuppression and gastrointestinal toxicity associated with chemotherapy in breast cancer patients. [ABSTRACT FROM AUTHOR]

Surface mining has been subject to increased criticism and pressure due to its potential to cause environmental damage. China accounts for more than half of world coal consumption, and this continued demand for coal, combined with low costs, has accelerated surface coal mining worldwide. However, it isn't easy to understand the impact of surface mining in China. Therefore, combined with POI, the Exposed Coal Frequency Index (ECFI) was constructed without any mining information in China. A LandTrendr algorithm was used to identify past mining disturbances and reclamation events (1986–2021). While examining these events, surface destruction due to coal mining in China was revealed. Based on the results, (1) the detection accuracy of statistical surface mining sites by province reaches 91.8%, while the detection accuracy of disturbance and reclamation events exceeds 72.59 %. Also, by comparing the mine data, our results provide more accurate information regarding both time and spatial consistency. (2) 253.61 km2 of surface mining sites were identified in 14 provinces or autonomous regions during 1986–2021. Of these, Inner Mongolia, Ningxia, Shanxi and Xinjiang ranked in the top four occupying 89.0% of the total mining site. (3) China has cumulatively disturbed 545.84 km2 and reclaimed 169.41 km2 including more comprehensive human activities. In the last 12 years, large-scale mining and reclamation have accounted for 51.63% and 75.17% of the cumulative area, respectively. (4) Generally, reclamation in China can be completed within four years. In contrast, reclamation time intervals and the proportion of reclamation varied widely between mining areas. Clearly, this study provides the most accurate data on surface coal mining disturbances in China, which will be beneficial for future studies in spatial geography related to mining. It also includes more policies and management creation for mines. [Display omitted] [ABSTRACT FROM AUTHOR]

Grain boundary engineering (GBE) can effectively improve the corrosion resistance of materials, but the traditional thermal-mechanical process still exhibits some limitations. In the present work, a novel surface spinning strengthening (3 S) technology followed by heat treatment was applied to modify the microstructure near the surface (∼ 400 μm) of a high-N Ni-free austenitic stainless steel. Under an optimal condition of annealing at 1323 K for 60 min after 3 S, the fraction of special boundaries mainly involving Σ3 boundaries in GBE layer was significantly improved from 48.3 % to 69.1 %, thus achieving excellent resistances to intergranular corrosion and stress corrosion cracking. • Surface spinning strengthening technology followed by heat treatment was proposed forward as an effective surface GBE process. • Surface GBE markedly improves corrosion resistance while remaining mechanical strength. • Surface GBE introduces a high fraction of Σ3n boundaries in surface layer and diminishes random high-angle GB connectivity. • Σ3 boundaries greatly hinder the propagation of corrosion cracks along GBs. [ABSTRACT FROM AUTHOR]

Organic-inorganic hybrid low-dimensional metal halides have been widely studied as a new class of luminescence materials due to abundant structural diversity and intriguing photophysical property. Herein, we explored two new Cd-based 0D halides of [BHEPZ]CdBr 4 (BHEPZ = 1,4-Bis(2-hydroxyethyl) piperazine) and [EPIPZ]CdBr 4 (EPIPZ = 1-ethylpiperazine) through facile wet-chemistry method. These 0D halides exhibit blue light emissions derived from radiative recombination of self-trapped excitons (STEs) based on detailed spectroscopy investigations. More interestingly, [BHEPZ]CdBr 4 exhibits rapid luminescence off switching toward benzaldehyde but fails in any other organic solvents. In-depth investigations demonstrate that the detection limit can fall to 2.65 ppm indicating perfect real-time fluorescent probe to detect benzaldehyde with high sensitivity and selectivity. This work enriches the cadmium halide materials and provide a new perspective for potential applications of 0D hybrid metal halides. Two Cd-based 0D halides were designed as blue light emitters from self-trapped excitons (STEs) with high thermal stability. Significantly, this halide displays fluorescence detection ability toward benzaldehyde with high selectivity, sensitivity and stability. [Display omitted] • Two 0D hybrid cadmium halides based on discrete [CdBr 4 ]2- clusters were synthesized. • The halides exhibits excellent chemical and thermal stabilities. • [BHEPZ]CdBr 4 can be explored as a good fluorescence sensor for benzaldehyde. [ABSTRACT FROM AUTHOR]

Intensive anthropogenic activities have led to drastic changes in land use/land cover (LULC) and impacted the carbon storage in high-groundwater coal basins. In this paper, we conduct a case study on the Yanzhou Coalfield in Shandong Province of China. We further classify waterbodies by using the Google Earth Engine (GEE) to better investigate the process of LULC transformation and the forces driving it in four periods from 1985 to 2020 (i.e., 1985–1995, 1995–2005, 2005–2015, and 2015–2020). We modeled the spatiotemporal dynamics of carbon storage by using InVEST based on the transformation in LULC and its drivers, including mining (M), reclamation (R), urbanization and village relocation (U), and ecological restoration (E). The results indicate that carbon storage had depleted by 19.69 % (321099.06 Mg) owing to intensive transformations in LULC. The area of cropland shrank with the expansion of built-up land and waterbodies, and 56.31 % of the study area underwent transitions in land use in the study period. U was the primary driver of carbon loss while E was the leading driver of carbon gain. While the direct impact of M on carbon loss accounted for only 5.23 % of the total, it affected urbanization and led to village relocation. R led to the recovery of cropland and the reclamation of water for aquaculture, which in turn improved the efficiency of land use. However, it contributed only 2.09 % to the total increase in carbon storage. Numerous complicated and intertwined processes (211) drove the changes in carbon storage in the study area. The work here provides valuable information for decision-makers as well as people involved in reclamation and ecological restoration to better understand the link between carbon storage and the forces influencing it. The results can be used to integrate the goals of carbon sequestration into measures for land management. [Display omitted] • The carbon storage impacted by LULC driving processes in high groundwater coal basins was investigated. • 56.31 % of the study area has undergone land use transition during 1985–2020. • The carbon storage decreased by19.69 % during the study years. • Urbanization and village relocation was the primary driver of carbon loss, ecological restoration was the leading driver of carbon gain. [ABSTRACT FROM AUTHOR]

Lifestyle interventions have been widely used to manage obesity, but their effects vary across individuals. Personality traits have increasingly drawn researchers' interest in exploring their role in obesity interventions, but study findings remain mixed. We aimed to systematically review and assess the associations between personality traits and the response to lifestyle-based obesity interventions for adult obesity. We searched PubMed, EMBASE, the Cochrane Central Register of Controlled Trials, Web of Science, PsycINFO, Scopus, Clinicaltrials.gov registry, and MedRxiv until February 8, 2023, and studies were screened as per the Preferred Reporting Items for Systematic Review and Meta-analysis (PRISMA) guidelines. We grouped personality traits into 5 superordinate traits according to the widely used Five-Factor model (FFM) and synthesized the results within each superordinate trait quantitatively (using meta-analyses) or narratively. We also used bubble plots to visualize patterns and trends within the results. We identified 3289 records and ultimately included 9 eligible studies in this review. We found that high conscientiousness tended to be positively associated with the response to lifestyle interventions for adult obesity and that low novelty seeking might be the main subordinate trait belonging to conscientiousness that was related to the intervention effect. Most of the included studies were rated as having a risk of bias due to inadequacy in comparisons of baseline characteristics or a short follow-up. Overall, studies included in this review are scarce, and more high-quality research of the present topic is urgently needed to inform individualized interventions for adult obesity stratified by personality traits. • High conscientiousness tended to be positively associated with the response to lifestyle interventions for adult obesity. • Low novelty seeking might be the main facet of Conscientiousness that was related to the intervention effect. • Studies in this field were still scarce in both quantity and quality. [ABSTRACT FROM AUTHOR]

Faced with a global biodiversity crisis, we need to concentrate our collective efforts on safeguarding Key Biodiversity Areas (KBAs), which serve as essential habitats for the world's threatened species. Clarifying the disturbance and protection requirements of KBAs is vital to the global persistence of biodiversity, which is not yet clear. Here, we evaluated the extent and severity of human disturbance in KBAs. Specifically, we analyzed the spatial patterns of disturbance and their potential effects on habitats. Roughly a quarter of terrestrial KBAs are challenged by crop production and urban construction activities, especially in Europe. The mean Human Footprint Index (HFI) for KBAs worldwide is 12.3, indicating a high level of human disturbance. On average, 62 % of each KBA is identified as Human Threatened Areas, signifying intense human impacts on these areas. 57 % of KBAs are subdivided by human disturbance, which can lead to substantial habitat fragmentation and loss of connectivity compared to other forms of disturbance. The halving of mean patch size and the tripling of the perimeter-area ratio for active habitats in KBAs provide evidence of the difficulties faced in conserving these areas. More importantly, increased coverage of Protected Areas fails to reduce HFI in KBAs, indicating some deficiencies in current protection systems. Therefore, we emphasize the importance of focusing on disturbance patterns for more impactful interventions, which potentially offer new pathways to mitigate adverse habitat impacts in post-2020 biodiversity conservation efforts. [Display omitted] • A quarter of KBAs are challenged by crop production and urban construction activities. • An average Human Footprint Index of 12.3 means high human disturbance in KBAs. • 57 % of KBAs are impacted by subdivision-related human disturbance. • A tripling of active habitats' perimeter-area ratio signals a high challenge in KBA protection • A method is explored to identify spatial patterns of human disturbance. [ABSTRACT FROM AUTHOR]

• Two novel systems, namely EHP-FC and FC-EHP were proposed to achieve fuel cell system performance enhancement. • A BPNN model with a topology of 7-10-3 was established for multi-objective optimization. • Synchronized optimization of system economy, environment impact, and power generation performance were achieved based on NSGA-Ⅱ. • The system optimal solution was selected based on LINMAP and TOPSIS multi-attribute decision-making methods. In this work, two methanol-reforming gas fuel cell systems coupled with an electrochemical hydrogen pump (EHP), namely, EHP pre-coupling and post-coupling fuel cell systems were proposed to achieve performance enhancement. A back propagation neural network surrogate model was established for the two systems to accurately describe system behavior, and a second-generation multi-objective non-dominated genetic algorithm was utilized for addressing the multi-objective optimization problem encompassing net output power, carbon mass-specific emission and the levelized cost of electricity. The linear non-weighted multi-attribute preference and technique for order preference by similarity to ideal solution multi-attribute decision-making methods were employed to select the optimal solutions. The optimized EHP pre-coupling fuel cell system exhibited lower carbon emissions (0.69 kgCO 2 /(kW·h)) and higher net output power (126.02 kW) compared to previous studies. While the EHP post-coupling system achieves a lower levelized cost of electricity (0.36 USD/(kW·h)), and stronger system stability (total efficiency reduction less 1 %). Both EHP-coupling systems offer viable process enhancements for fuel cell systems. [ABSTRACT FROM AUTHOR]