Gupta, S., Yelle, R. V., Schneider, N. M., Jain, S. K., Braude, A. S., Verdier, L., Montmessin, F., Nakagawa, H., Mayyasi, M., Deighan, J., and Curry, S. M.
We use the extensive stellar occultation data set of the Imaging Ultraviolet Spectrograph aboard the Mars Atmosphere and Volatile EvolutioN spacecraft to determine the first quantification of vertical variation in O2 mole fraction separately for day and night in the ∼90–130 km altitude range. The upper atmospheric O2 variation is expected to be due to the interplay between diffusion and advection because of its long photochemical lifetime. It is therefore a useful tracer of the state of atmospheric mixing and circulation. The altitude‐averaged mixing ratio is measured to be 2.69(±0.03) × 10−3 for the nightside and 2.05(±0.03) × 10−3 for the dayside. The average O2 mole fraction for day and night are nearly identical below 105 km, consistent with the value of 1.61 × 10−3 derived from the Mars Curiosity Rover/Sample Analysis at Mars near‐surface measurements. At higher altitudes, dominated by molecular diffusive separation, the measured O2 mole fraction demonstrates a vertical gradient with a local time dependence. The nightside mole fraction is a factor of 1.37 ± 0.04 larger than the dayside value at ∼125 km. This nightside enhancement is explained in terms of the relative role of solar‐driven rapid horizontal winds at high altitudes and slower vertical diffusion, resulting in a nightside (dayside) downward (upward) diffusive flux. Using the 1‐D diffusion model, the measured profiles correspond to a vertical eddy diffusion coefficient K = 3.5(±1.5) × 106 cm2/s. The Mars Climate Database predicts comparable but lower day‐night differences in oxygen mole fraction due to an overestimated K = 7.0(±1.0) × 106 cm2/s, which affects atmospheric mixing as well as the rate of atmospheric escape to space. Plain Language Summary: Molecular oxygen in the martian atmosphere is produced photochemically and behaves like an inert trace gas due to its long photochemical lifetime (∼60 Earth years). Its variations in the upper atmosphere are therefore governed by diffusion and dynamics and are indicative of the changes in atmospheric mixing and circulation. Other data sets have only provided a glimpse of O2 abundance in the upper atmosphere due to limited spatial and temporal coverage. The extensive stellar occultation data set of the Imaging Ultraviolet Spectrograph aboard the Mars Atmosphere and Volatile EvolutioN spacecraft can help fill this knowledge gap. This study shows the first quantification of vertical variation in O2 mixing ratio separately for day and night in the ∼90–130 km altitude range. While the day and night O2 mixing ratio is measured to be identical below 105 km in the well‐mixed atmosphere, significant local time dependence is seen under molecular diffusive separation, with a nightside enhancement and a dayside depletion. This is explained in terms of diffusive flux from the dayside to the nightside. However, the Mars Climate Database output is inconsistent with these measurements, which therefore have important implications for how species diffuse through the martian atmosphere and escape to space. Key Points: Stellar occultations observed by Mars Atmosphere and Volatile EvolutioN/Imaging Ultraviolet Spectrograph allow the most complete study of molecular oxygen in the upper atmosphereSignificant day/night differences reveal the importance of diurnal circulation and molecular diffusionObserved day/night differences exceed those in models, suggesting mixing is significantly overestimated in those models [ABSTRACT FROM AUTHOR]