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A dominating set of a graph is a subset of vertices such that every vertex not in the subset has at least one neighbor within the subset. The corresponding optimization problem is known to be NP-hard. It is proved to be beneficial to separate the solution process in two stages. First, one can apply a fast greedy algorithm to obtain an initial dominating set and then use an iterative procedure to purify (reduce) the size of this dominating set. In this work, we develop the purification stage and propose new purification algorithms. The purification procedures that we present here outperform, in practice, the earlier known purification procedure. We have tested our algorithms for over 1300 benchmark problem instances. Compared to the estimations due to known upper bounds, the obtained solutions are about seven times better. Remarkably, for the 500 benchmark instances for which the optimum is known, the optimal solutions are obtained for 46.33% of the tested instances, whereas the average error for the remaining instances is about 1.01. [ABSTRACT FROM AUTHOR]