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This study is focused on the synthesis of a solar light driven novel poly(vinyl alcohol) (PVA)-assisted TiO2/Ti film via a facile one pot hydrothermal technique and then its photocatalytic applications by adding with peroxymonosulfate (PMS) for efficient degradation of ciprofloxacin (CIP). The key hydrothermal synthesis parameters like PVA-content, hydrothermal time (HT), and pH were optimized. The best photocatalytic performance of the synthesized material was observed when prepared with the conditions of PVA = 8 mg, HT= 3 h, and pH = 2.62. Results showed that 98.3% of CIP was degraded within 60 min by PVA-assisted TiO2/Ti film with 0.5 mM PMS added, compared to 89.38% and 88.86% degradation with 0.5 mM persulfate (PS) and 0.5 mM hydrogen peroxide (H2O2), respectively. The photocatalytic degradation of CIP by PVA-assisted TiO2/Ti film with PMS added was dependent on the [PMS]0and increased with increase in [PMS]0. The kappvalues at [PMS]0of 0.2, 0.5, 0.8, and 1.0 mM were 0.029, 0.0582, 0.068, and 0.128 min–1, respectively. The photocatalytic degradation of CIP by PVA-assisted TiO2/Ti film with PMS added under solar light irradiation was highly dependent on the [pH]0as well as on the presence of coexisting anions like HCO3–, CO32–, NO2–, Cl–, and SO42–. Natural organic matter (NOM) retarded the photocatalytic degradation of CIP by PVA-assisted TiO2/Ti film with PMS added under solar light irradiation due to its strong scavenging ability toward •OH and SO4•–. The photocatalytic degradation of CIP by as-prepared photocatalyst under solar light irradiation was higher in Milli-Q water (kapp= 0.0582 min–1) than tap water (kapp= 0.0342 min–1) followed by river water (kapp= 0.0259 min–1) and then synthetic wastewater (kapp= 0.0212 min–1). The degradation products of CIP were investigated by UPLC-MS/MS, and accordingly degradation pathways were proposed. Moreover, the mineralization, ecotoxicity, and cyclic photocatalytic stability of the as-prepared photocatalyst were also investigated. These findings suggest that as-prepared PVA-assisted TiO2/Ti film with PMS added is a promising alternative for the treatment of wastewater containing antibiotics.