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Deuterium fractionation is a well-established evolutionary tracer in low-mass star formation, but its applicability to the high-mass regime remains an open question. The abundances and ratios of deuterated species have often been proposed as reliable evolutionary indicators for different stages of the high-mass star formation. We investigate the role of N$_2$H$^+$ and key deuterated molecules as tracers of the different stages of the high-mass star formation, and test whether their abundance ratios can serve as reliable evolutionary indicators. We conducted APEX observations of o-H$_2$D$^+$ (1$_{10}$-1$_{11}$), N$_2$H$^+$ (4-3), and N$_2$d$^+$ (3-2) in 40 high-mass clumps at different evolutionary stages, selected from the ATLASGAL survey. Molecular column densities ($N$) and abundances ($X$), were derived through spectral line modelling, both under local thermodynamic equilibrium (LTE) and non-LTE conditions. The $N$(o-H$_2$D$^+$) show the smallest deviation from LTE results when derived under non-LTE assumptions. In contrast, N$_2$D$^+$ shows the largest discrepancy between the $N$ derived from LTE and non-LTE. In all the cases discussed, we found that $X$(o-H$_2$D$^+$) decreases more significantly with time than in the case of $X$(N$_2$D$^+$); whereas $X$(N$_2$H$^+$) increases slightly. Therefore, the validity of the recently proposed $X$(o-H$_2$D$^+$)/$X$(N$_2$D$^+$) ratio as a reliable evolutionary indicator was not observed for this sample. While the deuteration fraction derived from N$_2$D$^+$ and N$_2$H$^+$ clearly decreases with clump evolution, the interpretation of this trend is complex, given the different distribution of the two tracers. Our results suggest that a careful consideration of the observational biases and beam-dilution effects are crucial for an accurate interpretation of the evolution of the deuteration process during the high-mass star formation process., Comment: 13 pages, 5 figures, 3 tables. Accepted for publication in A&A

ALMA-IMF observed 15 massive protoclusters capturing multiple spectral lines and the continuum emission. We focus on the G351.77 protocluster ($\sim$ 2500 M$_{\odot}$, estimated from single-dish continuum observations) located at 2 kpc. We trace the dense gas emission and kinematics with N$_2$H$^+$ (1-0) at $\sim$ 4 kau resolution. We estimate an N$_2$H$^+$ relative abundance $\sim (1.7 \pm 0.5) \times 10^{-10}$. We decompose the N$_2$H$^+$ emission into up to two velocity components, highlighting the kinematic complexity in the dense gas. By examining the position-velocity (PV) diagrams on small scales, we observe clear inflow signatures (V-shapes) associated with dense cores. The most prominent V-shape has a mass inflow rate of $\sim 9.8 \times 10^{-4}$ M$_{\odot}$ yr$^{-1}$ and a short timescale of $\sim$ 15.6 kyr. We also observe V-shapes without associated cores. This suggests both that cores or centers of accretion exist below the 1.3 mm detection limit, and that the V-shapes may be viable tracers of very early accretion and star formation on $\sim$ 4 kau scales. The large-scale PV diagram shows that the protocluster is separated into 2 principal velocity structures. Combined with smaller scale DCN and H$_2$CO emission, we propose a scenario of larger scale slow contraction with rotation in the center based on simple toy models. This scenario leads the suggestion of outside-in evolution of the protocluster as it collapses. The gas depletion times implied by the V-shapes are short ($\sim$ 0.3 Myr), requiring either very fast cluster formation, and/or continuous mass feeding of the protocluster. The latter is possible via the Mother Filament G351.77 is forming out of. The similarities in the properties of G351.77 and the recently published work in G353.41 indicate that many of the physical conditions inferred via the ALMA-IMF N$_2$H$^+$ observations may be generic to protoclusters., Comment: Submitted in A&A, 28 pages, 31 figures, 4 interactive figures, 7 tables

The increasing number of observations towards different environments in the Milky Way, as well as theoretical and experimental works, are improving our knowledge of the astrochemical processes in the interstellar medium (ISM). In this chapter we report some of the main projects to study the chemical complexity and isotopic ratios across the Galaxy. High-sensitivity spectral surveys covering broad bandwidths towards Galactic Center molecular clouds (e.g. G+0.693-0.027) and star-forming regions (e.g. the hot core G31.41+0.31) are revealing very rich astrochemical reservoirs, which include molecules of prebiotic interest. At the same time, isotopic ratios (e.g. $^{12}$C/$^{13}$C and $^{14}$N/$^{15}$N) can give important information on the Galactic chemical evolution, as well as on chemical local processes due to the physical conditions of the molecular clouds. We also highlight the role of cosmic rays as a key agent affecting the interstellar chemistry described above., Comment: 9 pages, 1 figures - Chapter II of the National Congress of (proto-)Planetary Astrochemistry (CNAP II) Proceedings - Accepted for publication on MemSAIt, in print

The first generation of ELT instruments includes an optical-infrared high-resolution spectrograph, indicated as ELT-HIRES and recently christened ANDES (ArmazoNes high Dispersion Echelle Spectrograph). ANDES consists of three fibre-fed spectrographs ([U]BV, RIZ, YJH) providing a spectral resolution of $\sim$100,000 with a minimum simultaneous wavelength coverage of 0.4-1.8 $\mu$m with the goal of extending it to 0.35-2.4 $\mu$m with the addition of a U arm to the BV spectrograph and a separate K band spectrograph. It operates both in seeing- and diffraction-limited conditions and the fibre feeding allows several, interchangeable observing modes including a single conjugated adaptive optics module and a small diffraction-limited integral field unit in the NIR. Modularity and fibre-feeding allow ANDES to be placed partly on the ELT Nasmyth platform and partly in the Coud\'e room. ANDES has a wide range of groundbreaking science cases spanning nearly all areas of research in astrophysics and even fundamental physics. Among the top science cases, there are the detection of biosignatures from exoplanet atmospheres, finding the fingerprints of the first generation of stars, tests on the stability of Nature's fundamental couplings, and the direct detection of the cosmic acceleration. The ANDES project is carried forward by a large international consortium, composed of 35 Institutes from 13 countries, forming a team of almost 300 scientists and engineers which include the majority of the scientific and technical expertise in the field that can be found in ESO member states., Comment: SPIE astronomical telescope and instrumentation 2024, in press

We aim to determine the $^{14}$N/$^{15}$N and $^{12}$C/$^{13}$C ratios for HCN in six starless and prestellar cores and compare the results between the direct method using radiative transfer modeling and the indirect double isotope method assuming a fixed $^{12}$C/$^{13}$C ratio. We present IRAM 30m observations of the HCN 1-0, HCN 3-2, HC15N 1-0 and H13CN 1-0 transitions toward six embedded cores. The ${}^{14}$N/${}^{15}$N ratio was derived using both the indirect double isotope method and directly through non-local thermodynamic equilibrium (NLTE) 1D radiative transfer modeling of the HCN emission. The latter also provides the ${}^{12}$C/${}^{13}$C ratio, which we compared to the local interstellar value. The derived ${}^{14}$N/${}^{15}$N ratios using the indirect method are generally in the range of 300-550. This result could suggest an evolutionary trend in the nitrogen fractionation of HCN between starless cores and later stages of the star formation process. However, the direct method reveals lower fractionation ratios of around $\sim$250, mainly resulting from a lower ${}^{12}$C/${}^{13}$C ratio in the range $\sim$20-40, as compared to the local interstellar medium value of 68. This study reveals a significant difference between the nitrogen fractionation ratio in HCN derived using direct and indirect methods. This can influence the interpretation of the chemical evolution and reveal the pitfalls of the indirect double isotope method for fractionation studies. However, the direct method is challenging, as it requires well-constrained source models to produce accurate results. No trend in the nitrogen fractionation of HCN between earlier and later stages of the star formation process is evident when the results of the direct method are considered., Comment: Accepted for publication in A&A

Cosmic rays (CRs) heavily impact the chemistry and physics of cold and dense star-forming regions. However, characterising their ionisation rate is still challenging from an observational point of view. In the past, a few analytical formulas have been proposed to infer the cosmic-ray ionization rate $\zeta_2$ from molecular line observations. These have been derived from the chemical kinetics of the involved species, but they have not been validated using synthetic data processed with a standard observative pipeline. We aim to bridge this gap. We perform the radiative transfer on a set of three-dimensional magneto-hydrodynamical simulations of prestellar cores, exploring different initial $\zeta_2$, evolutionary stages, types of radiative transfer (e.g. assuming local-thermodynamic-equilibrium conditions), and telescope responses. We then compute the column densities of the involved tracers to determine $\zeta_2$, using, in particular, the equation proposed by Bovino et. al (2020) and by Caselli et al. (1998) both used nowadays. Our results confirm that the method of Bovino et al. (2020) accurately retrieves the actual $\zeta_2$ within a factor of $2-3$, in the physical conditions explored in our tests. Since we also explore a non-local thermodynamic equilibrium radiative transfer, this work indirectly offers insights into the excitation temperatures of common transitions at moderate volume densities ($n\approx 10^5 \, \rm cm^{-3}$). We have also performed a few tests using the formula proposed by Caselli et al. (1998), which overestimates the actual $\zeta_2$ by at least two orders of magnitudes. We also consider a new derivation of this method, which, however, still leads to large overestimates., Comment: Accepted for publication in A&A (15th Feb.)