1. Evidence for Local Symmetry Breaking in the Skyrmion-Hosting Ni2In-type Hexagonal Compounds
- Author
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Singh, Anupam K., Singh, Sanjay, Dubey, Krishna K., Devi, Parul, Das, Pritam, Etter, Martin, Grendal, Ola. G., Dejoie, Catherine, Fitch, Andrew, Senyshyn, Anatoliy, Lee, Seung-Cheol, Bhattacharjee, Satadeep, and Pandey, Dhananjai
- Subjects
Condensed Matter - Materials Science - Abstract
Dzyaloshinskii-Moriya interaction (DMI) plays a crucial role to stabilize the exotic topologically stable skyrmion spin-textures in the noncentrosymmetric crystals. The recent discovery of biskyrmions and skyrmions in the globally centrosymmetric crystals has raised debate about the role of the DMI in causing the spin textures, since DMI vanishes in such crystal structures. Theoretical studies, on the other hand, suggest non-vanishing DMI even if there is local inversion symmetry breaking in an otherwise globally centrosymmetric crystal structure. Motivated by such theoretical predictions, we present here the results of a systematic crystal structure study of two skyrmion-hosting Ni2In-type centrosymmetric hexagonal compounds, MnNiGa and MnPtGa, using the atomic pair distribution function (PDF) technique. Our result provides information about structural correlations in the short-range (SR), medium-range (MR) and long-range (LR) regimes simultaneously. The analysis of the experimental PDFs, obtained from high flux, high energy and high-Q synchrotron x-ray powder diffraction patterns, reveal that the local SR structure of both MnNiGa and MnPtGa compounds corresponds to the noncentrosymmetric trigonal space group P3m1, while the structure in the MR+LR regimes remains hexagonal in the centrosymmetric P63/mmc space group. These findings are also supported by theoretical DFT calculations. Our results in conjunction with the previous theoretical predictions, provide a rationale for the genesis of skyrmions in centrosymmetric materials in terms of non-vanishing DMI due to local inversion symmetry breaking. We believe that our findings would encourage a systematic search of skyrmionic textures and other topological phenomena in a vast family of centrosymmetric materials.
- Published
- 2024