1. Understanding of Lithium-ion battery degradation using multisine-based nonlinear characterization method.
- Author
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Fan, Chuanxin, Liu, Kailong, Zhu, Tao, and Peng, Qiao
- Subjects
- *
LITHIUM-ion batteries , *ELECTRODES , *VOLTAGE - Abstract
The nonlinearity of lithium-ion battery voltage response has been recently gained high attention in battery characterization and health diagnosis. The multisine-based nonlinear characterization method has the potential for development as an expedient on-board technique for analyzing nonlinear responses. Despite this, it remains challenging to analyze the effect of aging degradation on LIB nonlinearity. In this study, the odd random-phase multisine method is performed on fresh and aged three-electrode experimental cells. This allowed for the separation of impedance-related linear approximation and odd or even order nonlinearity toward the full-cell voltage into their respective electrodes. The results demonstrate that, as the LIB degrades, the increase of impedance-related linear approximation estimated by the multisine-based method agrees well with the results of conventional EIS. The variation of nonlinearities is demonstrated in relation to the effect of degradation modes. The multisine-based method presents the advantage of simultaneously capturing impedance-related and nonlinearity information. This makes it become a fast diagnostic method that can be implemented in a BMS to quantify the causes of battery degradation, thereby supporting battery utilization optimization and future battery designs. • A multisine nonlinear characterization method is used to investigate LIB degradation. • A 3-electrode set-up is characterized for individual electrode degradation analysis. • Frequency domain response of individual electrodes is analyzed during cycle aging. • The nonlinearity in LIB voltage is demonstrated to provide degradation information. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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