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Owing to the occupying tendency of Mn4+ at octahedral sites, doping Mn4+ activators in tetrahedral structures poses challenges and hence is seldom reported. In this work, tetrahedrally sited Mn4+ phosphors were studied. By combining X-ray diffraction (XRD) data with Rietveld refinement analysis, the location of Mn4+ was determined. It was found that by adding excessive raw MgO, the phosphor synthesis temperature can be improved, enhancing the crystallinity of the crystal and thus improving the emission performance of the phosphor. In addition, excessive raw MgO forms a second phase in an LMGO matrix, which does not change the doping site for Mn4+. The Tanabe–Sugano diagram of Mn4+ in the tetrahedral field and the energy-level diagram of these phosphors were constructed for the first time, and the excitation and emission mechanisms are discussed in detail. With 1.2-fold excess of raw MgO, the prepared sample (LMGO-Mn-1.2) shows the best luminescence, demonstrating red emissions peaked at 656 nm and affording an emission intensity enhancement of over 50 times compared to a stoichiometric LMGO:Mn4+ system. At 150 °C, LMGO-Mn-1.2 keeps 90% emission intensity compared to that at room temperature. Finally, a high-efficiency warm white light–emitting diode was built. This work provides new insights into the study of Mn4+-activated phosphors in a tetrahedron crystal field. [ABSTRACT FROM AUTHOR]

The tail rotor of a helicopter, a crucial component, traditionally relies on a complex drive mode involving reducers and transmission gears. This conventional setup, with its lengthy transmission chain and numerous components, hinders miniaturization efforts. In response to this challenge, our paper presents a novel piezoelectric drive approach. Our objective was to suggest an innovative design capable of minimizing the components involved in the tail rotor drive. This design can be adjusted in size according to specific requirements and is effective up to a specified speed. Moreover, it facilitates the process of miniaturization and integration. The piezoelectric actuator's stator comprises an ultrasonic amplitude transformer, a ring, and three drive teeth. Utilizing the rod-like structure of the tail brace, the actuator is simplified by adhering ceramic sheets to it. The rotary piezoelectric actuator combines the first longitudinal mode of a rod with torus bending modes. The drive teeth then amplify the ring's displacement, facilitating rotor rotation. The resonant frequency and modal shape of the actuator were determined using the finite element method. Furthermore, an investigation was conducted to analyze the influence of the drive teeth positioning on the motion trajectory at the contact point. Theoretically, we infer that the declination angle of the drive tooth is a crucial parameter for achieving high speeds. To test our idea, we built three prototype stators with different drive tooth declination angles. Our actuator stands out for its cost-effectiveness, structural simplicity, compatibility with harmonic signals, and ease of miniaturization. It can be considered for the drive of the tail rotor of a microhelicopter. [ABSTRACT FROM AUTHOR]

Owing to the occupying tendency of Mn4+ at octahedral sites, doping Mn4+ activators in tetrahedral structures poses challenges and hence is seldom reported. In this work, tetrahedrally sited Mn4+ phosphors were studied. By combining X-ray diffraction (XRD) data with Rietveld refinement analysis, the location of Mn4+ was determined. It was found that by adding excessive raw MgO, the phosphor synthesis temperature can be improved, enhancing the crystallinity of the crystal and thus improving the emission performance of the phosphor. In addition, excessive raw MgO forms a second phase in an LMGO matrix, which does not change the doping site for Mn4+. The Tanabe–Sugano diagram of Mn4+ in the tetrahedral field and the energy-level diagram of these phosphors were constructed for the first time, and the excitation and emission mechanisms are discussed in detail. With 1.2-fold excess of raw MgO, the prepared sample (LMGO-Mn-1.2) shows the best luminescence, demonstrating red emissions peaked at 656 nm and affording an emission intensity enhancement of over 50 times compared to a stoichiometric LMGO:Mn4+ system. At 150 °C, LMGO-Mn-1.2 keeps 90% emission intensity compared to that at room temperature. Finally, a high-efficiency warm white light–emitting diode was built. This work provides new insights into the study of Mn4+-activated phosphors in a tetrahedron crystal field. [ABSTRACT FROM AUTHOR]

Owing to the occupying tendency of Mn 4+ at octahedral sites, doping Mn 4+ activators in tetrahedral structures poses challenges and hence is seldom reported. In this work, tetrahedrally sited Mn 4+ phosphors were studied. By combining X-ray diffraction (XRD) data with Rietveld refinement analysis, the location of Mn 4+ was determined. It was found that by adding excessive raw MgO, the phosphor synthesis temperature can be improved, enhancing the crystallinity of the crystal and thus improving the emission performance of the phosphor. In addition, excessive raw MgO forms a second phase in an LMGO matrix, which does not change the doping site for Mn 4+ . The Tanabe-Sugano diagram of Mn 4+ in the tetrahedral field and the energy-level diagram of these phosphors were constructed for the first time, and the excitation and emission mechanisms are discussed in detail. With 1.2-fold excess of raw MgO, the prepared sample (LMGO-Mn-1.2) shows the best luminescence, demonstrating red emissions peaked at 656 nm and affording an emission intensity enhancement of over 50 times compared to a stoichiometric LMGO:Mn 4+ system. At 150 °C, LMGO-Mn-1.2 keeps 90% emission intensity compared to that at room temperature. Finally, a high-efficiency warm white light-emitting diode was built. This work provides new insights into the study of Mn 4+ -activated phosphors in a tetrahedron crystal field.