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With an increase in environmental pollution and microplastic problems, it is more urgent now to replace non-biodegradable films with biodegradable films that are low-cost and from renewable resources. Cotton gin motes (GM), a type of cellulosic waste that is generated from cotton ginning, is an excellent candidate for fabricating biodegradable films due to its properties and abundance. In this study, GM was first mechanically milled into a fine powder, followed by compounding with polycaprolactone (PCL) and extruded to produce composite pellets which were then compress-moulded into composite films. This environmentally friendly process used physical processing and all the materials were consumed in the process without generating any waste residue. To improve the compatibility and mixing properties between GM and PCL, the use of a plasticiser (polyethylene glycol) was considered. A high content of GM powder (up to 50%) was successfully compounded with the polymer. The SEM images of the composite films showed smooth surface morphology and well-distributed GM powder in the PCL matrix. The added advantage of compounding GM with the polymer matrix was that the composite film developed UV-shielding properties due to the presence of lignin in the GM powder. This property will be critical for films used in UV-resistance applications. Furthermore, the composite even with high GM content (50%), showed good mechanical properties, with 9.5 MPa yield strength and 442% elongation, which was only a 50% decrease in elongation when compared with clear PCL film. The soil biodegradation of GM composite films under controlled temperature (20 °C) and humidity (50%) for 1 month showed around 41% weight loss. Overall, this study demonstrates the potential of GM to be used as a biodegradable and UV-protective composite film for a wide array of applications, such as packaging and UV-protective coverings. [ABSTRACT FROM AUTHOR]

N -methyl morpholine-N-oxide (NMMO) is the only commercialised solvent to dissolve cellulose and produce lyocell. However, the molecular mechanism of NMMO-induced cellulose solubilisation is unknown which limits further process development. In this work, and for the first time the complete dissolution process of a large cellulose bunch was simulated in NMMO monohydrate using long microsecond molecular dynamic simulations. The dissolution process was also simulated in 1-ethyl-3-methylimidazolium acetate (EmimAc) as an efficient ionic liquid in cellulose dissolution and the results were compared with the aqueous conditions. While the cellulose bunch showed a stable and insoluble structure in pure water, it was completely and efficiently dissolved in both NMMO monohydrate and EmimAc. It was shown that the dissolution time of cellulose in NMMO monohydrate is almost twice that in EmimAc, which is in agreement with the experimental observations. Although it is revealed that hydrogen bonding is the main driving force of cellulose dissolution in NMMO monohydrate, one cannot explain the complete molecular mechanism of NMMO-induced cellulose dissolution only by considering hydrogen bonds. A straightforward molecular mechanism was proposed, in which the interactions of NMMO molecules, not with cellulose, but with the other NMMO molecules play a critical role in the dissolution process. [Display omitted] [ABSTRACT FROM AUTHOR]