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Ultrafine noble metals have emerged as advanced nanocatalysts in modern society but still suffer from unavoidable sintering at temperatures above 250 °C (e.g., Pt). In this work, closely packed CeO 2 grains were confined elegantly in fibrous nanostructures and served as a porous support for stabilizing sub-3 nm Pt clusters. Through precisely manipulating the asymmetry of obtained nanofibers, uneven strain was induced within C-shaped CeO 2 nanofibers with tensile strain at the outer side and compressive strain at the inner side. As a result, the enriched oxygen vacancies significantly improved adhesion of Pt to CeO 2 , thereby boosting the sinter-resistance of ultraclose sub-3 nm Pt clusters. Notably, no aggregation was observed even after exposure to humid air at 750 °C for 12 h, which is far beyond their Tammann temperature (sintering onset temperature, below 250 °C). In situ HAADF-STEM observation revealed a unique sintering mechanism, wherein Pt clusters initially migrate toward the grain boundaries with concentrated stain and undergo slight coalescence, followed by subsequent Ostwald ripening at higher temperatures. Moreover, the sinter-resistant Pt/C-shaped CeO 2 effectively catalyzed soot combustion (over 700 °C) in a durable manner. This work provides a new insight for developing sinter-resistant catalysts from the perspective of strain engineering within nano-oxides.

Metal sintering poses significant challenges for developing reliable catalytic systems toward high-temperature reactions, particularly those based on metal clusters with sizes below 3 nm. In this work, electrospun dual-oxide fibril-in-tubes consisting of CeO 2 and Al 2 O 3 are rationally designed in an all-in-one manner, to stabilize 2.3 nm Pt clusters with a Tammann temperature (sintering onset temperature) lower than 250 °C. The abundant pores and channels effectively stabilize the Pt clusters physically, while the strong support, CeO 2 , with high adhesion, pins Pt clusters firmly, and the adjacent weak support, Al 2 O 3 , with low adhesion, provides energy barriers to prevent the clusters and emitted Pt atom(s) from moving across the support. Therefore, the ultra-close 2.3 nm Pt clusters, featuring an average nearest neighboring distance of only 2.1 nm, were carefully stabilized against sintering at temperatures exceeding 750 °C, even in oxidative and steam-containing environments. In addition, this catalytic system can efficiently and durably serve in diesel combustion, a high-temperature exothermic reaction, showing no activity decline after 5 cycles. This work provides a comprehensive understanding of sinter-resistant catalytic systems, and presents new insights for the development of advanced nanocatalysts., Competing Interests: The authors declare no competing interests., (This journal is © The Royal Society of Chemistry.)

Photothermal heating and photocatalytic treatment are two solar-driven water processing approaches by harnessing NIR and UV-vis light, respectively, which can fully utilize solar energy if integrated. However, it remains a challenge to achieve high performance in both approaches when integrated in a material due to uncontrollable heat diffusion. Here, we report a demonstration of heat confinement on photothermal sites and fluid cooling on photocatalysis sites at the nanoscale, within a well-designed heat and fluid confinement nanofiber reactor. Photothermal and photocatalytic nanostructures were alternatively aligned in electrospun nanofibers for on-demand nanofluidic thermal management as well as easy folding into 3D structures with enhanced light utilization and mass transfer. Such a design showed simultaneously high photothermal evaporation rate (2.59 kg m -2 h -1 , exceeding the limit rate) and efficient photocatalytic upcycling of microplastics pollutant into valued products. Enabled by controlled photothermal heating, the valued main product (i.e., methyl acetate) can be evaporated out with 100% selectivity by in situ separation., Competing Interests: Competing interests statement:The authors declare no competing interest.