Search

Your search keyword '"Concellón, Carmen"' showing total 1 results
Start Over Author "Concellón, Carmen" Publication Year Range This year

Refine your results

1 results on '"Concellón, Carmen"'

1. Organocatalytic CS 2 insertion into epoxides in neat conditions: a straightforward approach for the efficient synthesis of Di- and tri-thiocarbonates.

Author

López-Aguilar M, Ríos-Lombardía N, Gallegos M, Barrena-Espés D, García-Álvarez J, Concellón C, and Del Amo V

Abstract

The straightforward organocatalytic insertion of carbon disulfide (CS 2 ) into epoxides using either choline chloride ( ChCl ) or tetrabutylammonium chloride (TBACl) is reported, for the first time, under solvent-free (neat) conditions. Fine-tuning of our system allowed us to obtain either dithiocarbonates (DTCs) or trithiocarbonates (TTCs) with high efficiency. Additionally, a mechanistic proposal is presented, supported by experimental evidence, DFT calculations and wavefunction analyses.

Published
2025
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results