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Distinct types of luminescence that are activated by various stimuli in a single material offer exciting developmental opportunities for functional materials. A versatile sensing platform that exhibits photoluminescence (PL), persistent luminescence (PersL), and mechanoluminescence (ML) is introduced, which enables the sensitive detection of temperature, pressure, and force/stress. The developed Sr2MgSi2O7:Eu2+/Dy3+ material exhibits a linear relationship between ML intensity and force and can be used as an ML stress sensor. Additionally, the bandwidth of the PL emission band and the PL lifetime of this material are remarkably sensitive to temperature, with values of ≈0.05 nm K−1 and 1.29%/K, respectively. This study demonstrates PersL pressure sensing for the first time, using long‐lasting (seconds) lifetime as a manometric parameter. The developed material functions as an exceptionally sensitive triple‐mode visual pressure sensor; specifically, it exhibits: i) a sensitivity of ≈−297.4 cm GPa−1 (8.11 nm GPa−1) in bandshift mode, ii) a sensitivity of ≈272.7 cm−1/GPa (14.8 nm GPa−1) in bandwidth mode, and iii) a sensitivity of 42%GPa−1 in PL‐lifetime mode, which is the highest value reported to date. Notably, anti‐counterfeiting, night‐vision safety‐sign, 8‐bit optical‐coding, and QR‐code applications that exhibit intense PersL are demonstrated by 3D‐printing the studied material in combination with a polymer. [ABSTRACT FROM AUTHOR]

A comprehensive photoluminescence and mechanoluminescence analysis of a ZnS:Mn2+ nano-phosphor with a zinc blende structure is presented. The sample containing quantum dot-sized nanocrystallites was synthesized by the chemical precipitation method and shows excellent orange luminescence at ambient conditions related to the 4T1 → 6A1 transition. The sample shows stable and identical luminescence behavior under both UV and X-ray excitation at ambient conditions and also exhibits excellent self-powered mechanoluminescence properties. The pressure and temperature-induced luminescence mechanism of the phosphor is also established. The shift of the 4T1 → 6A1 luminescence band of Mn2+ with both pressure and temperature and the luminescence mechanism is explained via the d5 Tanabe Sugano diagram. The broad luminescence band of the 4T1 → 6A1 transition shifts from the visible to near-infrared range at a rate of −35.8 meV GPa−1 with the increase of the pressure and it is subsequently quenched completely at a pressure of 16.41 GPa due to a reversible phase transition from zinc blende (F4¯3m) to rocksalt (Fm3¯m) phase. The high-pressure and temperature-dependent decay kinetics measurements of the sample luminescence are also reported. [ABSTRACT FROM AUTHOR]