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The impact of the insertion of Pb2+ ions into the Li2O–BaO–B2O3 based glass matrix has been investigated. The Archimedes' method was used to determine the density (ρ) and, as a result, the molar volume (Vm) of the samples. The ρ of the glasses increased from 2.917 to 5.003 (g/cm3), and the Vm increased from 24.155 to 27.074 (cm3/mol). The optical band gap of the samples was determined based on their UV–visible spectra. The structural study of the present glasses has been carried out by XRD patterns and FTIR spectra analysis. Numerous theoretical methods were used to calculate some parameters such as ionic radius, optical basicity, non-linear refractive index, and oxide ion polarizability. The mass attenuation coefficient MAC was obtained experimentally as well as theoretically by the Phy-X/PSD software programs and the obtained results were in very good agreement. The half-value layer HVL, mean free path (MFP), effective atomic number (Zeff), atomic cross-sections and electron cross-sections were evaluated for all the present glass samples. In addition, exposure build-up factor and energy exposure build-up factor were estimated for each glass up to penetration depths of 40 MFP. Moreover, the effective neutron removal cross-section (ƩR) was also calculated. The shielding properties of the prepared glass samples were compared with different concrete shielding materials, and commercial glasses, therefore, the prepared glasses outperformed all the aforementioned materials in terms of gamma ray shielding ability. [ABSTRACT FROM AUTHOR]

In the present study, Sr0.7Bi0.2TiO3 is mixed with [(K0.5Bi0.5)(Mg1/3Nb2/3)O3] to form a solid solution of [(1 − x)SBT–x(KB)(MNb), x = 0.02, 0.04, 0.06, 0.1]. From the XRD results, it is indicated that KB is the main substituent for SBT ceramic at the A‐site. The breakdown strength (BDS) of ceramic gradually increases with an increase in doping content and achieves a high value of 280 kV/cm for x = 0.06. In addition, the 0.94SBT–0.06(KB)(MNb) ceramic shows excellent temperature stability (−55 to 140°C), a high recoverable energy density (Wd)—2.6 J/cm3, and an efficiency (η)—88% at 280 kV/cm. Therefore, 0.94SBT–0.06(KB)(MNb) ceramic is one of the possible materials for energy storage capacitor applications. [ABSTRACT FROM AUTHOR]

(1 − x)Sr0.7Bi0.2TiO3-xBi(Mg0.5Ce0.5)O3 (x = 0.02, 0.04, 0.06, and 0.1) ceramics were prepared through the solid-state reaction method. Structural, microstructural, dielectric, and energy storage characteristics were thoroughly examined. A dense microstructure with a single perovskite phase was obtained for x ≤ 0.06. A high energy storage density of ~ 1.86 J/cm3, recoverable energy density of ~ 1.67 J/cm3, and a high efficiency of ~ 90% at a breakdown electric field strength of 240 kV/cm were achieved for x = 0.06. Further, this composition also shows a ΔC/C25°C in the range of − 55 to 135 °C. The above characteristics indicate that this material is a suitable candidate for power-pulsed capacitor applications. [ABSTRACT FROM AUTHOR]

This study offers an extensive exploration into approaches for cultivating CsPbBr3 SCs using inverse temperature crystallization (ITC), with a specific focus on seed-induced (method (1)) and nucleation-mediated (method (2)) growth techniques. Our findings reveal that leveraging seed-assisted growth at lower temperatures yields noteworthy enhancements in the material's optical and electrical behaviors, outperforming the outcomes achieved through nucleation-driven growth. Concretely, through the employment of the space charge limited current (SCLC) technique, an evident contrast emerges in the trap-populated threshold voltage between the seed-facilitated crystal (SC1) (measuring 0.309 V) and its nucleation-facilitated counterpart (SC2) (measuring 1.513 V), consequently giving rise to discernable dissimilarities in trap density assessments. Evidence from temperature-dependent analysis of space charge limited currents substantiates these findings, revealing trap density values of 8.81 × 109 cm−3 for SC1, juxtaposed with 2.08 × 1010 cm−3 for SC2. Additionally, the SC1 displays a notably diminished trap energy level. Furthermore, the investigation underscores the affirmative influence of method (1) at lower temperatures on the optical and crystalline characteristics of the substance. This effect is evidenced by enhanced photoluminescence (PL) reactions and reduced lattice strain (Ls), as determined through X-ray diffraction (XRD) techniques. Moreover, the research establishes the substantial impact of this enhanced crystallization technique on the photodetector (PD) attributes of the crystal. This effect induces elevated levels of detectivity and responsivity for method (1). [ABSTRACT FROM AUTHOR]

In the pursuit of lead-free perovskite materials suitable for harnessing solar energy, a recent discovery has emerged regarding Cs 2 TiBr 6 . This compound has garnered attention as a prospective candidate, exhibiting favorable optical and electrical characteristics alongside exceptional resilience when subjected to environmental strains. This study details the successful synthesis of non-hazardous metal halide nanoparticles of Cs 2 TiBr 6 via the slow cooling method. Comprehensive investigations into the structural, optical, and dielectric characteristics have been undertaken. The temperature sensitivity of various electrical properties, including the dielectric constant, loss factor, electric modulus, and AC/DC conductivity, is evident in this perovskite material. This phenomenon is observed across a frequency range of 1 to 10 7 Hz. Furthermore, examination of the Nyquist plot highlights the distinctive contributions of both grain and grain boundaries to the overall impedance characteristics. In the high-frequency range, it is observed that the dielectric constant exhibits an upward trend as the temperature rises. Examination of the adapted Cole-Cole plot unveils that both space charge and free charge conductivity escalate with increasing temperature, while concurrently, the relaxation time experiences a reduction with the temperature's ascent. We observed an asymmetrical pattern in the electric modulus spectra at varying temperatures using a modified Kohlrausch-Williams-Watts equation. This asymmetry is consistent with the inherent non-Debye nature of perovskite materials. Additionally, as the temperature increases, we note a shift in the imaginary component of the electric modulus spectra, transitioning from a non-Debye character towards a semi-Debye nature, though it does not achieve a strictly Debye-type response. This transformation indicates the semiconducting properties of the material. We elucidate the AC conductivity behavior in Cs 2 TiBr 6 by employing the non-overlapping small-polaron tunneling (NSPT) mechanism as the basis. The activation energy, as determined from both the modulus spectra and DC conductivity, aligns closely, providing robust evidence for the congruence between the relaxation dynamics and the conduction mechanism. In addition to these attributes, Cs 2 TiBr 6 exhibits a substantial dielectric constant coupled with negligible dielectric loss, thus establishing its potential suitability for energy harvesting devices., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

This study offers an extensive exploration into approaches for cultivating CsPbBr 3 SCs using inverse temperature crystallization (ITC), with a specific focus on seed-induced (method (1)) and nucleation-mediated (method (2)) growth techniques. Our findings reveal that leveraging seed-assisted growth at lower temperatures yields noteworthy enhancements in the material's optical and electrical behaviors, outperforming the outcomes achieved through nucleation-driven growth. Concretely, through the employment of the space charge limited current (SCLC) technique, an evident contrast emerges in the trap-populated threshold voltage between the seed-facilitated crystal (SC 1 ) (measuring 0.309 V) and its nucleation-facilitated counterpart (SC 2 ) (measuring 1.513 V), consequently giving rise to discernable dissimilarities in trap density assessments. Evidence from temperature-dependent analysis of space charge limited currents substantiates these findings, revealing trap density values of 8.81 × 10 9 cm -3 for SC 1 , juxtaposed with 2.08 × 10 10 cm -3 for SC 2 . Additionally, the SC 1 displays a notably diminished trap energy level. Furthermore, the investigation underscores the affirmative influence of method (1) at lower temperatures on the optical and crystalline characteristics of the substance. This effect is evidenced by enhanced photoluminescence (PL) reactions and reduced lattice strain ( L s ), as determined through X-ray diffraction (XRD) techniques. Moreover, the research establishes the substantial impact of this enhanced crystallization technique on the photodetector (PD) attributes of the crystal. This effect induces elevated levels of detectivity and responsivity for method (1).