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Three‐dimensional multi‐axial warp knitted (3D MWK) reinforced composites are important components of advanced structural composites. The interfacial bonding between fiber and matrix is key to achieving high mechanical properties. In this work, graphene oxide (GO) and poly(oxypropylene) diamines (D400) were grafted on glass fiber (GF) multi‐axial warp knitted (MWK) fabrics to construct a "flexible‐rigid" structure. The surface morphologies of GF were characterized by SEM and EDS. Then, 3D MWK‐reinforced composites were prepared based on four kinds of modified fabrics using the VARTM method. The in‐plane compression properties were obtained at different high temperatures and their failure modes were analyzed. The strain–stress curves showed that the composites exhibited brittle fracture modes. D400 and GO‐modified multi‐scale composites exhibited outstanding compression properties. The strength of the related composited was improved by 55.78%, 76.78%, 52.19%, and 56.78% compared to that of desized composite at 30°C, 60°C, 120°C and 150°C, respectively. The damage to D400‐GO modified and D400 modified composites was the most serious, where shear fracture modes were obvious in addition to layer debonding features. This protocol provides a potential strategy to manufacture of D400 and GO‐modified hierarchical reinforced composites. Highlights: The modified 3D MWK glass fabrics based on poly(oxypropylene) diamines (D400) and graphene oxide (GO) were prepared.The compressive properties of 3D desized, D400‐, D400‐GO‐, and GO‐MWK fabrics reinforced epoxy composites were obtained and analyzed at different temperatures of 30°C, 60°C, 120°C, and 150°C.The failure mechanisms of 3D desized, D400‐, D400‐GO‐, and GO‐MWK fabrics reinforced epoxy composites at different temperatures were analyzed. [ABSTRACT FROM AUTHOR]

The present investigation targets the physical, mechanical, and thermal characteristics of glass fabric‐reinforced vinyl ester/polyester hybrid laminates filled with ferrous, nickel, and tungsten micro‐particles. The metal‐fillers‐glass fabric reinforced vinyl ester/polyester hybrid composites was produced by distributing 1 wt% ferrous, nickel, and tungsten with an ultrasonication probe‐assisted wet layup method. Polyester resin reinforced with glass fabrics and tungsten fillers (PRGT) presents improved mechanical characteristics compared with other hybrid laminates, with tensile, compression, and flexural strength values of 157.89 MPa, 163.74 MPa, and 167.29 MPa, respectively. The fractographic microstructure of tensile fracture PRGT laminates exhibits that glass fibers pull out, microcracks, and lower gaps, because of stronger filler‐fabric‐matrix adhesion when compared with other hybrid laminates. The artificial neural network modeling was conducted to choose the best composite among the various manufactured composites. Statistical analysis was observed from the one‐way ANOVA technique, substantiating that the physical, mechanical, and thermal characteristics of metal fillers‐reinforced hybrid composites were statistically significant. Highlights: Metal‐fillers‐glass fabric reinforced vinyl ester/polyester hybrid composites.Selection of the best composite from developed composites by ANN.Tungsten fillers are a useful material for reinforcement. [ABSTRACT FROM AUTHOR]

This research investigates the influence of kevlar and glass fiber reinforcements on the mechanical and thermal properties of epoxy/vinyl ester (hybrid resin) composite. The hybrid resin was synthesized by achieving an interpenetrating network between epoxy and vinyl ester. The composites were characterized using tensile, flexural, impact, and thermo‐gravimetric analysis (TGA). Scanning electron microscopy was employed to analyze surface morphology whereas Fourier‐Transformation Infrared Spectroscopy (FT‐IR) was used to investigate the possible interaction between the constituents of the composites. The findings have shown a notable improvement in the mechanical properties after the hybridization of the resin. For reference, the tensile strength of glass/hybrid resin and kevlar/hybrid resin composites were observed to increase by 8.33% and 23.65%, as compared to glass/epoxy and kevlar epoxy composites respectively, whereas, the bending strength of these composites was improved by 8.36% and 30.61%, respectively. TGA also showed an enhanced thermal stability of the hybrid resin‐based composites. Such improvements are noticed due to multi‐resin incorporation (the oxirane group of epoxy reacts with the hydroxyl group of vinyl ester), confirmed by the FTIR, TGA, and morphological analysis. This study signifies that the proposed hybrid composites are better in terms of strength and modulus relative to conventional metallic materials. Highlights: The paper presents the development of novel hybrid resin, reinforced with synthetic fibers.Hybrid resin is imparted positively and is highly favorable in improving the mechanical properties of composites.The tensile strength of novel composites is increased by 8.33% and 23.65% relative to their base specimens, and a similar trend is observed in flexural and impact analysis.Fractured analysis showed that composite laminates deteriorated more intensely due to cohesive matrix fracture; adhesion failure was not observed at all, as evidenced by the emergence of micro‐cracks in resin.Developed novel composites exhibited maximum thermal stability; residual char in glass/epoxy/vinyl‐ester composite attained 17.81% higher, whereas kevlar/epoxy/vinyl‐ester achieved 3.56% relative to glass/epoxy and kevlar/epoxy base samples. [ABSTRACT FROM AUTHOR]

This study focused on the wear behavior of unidirectional, thick GF epoxy composites produced using the autoclave method. The thermal aging process was applied for 250 and 500 cycles to understand the wear behavior of the material as it ages over time. To evaluate the wear behavior of the samples, wear tests were carried out under three different loads (10, 20, and 30 N) and three different sliding distances (150, 300, and 450 m). Taguchi‐based regression analysis was used to analyze the experimental results. The results obtained were evaluated using ANOVA tables and main and contour graphs. When the test results are examined, it is surprisingly observed that the wear resistance of the composite material increases positively with the aging effect. With thermally aging while the coefficient of friction value of composite samples increases from approximately 0.12 to 0.3, the wear volume decreases from approximately 4 to 1.3 mm3. Taguchi based regression analysis showed that the relationship between wear and thermal cycle sliding distance and load can be established by reducing the number of experiments in wear studies. Highlights: Thermal aging effect on wear properties of thick GFRP was determined.Minimum wear volume and COF values were determined by applying ANOVA.It was determined that a load increment has the most impact on wear volume.Worn surface images supported the reduction in the wear rates of the thick GFRP.Empirical regression models developed for the mathematical prediction. [ABSTRACT FROM AUTHOR]

The present research presents an examination of the consequential effects brought about by the introduction of short-cut E-glass fibers (GF) on the properties of high-dielectric constant, high-thermal conductivity microwave composite systems (x GF/(8- x)BNNS/78 wt%ST/polyolefin, x = 0-8 wt%, BNNS: hexagonal boron nitride nanosheets). The GF is modified using KH550, with the success of the surface modification definitively confirmed by X-ray Photoelectron Spectroscopy (XPS) and Fourier Transform infrared spectroscopy (FTIR). All components are found to exhibit consistently ultra-high and stable dielectric constants within the 8–12 GHz frequency range (D k = 17.7–18.08). Based on thermogravimetry analysis (TGA) and dynamic mechanical analysis (DMA) results, the incorporation of modified GF improve the thermal stability of the composite materials, enhancing thermal decomposition temperature, residual carbon content and glass transition temperature. Furthermore, replacing BNNS with GF significantly amplifies the mechanical properties of the composite substrate. This substitution leads to a notable reduction in the coefficient of thermal expansion (CTE) in all directions while simultaneously increasing the bending and tensile strength. At the same time, the composites can maintain reasonably high thermal conductivity values. Overall, with a GF concentration of 4 wt%, the composite showcases an appreciable increase in dielectric constants (17.81), a high thermal conductivity (1.3 W/m·K) and enhances mechanical properties (cross-plane CTE: 15.44 μm/(m·°C), in-plane CTE: 26.06 μm/(m·°C), bending strength: 65.6 MPa, tensile strength: 17.42 MPa). Considering its superior performance metrics, the composite can be identified as an optimal choice for microwave composite dielectric substrate material. [ABSTRACT FROM AUTHOR]

Glass fiber‐reinforced resin matrix composites have good mechanical and impact resistance properties, while with particle co‐reinforcement, a synergistic effect can further improve their performance. In this paper, continuous glass fiber‐reinforced nylon 6 (GF/PA6) and continuous glass fiber (GF) with glass beads (GBs) co‐reinforced nylon 6 (GB–GF/PA6) were prepared to investigate the co‐reinforcement mechanism and the synergistic effect of particle and fiber. A quantitative parameter of the residual impact force divided by the critical force Pr/Pcr, as the damage degree of the low‐velocity impact, is defined to evaluate the impact resistance of the composite. The results indicate that the damage of GB–GF/PA6 was lower than that of GF/PA6, and the synergistic effect reaches the most obvious at the GB addition of 10 wt%. Scanning electron microscope (SEM) and x‐ray computed tomography (XCT) images disclose that GB impedes the type II crack spread in the matrix and fiber/matrix interface. With the type II cracks reducing, the materials' resistance to delamination can be significantly enhanced. For the composite structure, in which 10 wt% GB and 60 wt% GF are introduced, the flexural strength, shear strength, and pendulum impact strength were tested with the maximum values of 379.4 MPa, 53.1 MPa, and 219.0 J/m2, respectively. This composite structure design, presenting a continuous GF and GBs co‐reinforce effect, offers a manufacturing process that is easily scalable to achieve excellent characteristics. [ABSTRACT FROM AUTHOR]

Because the physical properties of carbon fiber and glass fiber are very different, the fiber volume fraction in carbon/glass hybrid fiber composites cannot be tested by burning method or digestion method, respectively. Furthermore, these methods partially consume the fiber, especially for carbon fibers. To investigate the fiber volume fraction in carbon/glass hybrid fiber composites correctly, the test method is put forward. The burning method and the digestion method were combined to calculate the volume fraction of carbon fiber and glass fiber, respectively. The results show that the relative error between the measured value and the theoretical value is very small. The result of the present work implies that the feasibility and accuracy of this method through experimental verification. [ABSTRACT FROM AUTHOR]

To address the issues of insufficient strength and poor precision in polystyrene forming parts during the selective laser sintering process, a ternary composite of polystyrene/glass fiber/hollow glass microbeads was prepared through co-modification by incorporating glass fiber and hollow glass microbeads into polystyrene using a mechanical mixing method. The bending strength and dimensional accuracy of the sintered composites were investigated by conducting an orthogonal test and analysis of variance to study the effects of laser power, scanning speed, scanning spacing, and delamination thickness. The process parameters were optimized and selected to determine the optimal combination. The results demonstrated that when considering bending strength and Z-dimensional accuracy as evaluation criteria for terpolymer sintered parts, the optimum process parameters are as follows: laser power of 24 W, scanning speed of 1600 mm/s, scanning spacing of 0.24 mm, and delamination thickness of 0.22 mm. Under these optimal process parameters, the bending strength of sintered parts reaches 6.12 MPa with a relative error in the Z-dimension of only 0.87%. The bending strength of pure polystyrene sintered parts is enhanced by 15.69% under the same conditions, while the relative error in the Z-dimension is reduced by 63.45%. It improves the forming strength and precision of polystyrene in the selective laser sintering process and achieves the effect of enhancement and modification, which provides a reference and a new direction for exploring polystyrene-based high-performance composites and expands the application scope of selective laser sintering technology. [ABSTRACT FROM AUTHOR]

Composite materials made up of polymer matrix reinforced with synthetic fibers have gained popularity of late owing to their enhanced mechanical properties. However, very little work is reported to date on metals being used as filler material. Research gaps were obtained pertaining to the use of metallic fillers in synthetic fiber reinforced polymer composites. This paper demonstrates an attempt to fabricate composites made of Epoxy polymer matrix and E-glass fiber reinforcement with Mild Steel in its powdered form as fillers. Composites are prepared in varying weight percentages of the filler in the order of 2 wt. %, 4 wt. % and 6 wt. %. Hand layup method is employed for fabricating these composites which are later subjected to compression. Further, the samples are machined according to ASTM D3039 standard for tensile test and ASTM D256 standard for Izod impact test. Hardness test is also performed using a Shore D Durometer and these properties are compared with the unfilled samples. The results indicated that the weight percentage of the filler clearly influenced the mechanical properties of the developed composites. This study also revealed that the hardness and tensile strength of these composites improved with the incorporation of fillers up to 2 wt. % whereas, the impact strength improved up to 4 wt. %. Thereafter, there was a decline in their impact and tensile properties. However, hardness marginally increased beyond 4 wt. %. This area is open for research with regard to their usability under tribological, high temperature or magnetic conditions. [ABSTRACT FROM AUTHOR]

Fiber-reinforced polymer composites are manufactured using various methods, with vacuum-assisted resin transfer molding (VARTM or VARIM). This study's primary focus lies in assessing how the orientation of sampling impacts the mechanical properties of glass fiber-reinforced pure and nanocomposites. 2 wt.% nano Al2O3- doped and non-doped composites were produced using the VARTM process. Tensile, flexural, and density test specimens were extracted from three distinct zones and two distinc direction those aligned horizontally to the resin flow (HRF) and those oriented vertically to the resin flow (VRF). Remarkably, results showed up to a 3.91% increase in values from samples in the third zone, particularly on the vacuum outlet side. To facilitate precise stress value comparisons across plates, uniform sample orientation and consistent zone selection are essential. [ABSTRACT FROM AUTHOR]

Honeycomb composite with excellent mechanical–physical properties had attracted extensive attention. To achieve outstanding sound insulation while maximizing the high‐performance of honeycomb composite, this article reported a honeycomb composite structure filled with glass fiber (HFG) based on a paper‐making process and the corresponding sandwich structure. Pulping parameters, mechanical property, air permeability and sound insulation of HFG were analyzed. The results showed that the hanging index and settling height of glass fiber slurry were inversely proportional to the beating degree, which was beneficial for reducing the coefficient of variation (CV) of HFG with value of 4%–6%. The maximum improvement in tensile strength and bursting strength of HFG were 70% and 53%, respectively. In addition, sound transmission loss (STL) of HFG was proportional to cell size, density, filling amount and thickness of the honeycomb. Compared to HFG, sandwich structure consisting of HFG and glass fiber/hot melt fiber panels effectively improved STL, especially at low‐mid frequencies. It was also found that designing holes on the surface of sandwich structure could further improve STL in certain frequency bands. The structure offered a lightweight and high‐performance response for construction, transportation and infrastructure. Highlights: This article designs a new type of honeycomb filled glass fiber via paper‐making process, aiming to improve the comprehensive performance of honeycomb.By the design of embedded structure, the maximum improvement in tensile strength and bursting strength of honeycomb were 70% and 53%, respectively.By designing perforated, embedded and laminated structures, sound insulation has been improved, while reducing material quality. [ABSTRACT FROM AUTHOR]

Composites with excellent flame retardant and mechanical properties are in high demand in the aerospace and various industrial fields. Glass fiber (GF) reinforced polyimide (PI) composites (GFRPCs) were fabricated using a simple ball milling and hot pressing technique. The effect of GF content on the thermal stability, mechanical and flame retardant properties of composites has been systematically studied. The Rockwell hardness of GFRPCs increase with increasing GF content, while the compressive strength, impact strength and flexural strength initially show an increase followed by a decrease due to the excellent dispersibility of the fillers and the strong interfacial interaction between the one‐dimensional GF and PI matrix. Thermogravimetric analysis results show that the addition of GF with very low thermal conductivity and excellent temperature resistance can effectively improve the thermal stability of PI. Adding GF into PI can obviously improve the limiting oxygen index value. Moreover, as the GF content increased, the time to ignition of the composites prolonged while total heat release decreased. These findings suggest a viable solution for enhancing both the flame retardance and mechanical properties of PI‐based composites. Highlights: GFRPCs with high GF content fabricated via ball milling‐hot pressing method.Silane modified GF obviously improves the thermal stability of PI matrix.GFRPCs‐28 exhibits superior mechanical properties.An increases in time to ignition (TTI) and mass residual rate (MRR) of the GFRPCs was observed on adding GF. [ABSTRACT FROM AUTHOR]

Polymer gears are often used in power transmission due to their numerous advantages. Heat accumulates on polymer gears during operation. Over time, this accumulated heat leads to damage; and shortens the service life of the gears. To prevent this, various fillers are added to the polymer materials. These fillers help to dissipate the heat generated on the gears. In this study, 25% glass fibers, 35% carbon powder, and 60% bronze particles were added to the polytetrafluoroethylene (PTFE) matrix to determine the wear behavior of gears. The properties of the matrix and the filler mainly influence the wear behavior of PTFE composites. The study showed that all composite gears with filler have better wear resistance than pure PTFE gears due to their better thermal stability. After the tests, it was found that the gears made of PTFE + 35% carbon additive had about 12 times better wear rates than those made of pure PTFE. Based on the average temperature values of the experiment, it was found that the mass temperature of gears made of 35% carbon-doped PTFE is about 38-39% lower than that of pure PTFE. This study contributes to the standard studies on heat build-up, thermal damage, and wear of gears made of polymers with different fillers and ratios. [ABSTRACT FROM AUTHOR]

Waste printed circuit boards (WPCBs) -- a common type of ewaste consisting of electronic components with a significant amount of rare and precious metals as well as glass fiber composites. The development of WPCB retreatment technology through mechanical methods, resulting in metallic and nonmetallic waste fractions, can be efficiently classified as enriched concentrate. The research presented in this paper highlights the potential trends for recycling WPCBs. The integration of impact milling for WPCBs is a promising technology for the partitioning and fragmentation of different components and for the separation of fractions. The mechanical sizereduction and separation technology of precrushed WPCBs, using direct and separative disintegrator milling, has been compared with other technologies (hammer milling and high voltage fragmentation). The main parameters, such as the specific energy (ES) of WPCB treatment and the rate of separation of different phases, were studied. As preliminary results show the optimal parameters of partitioning of the metallic and nonmetallic parts, fragmentation and delamination (specific energy of treatment and rate of separation) by disintegrator milling were proposed. [ABSTRACT FROM AUTHOR]

Glass Fiber-Reinforced Polymer (GFRP) bars can enhance the flexural bearing capacity and durability of concrete beam members under sustained loading and alkaline environment over an extended period. However, addressing the challenges related to durability and deformation resistance remains crucial for long-term service. In this paper, the flexural performance of GFRP-reinforced concrete beams with different glass fiber contents under the coupling action of the alkaline environment and continuous load is studied, and the mechanism of improving the flexural performance of GFRP-reinforced concrete beams by dispersed fibers is analyzed from a microscopic point of view by scanning electron microscope (SEM) test. In addition, the finite element analysis software was used to simulate and verify the improvement effect of singly dispersed fiber on the bending of GFRP-reinforced concrete beams. The results demonstrate that GFRP-RC beams containing 0.5%, 1.0%, or 1.5% glass fiber exhibit a reduction in deflection ranging from 11% to 23% compared GFRP-RC beams without glass fiber, thereby improving their deformation resistance. The optimal glass fiber content is 1.5%. Simulation analysis demonstrates that the model exhibits enhanced resistance to deformation when the glass fibers are randomly dispersed. Specifically, increasing the random scattering of fibers at the bottom of the beam by two to three times results in a reduction of 7%-12% in mid-span displacement of the model. Additionally, within the cracked area, the fibers bear greater tensile stress compared to those in other uncracked regions, effectively preventing further cracking of GFRP-RC beams. This study offers valuable design guidance for enhancing performance of GFRP-RC members during long-term service. • This paper studied glass fiber GFRP-RC beams. • The working condition is the coupling of sustained loading and alkaline environment. • The influence of fiber on the flexural property of beam was investigated by finite element method. • The corrosion age of alkaline environment is 450 d. [ABSTRACT FROM AUTHOR]

The fiber hybridization in high-strength composites is one of the most researched strategies to enhance their limited toughness. In this work, hybrid composites at laminate level by stacking together plies of carbon and glass fiber were prepared using fused filament fabrication (FFF) technique. The large void content and the poor adhesion between layers attributed to this technology are overcome by the addition of an optimized thermo-pressurized treatment. The analysis of post-processing temperature effects on the microstructural, thermal and interlaminar properties of additive manufactured hybrid composites, revealed a progressive porosity reduction preserving the dimensional accuracy. The enhancement of mechanical properties is due to different contributions that occurred during post-processing: (i) drying effect, which reduces the plasticization of the composites; (ii) improvement of interface adhesion due to the miscibility of polymers; and (iii) significant porosity reduction (below 1 %). This work opens a wider space of possibilities, since FFF allows more complex designs than traditional composite manufacturing, and additionally provides an approach to promote molecular diffusion at the interface, which is the most critical region of FFF parts. [ABSTRACT FROM AUTHOR]

• Adding 1 % nano Al 2 O 3 maintained mechanical properties by reducing water absorption. • Nano Al 2 O 3 enhances decomposition temperature by 8.35 % and acts as a thermal barrier. • 1 % nano Al 2 O 3 additive improves t g by 8.76 % in the hydrothermal aging environment. • Aging led to wear property deterioration, but nano Al 2 O 3 decreased this effect. Glass fiber composites are widely used in offshore structures for marine application due to their exceptional strength-to-weight ratio, corrosion resistance, and durability. As offshore structures are exposed to harsh environmental conditions, including saltwater, fluctuating temperatures, and hydrothermal influences, understanding the effects of aging on structural integrity on glass fiber composites becomes very important. In this study glass fiber-reinforced epoxy nanocomposites with 1 % and 2 % nano Al 2 O 3 reinforcement were produced using the vacuum-assisted resin transfer molding. These composites were subjected to a three-month aging process in artificial seawater at a temperature of 70 °C. Mechanical properties were assessed through Tensile and Flexural Tests, while thermal properties were analyzed via TGA, DTA, and DSC analysis. To examine the structural characteristics, Fourier Transform Infrared (FT-IR) spectrophotometry was utilized, and SEM analysis was conducted. Wear properties were evaluated through dry sliding wear tests. Water absorption properties were determined in a precisely controlled seawater bath. The findings reveal that the incorporation of 1 % nano Al 2 O 3 effectively diminishes the water absorption rate, thereby safeguarding the mechanical, thermal, and structural properties within a hydrothermal environment. [Display omitted] [ABSTRACT FROM AUTHOR]

[Display omitted] This work evaluates several mechanisms of separation of surfactant-stabilized emulsified water droplets from diesel fuel using high surface area (50–370 m2/g) and high porosity (>90 %) filter media fabricated by combining aerogels and glass fiber mats. Specifically, high surface area, porous gels of syndiotactic polystyrene (sPS) and silica are developed inside glass fiber mats via dip coating in corresponding sol followed by sol–gel transition. The resultant materials are supercritically dried to obtain aerogel-coated separation media. The abundant meso- and macropores of the aerogel network and the different surface energy of sPS and silica produce cooperative functioning of the mechanisms of size exclusion, coalescence filtration, surfactant adsorption, and volumetric water absorption for removal of emulsified water droplets from ultralow sulfur diesel fuel under continuous flow conditions. The role of each separation mechanism is elucidated in this paper. The results reveal high water separation efficiency of ∼92 % compared to ∼30 % for the glass fiber mats. [ABSTRACT FROM AUTHOR]

Marl clays with varying levels of calcite content often exhibit more erratic behavior compared to other problematic soils, especially when exposed to repetitive Freeze-Thaw (F-T) cycles. It is crucial to prioritize the mechanical properties and durability of this particular soil variety as neglecting such characteristics can result in irreversible harm to the superstructures. This research focused on examining the utilization of lime and Nanoclay (NC) as stabilizers and Glass Fiber (GF) as reinforcement for natural marl soil. The study involved preparing samples with 6% lime and up to 1.5% NC, combined with varying amounts of GF ranging from 0 to 1%. The samples were cured for 7 and 28 days and subjected to 0, 1, 4, and 8 F-T cycles. Several Unconfined Compressive Strength (UCS) and Indirect Tensile Strength (ITS) tests as well as microstructural analyses including Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD) were performed on the samples before and after being exposed to F-T cycles. Results showed that the application of GF enhanced the UCS and ITS of lime-NC-stabilized marl soil by creating interlocking zones between the particles. The addition of lime and NC shifted the behavior of the soil sample from ductile to brittle, while the inclusion of GF caused the soil to revert to ductile behavior, resulting in a decrease in secant modulus (E 50) and an increase in energy absorption capacity (E u) compared to samples without GF. Furthermore, incorporating GF along with lime and NC into the marl soil improved the F-T durability even after 8 cycles and resulted in reduced strength deterioration compared to the control sample. The optimum mixture was found to be 6% lime, 1% NC, and 0.75% GF, resulting in a noteworthy improvement of 6.5 times in the ITS and a slight decrease of 6% after 8 F-T cycles compared to the untreated marl soil. [Display omitted] • Glass fiber enhances the freeze-thaw durability of the lime-nanoclay-stabilized marl soil. • Inclusion of glass fiber and naoclay improves the mechanical properties of marl soil. • Glass fiber changes failure behavior to ductile state even after freeze-thaw cycles. • NC particles can effectively enhance the durability of the system. [ABSTRACT FROM AUTHOR]

Shape memory polymers (SMPs) are a new class of materials in which their shapes can be changed over time. Despite their lightness and ease of fabrication, SMPs have very low recovery forces and are therefore inefficient when high loads are applied. To improve the mechanical properties of polymeric materials, glass fiber (GF) is commonly used as a reinforcement. The purpose of this study was to demonstrate a four-dimensional (4D) printing process using material extrusion additive manufacturing on both polylactic acid (PLA) and thermoplastic polyurethane (TPU). The goal was to improve the recovery forces in SMPs. GF roving was fed continuously into the nozzle of a three-dimensional (3D) printer to fabricate composite specimens. Also, multi-layer PLA/TPU specimens were printed. There was a measurement of shape fixity, shape recovery, and force recovery ratios. A multi-objective function analysis was performed to determine the optimum material based on recovery force priority in this study. In terms of recovery force, GF showed a superior effect. For composite specimens, shape fixity and recovery ratios decreased and increased, respectively. According to the result of optimization, PLA with 6.62 % GF proved to be the best material. PLA's recovery force has been improved by annealing heat treatment. Furthermore, cyclic experiments up to three cycles were conducted to evaluate the performance of the optimum material. [ABSTRACT FROM AUTHOR]