1. Recyclable porous core-shell Mn-Co-O flame retardant for improving flame retardancy and smoke suppression of epoxy resin.
- Author
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Zou, Yingbing, Niu, Kui, Luo, Fubin, and Li, Hongzhou
- Subjects
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FIREPROOFING , *FIREPROOFING agents , *EPOXY resins , *ENTHALPY , *HEAT release rates , *COMBUSTION , *FLAMMABILITY - Abstract
• Mn 3 CoO x was prepared to enhance the fire safety of epoxy resins (EP). • Mn 3 CoO x impressively reduced pHRR and pSPR by 47.5 % and 34.6 %, respectively. • Mn 3 CoO x can effectively catalyze the transformation of hazardous gases. • Recovery of Mn 3 CoO x to 90.0 % in EP composite. The development of metal oxide flame retardants that are easy to synthesize, efficient, and recyclable would be more beneficial to circular economy. In this work, a porous core-shell Mn 3 CoO x was developed to efficiently reduce heat, smoke as well as hazardous gas during the combustion of epoxy resin (EP). Compared with pure EP, the peak heat release rate (pHRR), total heat release (THR), peak smoke production rate (pSPR), total smoke production (TSP), peak CO production rate (pCOPR), and peak CO 2 production rate (pCO 2 PR) of EP/Mn 3 CoO x are reduced by 47.5 %, 21.5 %, 34.6 %, 17.6 %, 58.6 %, and 55.4 %, respectively. It has been shown that Mn 3 CoO x not only catalyzes the formation of high-quality char layer but also effectively catalyzes the conversion of hazardous gas products into CO 2. Recovery experiments of Mn 3 CoO x filler in EP composites show that the recovery of Mn 3 CoO x can reach 90.0 %. This work provides insights into the design of efficient metal oxide flame retardants and ideas for the development of recycled flame retardants. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
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