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• Soil reflectance composites were generated with Sentinel-2 L2A data. • A multi-channel CNN learning framework for soil organic carbon prediction is proposed. • A dual input deep learning architecture improves the predictions. • The framework produced results that can be interpreted. The Copernicus Sentinel-2 multispectral imagery data may be aggregated to extract large-scale, bare soil, reflectance composites, which enable soil mapping applications. In this paper, this approach was tested in the German federal state of Bavaria, to provide estimations for soil organic carbon (SOC). Different temporal ranges were considered for the generation of the composites, including multi-annual and seasonal ranges. A novel multi-channel convolutional neural network (CNN) is proposed. By leveraging the advantages of deep learning techniques, it utilizes complementary information from different spectral pre-treatment techniques. The SOC predictions indicated little dissimilarity amongst the different composites, with the best performance attained for the six-year composite containing only spring months (RMSE = 12.03 g C · kg−1, R2 = 0.64, RPIQ = 0.89). It has been demonstrated that these outcomes outperform other well-known machine learning techniques. An ablation analysis was accordingly performed to evaluate the interplay of the CNN's different components to disentangle the advantages of each aspect of the proposed framework. Finally, a DUal inPut deep LearnIng architecture, named DUPLICITE, is proposed, which concatenates deep spectral features derived from the CNN mentioned earlier, as well as topographical and environmental covariates through an artificial neural network (ANN) to exploit their complementarity. The proposed approach was demonstrated to provide an improvement in the overall prediction performance (RMSE = 11.60 gC · kg−1, R2 = 0.67, RPIQ = 0.92). [ABSTRACT FROM AUTHOR]