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Within the context of fewest-switch surface hopping (FSSH) dynamics, one often wishes to remove the angular component of the derivative coupling between states J and K . In a previous set of papers, Shu et al. [J. Phys. Chem. Lett. 11, 1135–1140 (2020)] posited one approach for such a removal based on direct projection, while we isolated a second approach by constructing and differentiating a rotationally invariant basis. Unfortunately, neither approach was able to demonstrate a one-electron operator O ̂ whose matrix element J O ̂ K was the angular component of the derivative coupling. Here, we show that a one-electron operator can, in fact, be constructed efficiently in a semi-local fashion. The present results yield physical insight into designing new surface hopping algorithms and are of immediate use for FSSH calculations. [ABSTRACT FROM AUTHOR]

In his remarkable new book, Emotion and Virtue, Sreenivasan defends the view that, in the case of many virtues, in order for an exemplar of each of these virtues to be a reliable judge of what that virtue requires in specific circumstances, she must possess a particular, morally rectified, emotional trait. In this article, I raise two challenges to “the argument from salience” that Sreenivasan offers in favor of this view. First, I argue that, although Sreenivasan wishes to remain neutral about different philosophical theories of emotions, the success of his argument depends, in fact, on the outcome of the debate about the nature of emotions. Second, I challenge the central claim of Sreenivasan's argument from salience, namely, that the possession of a morally rectified emotional trait, cleverness, and supplementary moral knowledge is sufficient to explain an agent's ability to reliably judge what a given virtue requires in specific circumstances. [ABSTRACT FROM AUTHOR]

The history of slavery in the age of abolition is full of contradictions. The fate of enslaved persons depended on coincidences, on bad luck and good fortune. To understand what this meant in practice, this article focuses on questions of flight and longing. It zooms in on the colonial enclave Manado, North Sulawesi (Indonesia), where slavery was both an indigenous-regional and a local-colonial phenomenon, two worlds that were never fully separated. This exploration centers around two sets of archives: a slave register and a series of interviews with runaways. These fascinating documents were produced at the same time and in the same space, but provides us markedly different perspectives. What do they tell us about motives and experiences of people who escaped slavery? To what extend can we reconstruct life in and out of slavery when we combine these two sets of sources? The critical exploration that this article presents is meant as a step towards a fuller comprehension of the history of slavery in colonial Indonesia. [ABSTRACT FROM AUTHOR]

In terminally ill individuals who would otherwise end their own lives, active voluntary euthanasia (AVE) can be seen as life-extending rather than life-shortening. Accordingly, AVE supports key pro-euthanasia arguments (appeals to autonomy and beneficence) and meets certain sanctity of life objections. This paper examines the extent to which a terminally ill individual's wish to donate organs after death contributes to those life-extension arguments. It finds that, in a terminally ill individual who wishes to avoid experiencing life he considers to be not worth living, and who also wishes to donate organs after death, AVE maximizes the likelihood that such donations will occur. The paper finds that the wish to donate organs strengthens the appeals to autonomy and beneficence, and fortifies the meeting of certain sanctity of life objections, achieved by life-extension arguments, and also generates appeals to justice that form novel life-extension arguments in favour of AVE in this context. [ABSTRACT FROM AUTHOR]

Background: Youth healthcare has an important role in promoting a healthy lifestyle in young children in order to prevent lifestyle-related health problems. To aid youth healthcare in this task, a new lifestyle screening tool will be developed. The aim of this study was to explore how youth healthcare professionals (YHCP) could best support parents in improving their children's lifestyle using a new lifestyle screening tool for young children. Methods: We conducted four and seven focus groups among parents (N = 25) and YHCP (N = 25), respectively. Two main topics were addressed: the experiences with current practice of youth healthcare regarding lifestyle in young children, and the requirements for the lifestyle screening tool to be developed. The focus groups were recorded, transcribed verbatim and analysed using an inductive approach. Results: Both parents and YHCP indicated that young children's lifestyles are often discussed during youth healthcare appointments. While parents felt that this discussion could be more in-depth, YHCP mainly needed clues to continue the discussion. According to parents and YHCP, a new lifestyle screening tool for young children should be easy to use, take little time and provide courses of action. Moreover, it should be attractive to complete and align with the family concerned. Conclusions: According to parents and YHCP, a new lifestyle screening tool for young children could be useful to discuss specific lifestyle topics in more detail and to provide targeted advice. [ABSTRACT FROM AUTHOR]

Introduction: Early integration of palliative care and advance care planning (ACP) play an increasingly important role in the treatment of patients with advanced cancer. Advance directives (ADs) and patients' preferences regarding end-of-life (EoL) care are important aspects of ACP. In the outpatient setting, the prevalence of those documents and EoL care wishes is not well investigated, and changes in the longitudinal course are poorly understood. Methods: From June 2020 to August 2022, 67 outpatients with advanced solid tumors undergoing palliative cancer therapy were interviewed on the topic of ACP in a longitudinal course. From this database, the prevalence of ADs, healthcare proxy, EoL care wishes, and the need for counseling regarding these issues were collected. In addition, EoL care wishes were examined for their stability. Results: Fifty-one patients (76.1%) reported having ADs, and 41 patients (61.2%) reported having a healthcare proxy. Nineteen patients (37.3%) with ADs and 11 patients (68.7%) without ADs indicated a wish for counseling. Reported EoL care wishes remained stable over a period of approximately 6 months. Nevertheless, intraindividual changes occurred over time within the different EoL care preferences. The desire for resuscitation and dialysis were significantly higher in men than in women (resuscitation: 15 of 21 men [71.4%] versus 9 of 22 women [40.9%], odds ratio [OR] 3.611, 95% confidence interval [CI], 1.01–12.89, p = 0.048; dialysis: 16 of the 23 men [69.6%] versus 9 of the 25 women [36.0%], OR: 4.063, 95% CI: 1.22–13.58, p = 0.023). Conclusion: Our results show a reasonably high percentage of ADs and healthcare proxies in our study cohort. The observed stability of EoL requests encourages the implementation of structured queries for ADs and healthcare proxy for outpatients undergoing palliative treatment. Our data suggest that gender-specific characteristics should be further investigated in this context. [ABSTRACT FROM AUTHOR]

The synthesis of a novel disorazole C1 analogue is described, and its biological activity as a cytotoxic compound is reported. Based on our convergent and flexible route to the disorazole core, we wish to report a robust strategy to synthesize a non-symmetrical disorazole in which we couple one half of the molecule containing the naturally occurring oxazole heterocycle and the second half of the disorazole macrocycle containing a thiazole heterocycle. This resulted in a very unusual non-symmetrical disorazole C1 analogue containing two different heterocycles, and its biological activity was studied. This provided exciting information about SAR (structure-activity-relationship) for this highly potent class of antitumor compounds. [ABSTRACT FROM AUTHOR]

Background: In Austria, due to its history, only relatively little research on the topic of intellectual disabilities and dementia has been conducted to date. The present study thus aims to explore the challenges and tasks currently facing formal caregivers, together with assessing their wishes for further development. Methods: Ten semi‐structured interviews were held with formal caregivers. Interviews were transcribed and analysed by means of structured qualitative content analysis. Results: Caregivers must deal with conflicts between residents, and with increasing demands for care and emotional support. Education and training on dementia and intellectual disability are mostly of high quality, but still remain insufficient. Caregivers would like to see suitable adaptation of care premises, smaller groups, more staff and better training on dementia and intellectual disability. Conclusion: To ensure quality care and 'ageing in place', caregivers and providers need to pay greater attention to dementia‐related changes when planning and adapting services. [ABSTRACT FROM AUTHOR]

The letter charts my relationship to geography through a letter to Donald Deskin Jr. From Black geographer junior scholar to pioneering Black geographer, this letter uses Black geographies as an analytic to think through Black geographical knowledge, practice and kinship. [ABSTRACT FROM AUTHOR]

Intensive weight management programs are effective but often have low enrollment and high attrition. Lack of motivation is a key psychological barrier to enrollment, engagement, and weight loss. Mental Contrasting with Implementation Intentions (MCII) is a unique imagery technique that increases motivation for behavior change. We describe our study protocol to assess the efficacy and implementation of MCII to enhance the effectiveness of VA's MOVE! or TeleMOVE! weight management programs using a procedure called "WOOP" (Wish, Outcome, Obstacle, Plan) for Veterans. We hypothesize that WOOP+MOVE! or TeleMOVE! (intervention) will lead to greater MOVE!/TeleMOVE! program engagment and consequently weight loss than MOVE!/TeleMOVE! alone (control). Veterans are randomized to either the intervention or control. Both arms receive the either MOVE! or TeleMOVE! weight management programs. The intervention group receives an hour long WOOP training while the control group receives patient education. Both groups receive telephone follow up calls at 3 days, 4 weeks, and 2 months post-baseline. Eligible participants are Veterans (ages 18–70 years) with either obesity (BMI ≥ 30 kg/m2) or overweight (BMI ≥ 25 kg/m2) and an obesity-associated co-morbidity. At baseline, 6 and 12 months, we assess weight, diet, physical activity in both groups. The primary outcome is mean percent weight change at 6 months. Secondary outcomes include changes in waist circumference, diet, physical activity, and dieting self-efficacy and engagement in regular physical activity. We assess implementation using the RE-AIM framework. If WOOP VA is found to be efficacious, it will be an important tool to facilitate weight management and improve weight outcomes. Clinical Trial Registration: NCT05014984 [ABSTRACT FROM AUTHOR]

The document is a reviewer acknowledgement from the journal "Holzforschung: International Journal of the Biology, Chemistry, Physics, & Technology of Wood." It thanks numerous colleagues for their assistance in acting as referees for the journal. The list includes a diverse range of individuals from various countries and backgrounds, reflecting the global nature of the journal's contributors. [Extracted from the article]

The NETWORK Globalhealth celebrates its 20th anniversary and the magazine "Kosmetische Medizin" congratulates and wishes continued success. The network consists of over 1,000 German-speaking members and has a productive collaboration with the magazine. It offers further education for aesthetic treatments and recommends interesting products. The network has also launched another network for Extended Medicine. The editor of the magazine is looking forward to further collaboration with the network. [Extracted from the article]