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The occurrence of extreme rainfall events over mountain catchments is likely to trigger mass failure processes on hillslopes and sediment transport within the channel network. Understanding the degree of linkage between the sediment sources and transfer pathways downstream is essential in those catchments where settlements are affected by hydro-geomorphic processes, in order to plan suitable interventions for risk mitigation. A recent storm (October 2020) named "Alex", estimated to be an extratropical cyclone with a more than 100-year return period, hit the Mediterranean Alps at the border between Italy and France, triggering deadly landslides and flooding processes. This work focuses on two adjacent mountain catchments located in the Liguria region (Italy) which share the same outlet, where a small village was damaged by high-magnitude sediment transport and deposition processes during the storm. In order to analyze sediment dynamics at the catchment scale leading to severe damage to the urban settlements at the outlet, an integrated approach was used. Very high resolution (0.5 m) satellite imagery was employed to map the mass failure processes on the hillslopes with a visual interpretation. This dataset was then compared with a map of the Index of Connectivity created using the SedInConnect 2.3 software to characterize the pre-event structural connectivity in both catchments. The integration of these two datasets permitted understanding that debris slides evolving into debris flows downstream supplied most of the sediments to the channel network. These processes concentrated mainly in a specific catchment where hillslopes have the highest connectivity with the valley bottom. This outcome provided a clear evidence that inventory maps developed soon after an extreme event, coupled with sediment connectivity datasets, can provide relevant information for future land management and risk mitigation strategies. These can be exploited to prioritize structural interventions in specific areas, to reduce the connectivity or disconnect inhabited areas from the hydro-geomorphic systems and avoid future damage. • We analyzed the geomorphic impact of a storm on two adjacent mountain catchments. • Debris slides turned into debris flows represented the principal sediment sources. • The Index of Connectivity allowed knowing the degree of linkage with valley bottoms. • Part of the mobilized sediments travelled up to the outlet damaging an urban center. • Inventory maps coupled with sediment connectivity represent relevant potentialities. [ABSTRACT FROM AUTHOR]