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In many situations, the quality of a process or product can be characterized by a functional relationship or profile. It is well-known that the independence assumptions of the error terms within or between profiles are not always valid and could be violated due to within or between profile autocorrelation. Since most of the process capability indices (PCIs) have been developed for simple linear profiles (SLPs) without considering autocorrelation, this paper provides some novel methods to analyze the capability of SLP under each of the two different autocorrelation effects separately, as well as the case where both autocorrelation effects are present. We assume that the first-order autoregressive AR(1) model explains the within- and between-profile autocorrelation in error terms. To evaluate the process capability, a new functional index called C p ‴ (P r o f i l e) is introduced for SLP with independent errors, and then it is modified to include the three possible cases of within, between, and simultaneous autocorrelation. The simulation results demonstrate that the proposed schemes outperform existing schemes regarding bias and mean square error (MSE) criteria. Moreover, bootstrap confidence intervals for the proposed index are obtained. Finally, an illustrative example in the chemical industry is used to demonstrate the applicability of the proposed method. [ABSTRACT FROM AUTHOR]

Epoxy resins were reinforced with different ZnO nanofillers (commercial ZnO nanoparticles (ZnO NPs), recycled ZnO and functionalized ZnO NPs) in order to obtain ZnO–epoxy composites with suitable mechanical properties, high adhesion strength, and good resistance to corrosion. The final properties of ZnO–epoxy composites depend on several factors, such as the type and contents of nanofillers, the epoxy resin type, curing agent, and preparation methods. This paper aims to review the preparation methods, mechanical and anti-corrosion performance, and applications of ZnO–epoxy composites. The epoxy–ZnO composites are demonstrated to be valuable materials for a wide range of applications, including the development of anti-corrosion and UV-protective coatings, for adhesives and the chemical industry, or for use in building materials or electronics. [ABSTRACT FROM AUTHOR]

In this paper, a detailed mechanism is discussed for two processes: deNOx and deN2O. An FAU catalyst was used for the reaction with Cu-Fe bimetallic adsorbates represented by a dimer with bridged oxygen. Partial hydration of the metal centres in the dimer was considered. Ab initio calculations based on the density functional theory were used. The electron parameters of the structures obtained were also analysed. Visualisation of the orbitals of selected structures and their interpretations are presented. The presented research allowed a closer look at the mechanisms of processes that are very common in the automotive and chemical industries. Based on theoretical modelling, it was possible to propose the most efficient catalyst that could find potential application in industry–this is the FAU catalyst with a Cu-O-Fe bimetallic dimer with a hydrated copper centre. The essential result of our research is the improvement in the energetics of the reaction mechanism by the presence of an OH group, which will influence the way NO and NH3 molecules react with each other in the deNOx process depending on the industrial conditions of the process. Our theoretical results suggest also how to proceed with the dosage of NO and N2O during the industrial process to increase the desired reaction effect. [ABSTRACT FROM AUTHOR]

This document discusses the synthesis and utilization of furans and their derivatives as platform chemicals in the chemical industry. Furans, such as furfural and 5-hydroxymethylfurfural (HMF), can be derived from hemicellulose and cellulose and used in various reactions to produce renewable biofuels and biochemicals. However, the reactivity of furans also leads to the formation of significant by-products, making the development of sustainable processes challenging. The document presents recent advances in furan synthesis and utilization, focusing on catalytic systems, process conditions, and kinetic and mechanistic aspects. The papers highlight the importance of furanic compounds for the development of biorefineries and a sustainable energy transition. [Extracted from the article]

This paper presents the preparation of heterogeneous catalysts for the direct hydrogenation process of CO2 to methanol. The development of the modern chemical industry is inextricably linked to the use of catalytic processes. As a result, currently over 80% of new technologies introduced in the chemical industry incorporate catalytic processes. Since the basic factor of catalytic processes is the catalysts, the studies for the deepening of the knowledge regarding the nature of the action of the catalysts, for the development of new catalysts and catalytic systems, as well as for their improvement, represent a research priority of a fundamental or applied nature. The Cu/ZnO/Al2O3 catalyst for the synthesis of green methanol, using precursors of an inorganic (copper nitrate, denoted by Cu/ZnO/Al2O3-1) and organic (copper acetate, denoted by Cu/ZnO/Al2O3-2) nature, are obtained by chemical impregnation that includes two stages: preparation and one of calcination. The preparation methods and conditions, as well as the physico-chemical properties of the catalyst precursor, play a major role in the behavior of the catalysts. The prepared catalysts were characterized using atomic adsorption analysis, scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis, specific surface area and pore size analyses, adsorption, and the chemisorption of vapor (BET). [ABSTRACT FROM AUTHOR]

N-heterocycles with quinoline structures hold significant importance within the chemical and pharmaceutical industries. However, achieving their efficient transformations remains a vital yet challenging endeavor. Herein, a series of W-doped Ga2O3-NC catalysts were synthesized using a Ga-MOF-derived strategy through a simple solvothermal method, with a remarkably high activity and selectivity towards the oxidative dehydrogenation of N-heterocycles. Furthermore, the MOF-derived W-doped Ga2O3-NC catalysts exhibit remarkable substrate tolerance and recyclability. The outstanding catalytic activity was attributed to the robust synergistic interaction between the W species and the Ga2O3-NC carrier, which facilitates the activation of hydrogen atoms in the C-H and C=N bonds on both the oxygen molecule and the substrate to produce H2O2. Additionally, the solvent effect of methanol can significantly enhance dehydrogenation due to its strong ability to donate and accept protons of hydrogen bonding. The present work provides a new approach to MOF-derived non-precious metal catalysts for achieving the efficient oxidation dehydrogenation of N-heterocycles. [ABSTRACT FROM AUTHOR]

The catalytic hydrogenation of the toxic and harmful p-chloronitrobenzene to produce the value-added p-chloroaniline is an essential reaction for the sustainable chemical industry. Nevertheless, ensuring satisfactory control of its chemoselectivity is a great challenge. In this work, a N/S co-doped metal-free carbon catalyst has been fabricated by using cysteine as a source of C, N, and S. The presence of calcium citrate (porogen agent) in the mixture subjected to pyrolysis provided the carbon with porosity, which permitted us to overcome the issues associated with the loss of heteroatoms during an otherwise necessary activation thermal treatment. Full characterization was carried out and the catalytic performance of the metal-free carbon material was tested in the hydrogenation reaction of p-chloronitrobenzene to selectively produce p-chloroaniline. Full selectivity was obtained but conversion was highly dependent on the introduction of S due to the synergetic effect of S and N heteroatoms. The N/S co-doped carbon (CYSCIT) exhibits a mesoporous architecture which favors mass transfer and a higher doping level, with more exposed N and S doping atoms which act as catalytic sites for the hydrogenation of p-chloronitrobenzene, resulting in enhanced catalytic performance when compared to the N-doped carbon obtained from melamine and calcium citrate (MELCIT) used as a reference. [ABSTRACT FROM AUTHOR]

Disc stack centrifuge belongs to one kind of sedimentation centrifuge, widely used in the environmental protection, pharmacy, and chemical industries, etc. The flow process inside the disc stack centrifuge seriously affects the separation efficiency. However, the flow process inside the disc stack centrifuge and its influence on the separation efficiency have not yet been detailed. We plan to study the flow process of oil and water phases inside the disc stack centrifuge and to explore the process of fragmentation and accumulation of water droplets. In this study, the Mixture-PBM (Population Balance Model) model is used to numerically simulate the two-phase flow of oil and water in the disc stack centrifuge and compare it with the tests. The research found that with the increase in rotational speed, the separation efficiency rises in both the test and numerical simulation results, and the difference between the test and simulation results is below 1%. The effect of ribs on the flow is considered, and the results show that the hysteresis of the liquid flow in the disc stack centrifuge is significantly reduced after considering the ribs, and the numerical simulation results can reach 98% of the theoretical results. Fluid entering the separation channel from the neutral pore creates a vortex, and as the dimensionless number λ increases, the degree of deviation of the fluid's trajectory from the generatrix increases. The circumferential and radial velocities in the separation channel appear large in the center and small near the wall. The water content in the rising channel gradually decreases, and 90% of the water finishes settling in the distributor. The processing volume of the separation channel in each layer shows a small bottom layer, a large top layer, and a uniform law in the middle. The coalescence of water droplets occurs mainly in the separation channel, as found by analyzing the laws of the internal flow of the disc stack centrifuge, which provides the basis for improving the structure of the disc stack centrifuge, increasing the separation efficiency and reducing the floor space. [ABSTRACT FROM AUTHOR]

Simvastatin is a widely used statin medication that is commonly prescribed to lower cholesterol levels and reduce the risk of cardiovascular events. It is marketed under the brand name Zocor and is known for its effectiveness in treating high cholesterol and managing cardiovascular disease. Monacolin J is an important precursor used to synthesize simvastatin and is mainly produced by chemical methods in industry. Here, monacolin J was synthesized through an enzymatic method under optimized reaction conditions. One recombinant Escherichia coli BL21 (DE3) strain containing lovastatin hydrolase (encoded by CDV55_102090) from Aspergillus turcosus was constructed, which effectively transformed 100 g/L of lovastatin to monacolin J within 3.5 h at pH 8.0 and 30 °C, with a conversion rate of >99.8%. Furthermore, the T5010, the temperature at which the residual activity was half of the initial enzymatic activity after 10 min of heat treatment, was >50 °C, indicating the tremendous potential of this bioprocess for synthesizing monacolin J at an industrial scale. [ABSTRACT FROM AUTHOR]

The European Union aims to be climate neutral by 2050. To achieve this ambitious goal, net greenhouse gas emissions must be reduced by at least 55% by 2030. Post-combustion CO2 capture methods are essential to reduce CO2 emissions from the chemical industry, power generation, and cement plants. To reduce CO2, it must be captured and then stored underground or converted into other valuable products. Apromising alternative for CO2 reduction is the use of humic acid salts (HASs). This work describes a process for the preparation of potassium (HmK) and ammonium (HmA) humic acid salts from oxidized lignite (leonardite). A detailed characterization of the obtained HASs was conducted, including elemental, granulometric, and thermogravimetric analyses, as well as 1H-NMR and IR spectroscopy. Moreover, the CO2 absorption capacity and absorption rate of HASs were experimentally investigated. The results showed that the absorption capacity of the HASs was up to 10.9 g CO2 per kg. The CO2 absorption rate of 30% HmA solution was found to be similar to that of 30% MEA. Additionally, HmA solution demonstrated better efficiency in CO2 absorption than HmK. One of the issues observed during the CO2 absorption was foaming of the solutions, which was more noticeable with HmK. [ABSTRACT FROM AUTHOR]

The ever-increasing expansion of chemical industries produces a variety of common pollutants, including colors, which become a global and environmental problem. Using a nanocatalyst is one of the effective ways to reduce these organic contaminants. With this in mind, a straightforward and effective method for the production of a novel nanocatalyst based on lignin-derived carbon, titanium dioxide nanoparticles, and Ag particles (TiO2/C/Ag) is described. The preparation of carbon and Ag particles (in sub-micro and nano size) was carried out by laser ablation in air. The nanocomposite was synthesized using a facile magnetic stirrer of TiO2, C, and Ag. According to characterization methods, a carbon nanostructure was successfully synthesized through the laser irradiation of lignin. According to scanning electron microscope images, spherical Ag particles were agglomerated over the nanocomposite. The catalytic activities of the TiO2/C/Ag nanocomposite were tested for the decolorization of methylene blue (MB) and Congo red (CR), employing NaBH4 in a water-based solution at 25 °C. After adding fresh NaBH4 to the mixture of nanocomposite and dyes, both UV absorption peaks of MB and CR completely disappeared after 10 s and 4 min, respectively. The catalytic activity of the TiO2/C/Ag nanocomposite was also examined for the reduction of 4-nitrophenol (4-NP) using a NaBH4 reducing agent, suggesting the complete reduction of 4-NP to 4-aminophenol (4-AP) after 2.30 min. This shows excellent catalytic behavior of the prepared nanocomposite in the reduction of organic pollutants. [ABSTRACT FROM AUTHOR]

Revealing the coordinated correlation between chemical industry development and the water environment is essential for promoting high-quality development in the Yangtze River Economic Belt. Based on the data in the Yangtze River Economic Belt from 2011 to 2021, this study explores the spatial–temporal evolution and influencing factors of the coupled coordination between chemical industry development and the water environment by using the global entropy method, a coupling coordination model, and the Tobit model. The results indicate a general upward trend in the comprehensive indices of chemical industry development and water environment systems, albeit with distinct spatial patterns. A mismatch between the two systems is observed in terms of spatial distribution. Regarding the coupling coordination degree, the relationship shows an upward trend, primarily at a mild-to-moderate coupling stage, exhibiting a spatial pattern of "downstream > midstream > upstream". Moreover, a trend of increasing coordination and narrowing disparities between high- and low-level regions can be observed. The model results suggest that environmental regulation, economic development, government capacity, and urbanization play a crucial role in promoting the coupled development of the chemical industry and the water environment. However, openness to external markets may not enhance coupled coordination. These findings may provide policy guidance for the development status of two subsystems in other locations. [ABSTRACT FROM AUTHOR]

Pd/C catalysts play a pivotal role in contemporary chemical industries due to their exceptional performance in diverse hydrogenation processes and organic reactions. Over the past century, researchers have extensively explored the factors influencing Pd/C catalyst performance, particularly emphasizing the impact of oxygen-containing groups through oxidation or reduction modifications. However, most studies use respective Pd/C catalysts to analyze the catalytic reactions of one or a class of chemical bonds (polar or non-polar). This study investigates alterations in Pd/C catalysts during temperature-programmed reduction (TPR) and evaluates the hydrogenation activity of unsaturated polar bonds (C=O, acetophenone) and non-polar bonds (C≡C, phenylacetylene) in Pd/C catalysts. The experimental results indicate that the reduction of Pd/C decreases the content of oxygen-containing groups, reducing hydrogenation activity for acetophenone but increasing it for phenylacetylene. This research highlights the preference of regular Pd surfaces for non-polar bond reactions and the role of Pd/oxide sites in facilitating polar bond hydrogenation. These discoveries offer essential insights into how oxygen-containing groups influence catalytic performance and allow us to propose potential avenues for enhancing the design and production of Pd/C catalysis. [ABSTRACT FROM AUTHOR]

The aim of this study was to develop a new manufacturing process for bimetallic materials by combining laser treatment with traditional casting methods. This process involves laser-treating nickel alloy-grade UNS 6230 plates to create a regular macro-relief on their surface. These treated plates are then placed in a sand mold, and molten non-alloy steel (S235JRG2) is poured into the mold to create bimetallic layered castings. The experimental procedure focuses on optimizing the melt-to-solid phase ratios and pouring temperatures to achieve a uniform microstructure and strong mechanical properties in the bimetals. The produced bimetallic castings are suitable for applications in the oil refining and chemical industries and heavy machinery sector. The quantitative results indicate that the optimized process parameters lead to a high-quality transition zone with minimal defects, characterized by the diffusion of alloying elements from the nickel alloy to the steel. The microstructure, chemical, and phase compositions were evaluated using XRD and SEM with EDS, confirming the formation of a robust metallurgical bond. Key findings include a significant improvement in the hardness and strength of the transition layer, with the optimal pouring temperature being 1600 °C. The resulting bimetallic materials demonstrate an improved performance in demanding industrial environments. [ABSTRACT FROM AUTHOR]

Triethylamine is a common volatile organic compound (VOC) that plays an important role in areas such as organic solvents, chemical industries, dyestuffs, and leather treatments. However, exposure to triethylamine atmosphere can pose a serious threat to human health. In this study, gas-sensing semiconductor materials of LaFeO3 nano materials with different Mo-doping ratios were synthesized by the sol–gel method. The crystal structures, micro morphologies, and surface states of the prepared samples were characterized by XRD, SEM, and XPS, respectively. The gas-sensing tests showed that the Mo doping enhanced the gas-sensing performance of LaFeO3. Especially, the 4% Mo-doped LaFeO3 exhibited the highest response towards triethylamine (TEA) gas, a value approximately 11 times greater than that of pure LaFeO3. Meantime, the 4% Mo-doped LaFeO3 sensor showed a remarkably robust linear correlation between the response and the concentration (R2 = 0.99736). In addition, the selectivity, stability, response/recovery time, and moisture-proof properties were evaluated. Finally, the gas-sensing mechanism is discussed. This study provides an idea for exploring a new type of efficient and low-cost metal-doped LaFeO3 sensor to monitor the concentration of triethylamine gas for the purpose of safeguarding human health and safety. [ABSTRACT FROM AUTHOR]

There is a high interest in utilizing natural bioactive products derived from plants as a substitute for synthetic chemicals in the industry. This research focuses on the phytochemical composition of essential oils (EOs) of Ammi visnaga L. and Trachyspermum ammi L and their insecticidal activity against Sitophilus oryzae (L.), a common pest found in stored cereals. The EOs were extracted through steam distillation and analyzed using gas chromatography coupled with mass spectrometry (GC-MS). The EOs of A. visnaga consisted of twenty-four components, with Abietadiene (41.23%) being the most abundant, followed by linalool (25.54%) and limonene (19.04%). On the other hand, the EOs of T. ammi consisted of twenty-eight main components, with isothymol being the most abundant (51.88%). The results revealed that the EOs of T. Ammi (DL50 = 0.1 µL EOs/L of air) were more toxic than A. visnaga (0.38 µL EOs/L of air), with the toxicity varying based on doses and exposure periods. To further understand the molecular mechanisms underlying this activity, molecular docking and dynamic simulations were performed using the major chemical constituents of the oils. The simulation results indicated that the major compounds, Abietadiene and isothymol, interact with the catalytic sites of the target proteins, inhibiting acetylcholinesterase and chitin synthase. These interactions form energetically favorable systems that remain stable throughout the molecular dynamic period. This research provides valuable insights into the potential of these EOs as natural insecticides and highlights the importance of molecular modeling in understanding the biological activities of plant-derived compounds. [ABSTRACT FROM AUTHOR]

Tri-n-butyl phosphate (TBP) is essential in the chemical industry for dissolving and purifying various inorganic acids and metals, especially in hydrometallurgical processes. Recent advancements suggest that machine learning can significantly improve the prediction of TBP mixture viscosities, saving time and resources while minimizing exposure to toxic solvents. This study evaluates the effectiveness of five machine learning algorithms for automating TBP mixture viscosity prediction. Using 511 measurements collected across different compositions and temperatures, the neural network (NN) model proved to be the most accurate, achieving a Mean Squared Error (MSE) of 0.157% and an adjusted R2 (a measure of how well the model predicts the variability of the outcome) of 99.72%. The NN model was particularly effective in predicting the viscosity of TBP + ethylbenzene mixtures, with a minimal deviation margin of 0.049%. These results highlight the transformative potential of machine learning to enhance the efficiency and precision of hydrometallurgical processes involving TBP mixtures, while also reducing operational risks. [ABSTRACT FROM AUTHOR]

α-Pinene is the bicyclic, unsaturated terpene hydrocarbon present in many plants. Due to its beneficial chemical properties, this compound is of great interest and has found numerous applications as a raw material in many chemical industries as well as in medicine and cosmetics. The aim of this study was to evaluate the antioxidant activities of ethanolic extracts obtained from plants containing α-pinene and to test the properties of cosmetic emulsions prepared with these extracts. The raw plant materials consisted of fresh parts of Pinus sylvestris L., such as cones, needles, and branches, as well as dried unground and ground pinecones; dried and fresh Rosmarinus officinalis leaves; dried Levisticum officinale leaves; and dried Salvia officinalis L. leaves. The plant materials were individually extracted with 40% (v/v), 70% (v/v), and 96% (v/v) ethanol using ultrasound-assisted extraction (UAE) for 15, 30, or 60 min. This method is a green extraction technique, frequently applied to isolate active substances from plants. For the selected plant materials, Soxhlet extraction with 96% (v/v) ethanol was also performed. The qualitative and quantitative analyses of the components in the selected extracts were performed with gas chromatography coupled with mass spectrometry (GC-MS). The antioxidant activities of the extracts were evaluated with the DPPH and ABTS methods. The extracts of three plant materials with the highest antioxidant activities—dried Rosmarinus officinalis leaves, dried Salvia officinalis L. leaves, and dried and ground Pinus sylvestris L. cones—were selected to be incorporated in cosmetic emulsions containing glyceryl monostearate and Olivem 1000 as emulsifiers. The stabilities and antioxidant activities of the emulsions were evaluated. Moreover, the antimicrobial properties of the emulsions using microbiological tests were also determined. The findings suggest that the prepared emulsions are stable cosmetic products with a high antioxidant potential. [ABSTRACT FROM AUTHOR]

Offshore wind power stands out as a promising renewable energy source, offering substantial potential for achieving low carbon emissions and enhancing energy security. Despite its potential, the expansion of offshore wind power faces considerable constraints in offshore power transmission. Hydrogen production derived from offshore wind power emerges as an efficient solution to overcome these limitations and effectively transport energy. This study systematically devises diverse hydrogen energy supply chains tailored to the demands of the transportation and chemical industries, meticulously assessing the levelized cost of hydrogen (LCOH). Our findings reveal that the most cost-efficient means of transporting hydrogen to the mainland is through pipelines, particularly when the baseline distance is 50 km and the baseline electricity price is 0.05 USD/kWh. Notably, delivering hydrogen directly to the port via pipelines for chemical industries proves considerably more economical than distributing it to hydrogen refueling stations, with a minimal cost of 3.6 USD/kg. Additionally, we assessed the levelized cost of hydrogen (LCOH) for supply chains that transmit electricity to ports via submarine cables before hydrogen production and subsequent distribution to chemical plants. In comparison to offshore hydrogen production routes, these routes exhibit higher costs and reduced competitiveness. Finally, a sensitivity analysis was undertaken to scrutinize the impact of delivery distance and electricity prices on LCOH. The outcomes underscore the acute sensitivity of LCOH to power prices, highlighting the potential for substantial reductions in hydrogen prices through concerted efforts to lower electricity costs. [ABSTRACT FROM AUTHOR]

Hydroformylation of olefins is widely used in the chemical industry due to its versatility and the ability to produce valuable aldehydes with 100% atom economy. Herein, a hybrid phosphate promoter was found to efficiently promote rhodium-catalyzed hydroformylation of styrenes under remarkably mild conditions with high regioselectivities. Preliminary mechanistic studies revealed that the weak coordination between the Rhodium and the P=O double bond of this pentavalent phosphate likely induced exceptional reactivity and high ratios of branched aldehydes to linear products. [ABSTRACT FROM AUTHOR]

In the face of geopolitical challenges and climate change, economic progress, safe production, and environmental protection have emerged as important directions for chemical industry development. However, the rational optimization of the chemical industry layout under the backdrop of ecological environmental protection necessitates further exploration. This study explores the evolution and future development direction of the chemical industry layout within the coastal region of Jiangsu Province, China, using the CA–Markov model. The findings reveal a trend of spatial agglomeration growth among coastal chemical enterprises, with Moran's Index increasing from 0.109 in 2007 to 0.206 in 2017. The petrochemical industry, in particular, demonstrated the most significant agglomeration effect, with approximately 52.10% being concentrated in 14 coastal industrial parks in 2017. Under the constraints of the ecological environment and policy guidance, the land area allocated for the chemical industry experienced a reduction of over 10%, further strengthening the emphasis on spatial agglomeration. Chemical industries along Jiangsu's coast have become agglomerated and concentrated near industrial parks and ports. Their spatial distribution and connectivity were mainly influenced by factors such as convenient transportation, the ecological environment, local policies, the distance from residential areas, and industrial agglomeration. Under different scenarios—including natural growth, ecological environment constraints, and policy guidance—chemical industries show diverse spatial patterns. Ecological environmental constraints and policy guidance can provide various intervention methods for the government to promote the optimization direction and focus of the chemical industry layout while minimizing its impact on the ecological environment. [ABSTRACT FROM AUTHOR]

Tritium permeation constitutes a key issue for the future EU-DEMO, especially in the Breeding Blanket (BB) where fusion energy must be delivered to the Primary Heat Transport System (PHTS) and where tritium must be bred. Currently, the mitigation strategy of the tritium permeation from BB into primary coolant is based on the adoption of anti-permeation barriers and on the operation of the Coolant Purification System (CPS). This system must ensure a tritium removal rate from the primary coolant equal to the BB permeation rate at a target tritium-specific activity inside the PHTS. In the case of the Water-Cooled Lithium Lead (WCLL) BB, water distillation was selected as the most promising technology for the primary coolant detritiation due to its intrinsic simplicity and safety. Nevertheless, power consumption was recognized as a relevant concern. For this reason, the present work aims at investigating possibilities to reduce power consumption of the water CPS implementing Heat Pump-Assisted Distillation (HPAD) concepts. To do this, a review of the HPADs developed in the chemical industry was carried out, and the best options for the water CPS were identified based on qualitative considerations. Then, a quantitatively assessment of the best solution in terms of power consumption and tritium inventory was performed with the commercial numerical tool Aspen Plus. Finally, the Mechanical Vapor Recompression (MVR) concept was recognized as the most promising solution, ensuring a power saving of around 80% while keeping a limited tritium inventory. [ABSTRACT FROM AUTHOR]

High-frequency traveling-wave magnetic fields refer to alternating magnetic fields that propagate through space in a wave-like manner at high frequencies. These magnetic fields are characterized by their ability to generate driving forces and induce currents in conductive materials, such as liquids or metals. This article investigates the application and approaches of a unique form of high-frequency traveling-wave magnetic fields to low-conductivity liquids with conductivity ranging from 1 to 102 S/m. Experiments were conducted using four representative electrolytic solutions commonly employed in the chemical industry: sulfuric acid (H2SO4), sodium hydroxide (NaOH), sodium chloride (NaCl), and ionic liquid ([Bmim]BF4). The investigation focuses on the impact of high-frequency magnetic fields on these solutions at the optimal operating point of the system, considering the effects of Joule heating. The findings reveal that the high-frequency traveling magnetic field exerts a significant volumetric force on all four low-conductivity liquids. This technology, characterized by its non-contact and pollution-free nature, high efficiency, large driving volume, and rapid driving speeds (up to several centimeters per second), also provides uniform velocity distribution and notable thermal effects. It holds considerable promise for applications in the chemical industry, metallurgy, and other sectors where enhanced three-phase transfer processes are essential. [ABSTRACT FROM AUTHOR]

This summary provides an overview of a special issue of the journal Fermentation, which focuses on bioprocesses and biorefineries. The articles in this issue cover a range of topics, including the use of different biomass sources in biorefineries and the production of various products such as bioethanol, lactic acid, and bioplastics. The issue also discusses the importance of efficient operations, biocatalysts, and empirical kinetic models for industrial-scale implementation. The authors emphasize the need to consider operational costs in the development of lignocellulose-based biorefineries. Overall, this special issue offers valuable insights into the field of bioprocessing and its potential applications. [Extracted from the article]