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This research explores the adsorption (AD) of diclofenac sodium (DS) onto a Hydrothermally produced activated carbon impregnated with ZnO (HTC-AC/ZnO) surface, considering various factors such as initial concentration (IC), adsorbent dose, contact time, and pH. The characterization of HTC-AC/ZnO was performed using X-ray diffractometer (XRD), scanning electron microscope (SEM), Fourier-transform infrared spectroscopy (FTIR), and nitrogen physisorption spectroscopy (BET). Tests were conducted with different adsorbent doses (0.5–4 g/L) at 303 K and various initial diclofenac concentrations (ranging from 50 mg/L to 250 mg/L) to observe their effects. Additionally, pH values were altered from 2 to 12 to study their influence on AD. Kinetic studies, thermodynamic studies, and AD isotherm models were examined. The Temkin isotherm model (TIM) was found to be the most accurate for DS-AD on HTC-AC/ZnO. For DS-AD on HTC-AC/ZnO, pseudo-first-order models (PFOM), intraparticle diffusion model (IPDM), and pseudo-second-order models (PSOM) were applied, with a correlation coefficient of 0.945, indicating a good fit for PFOM. The kinetics suggested rapid adsorption. Notably, the HTC-AC/ZnO composite exhibited consistent AD characteristics across four consecutive cycles, with a removal efficiency exceeding 99.38%. This suggests that HTC-AC/ZnO is an appropriate and economically viable adsorbent for the elimination of DS from water-based solutions. The investigation provides compelling evidence that HTC-AC/ZnO is a viable adsorbent for the effective elimination of DS from water sources. [ABSTRACT FROM AUTHOR]

In this research, the main aim is to focus the enhancement of aluminium-based metal matrix composites for improving the attributes of light weight metals, aerospace structures and other tailor blank material properties. By this way, the friction stir processing (FSP) was the suited alternate technique to enhancing the mechanical attributes and superior microstructural amendment in the processed MMCs. Therefore, this study investigates the dispersion of ceramic-based strengthening particles of chromium oxide (Cr2O3) in the aluminium base matrix of A356 alloy. During the processing, the different tool pin sizes having the conical threaded tool pin profiles. Similarly, the tool spinning speed and tool travel speed also varied while in FSP. Before the processing, the A356 alloy was prepared by the grooved surfaces for packing the chromium oxide particles to compose the aluminium metal matrix composites. The tensile strength and hardness was employed to carry out from the friction stir processed A356 alloy with influencing of Cr2O3. The maximum occurred tensile processing parameters are 1500 rpm of spinning speed, 6 mm of tool pin sizes and 90 mm/min of tool travel speed. Similarly, the maximum obtained hardness processing parameter are 2000 rpm of spinning speed, 5 mm of tool pin sizes and 90 mm/min of tool travel speed. A scanning electron microscope was utilized to investigate the dispersed Cr2O3 in the A356 alloy for confirming the refinement grains in the nugget zones of FSPed A356 alloy. The increased grain boundary by the influence of different tool pin sizes was the major reason to produces the better mechanical properties in the processed A356/Cr2O3. [ABSTRACT FROM AUTHOR]

Magnetite nanoparticles (Fe3O4) were prepared by chemical coprecipitation method using ferric chloride (FeCl3) and heptahydrate ferrous sulfate (FeSO4·7H2O) salts employing sodium hydroxide (NaOH) as a precipitant. To determine the size, shape, and chemical makeup of the produced magnetite nanoparticles, the generated powders were examined by transmission electron microscope, scanning electron microscope, atomic force microscope, and X-ray diffractometer. It was found that the magnetite powder had made a face-centered cubic crystal structure and spherical-like particle form with particle diameters of about 30 nm. The magnetic properties of magnetite nanoparticles were evaluated using a vibrating sample magnetometer. The obtained superparamagnetic properties of the produced nanoparticles, with saturation magnetization and coercivity of 50.75 emu/g and 30.09 Oe, respectively, allow them for applications in drug delivery, MRI contrast agent, catalysis, degradation of antibiotics, antibacterial activity, removal of heavy metals and organic dyes, etc. [ABSTRACT FROM AUTHOR]