1. Effects of TiO2 on fiber spinnability, structure, and mechanical properties of glasses derived from simulated lunar soils.
- Author
-
Ding, Mengzhao, Li, Yunpeng, Han, Huimin, Song, Letong, Luo, Lida, Li, Hong, and Wang, Qingwei
- Subjects
- *
LUNAR soil , *TITANIUM dioxide , *FIBERS , *FIBROUS composites , *GLASS structure , *GLASS fibers , *SILICATE minerals , *METALLIC glasses , *CONSTRUCTION materials - Abstract
The construction of lunar stations for research and habitation requires high-performance building materials that can adapt to the harsh lunar environment. One of the feasible building materials is fiber-reinforced composites, for which the composition of glass fibers can be designed like lunar soils, i.e., terrestrial basalt, and in turn the "lunar glass" can be drawn into fibers. Because of a wide variation of TiO 2 in lunar soils, our study focused on a series investigation on the effect of TiO 2 (0.55 wt%-6.14 wt%) on fiber spinnability and strength of the simulated "lunar glass and glass fibers". The baseline glass composition was derived from a simulated TiO 2 -lean lunar soil and other glasses were made at different TiO 2 doping levels. The addition of TiO 2 was found to reduce the thermal stability of the melt, there appears a TiO 2 threshold (6.14 wt%), at which fibers cannot be drawn without breakage because of melt devitrification. The fiber tensile strength exhibits a nonlinear characteristic with an apparent maximum at 1.52 wt% TiO 2. FTIR and Raman spectroscopic studies were carried out to investigate the glass network structure responses to TiO 2 modifications and show TiO 2 functions as a network modifier, depolymerizing the silicate network. Statistical structure (FTIR & Raman based)–property modeling was attempted to further elucidate the effect of TiO 2 -induced structure change on T g and fiber tensile strength. Good agreements were found between the model predictions and the measured values. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF