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Efforts to enhance greenhouse gas (GHG) emission reduction in East Asia play a pivotal role on both global and regional scales in advancing climate mitigation strategies. This study aimed to better constrain anthropogenic CO 2 emission estimates by expanding the network of near-surface in-situ stations for CO 2 observations across South Korea. To achieve an optimal CO 2 network design, we conducted an Observing System Simulation Experiment (OSSE) coupled with the Stochastic Lagrangian Transport model (STILT), utilizing meteorological data from the Korean Integrated Model (KIM). Our inversion setup incorporated two CO 2 emission datasets with a 0.1o resolution: EDGAR v6 for prior emissions and GRACED for truth emissions. A uniform model-mismatch error of 3 ppm was introduced across sites. The effectiveness of the existing five in-situ stations, termed the base network, in South Korea was evaluated to gauge their ability to constrain CO 2 surface flux estimates. However, the findings revealed a reduction in flux uncertainty of only 29.2%, which fell short of the desired uncertainty reduction goal. In this base network, the Lotte World Tower (LWT: 37.5126°E, 127.1025°E) in Seoul and the Anmyeondo (AMY: 36.538576° N, 126.330071° E) site in Taean county stood as major contributors, with estimated reductions of 17.48% and 6.35%, respectively. Consequently, we proposed and developed an extended network, identifying seven candidate sites based on consideration of logistical factors, existing infrastructures, and proximity to the emission source regions. An incremental optimization scheme ranked their contributions, resulting in an additional 25% reduction, bringing the total to 54.13%. However, it is noteworthy that diminishing returns (ranging from 13% to less than 0.1%) were observed with an increase in station count mainly due to the possibility that adding a station earlier in the sequence might render subsequent stations redundant. Despite this, the proposed CO 2 network successfully reduced uncertainty in emissions, narrowing the gap with the objectives of the Global Greenhouse Gas Watch (G3W). • Designing CO 2 near-surface observation network over South Korea. • New stations selected considering logistic factors, existing infrastructures, and proximity to emission sources. • The base network was able to reduce 29.18% of the uncertainty in CO 2 emissions. • Extending network, by adding new seven candidate sites, led to a total uncertainty reduction of 54.13%. [ABSTRACT FROM AUTHOR]

The Chinese government has announced ambitious carbon reduction goals to address climate change, however, there has been limited scientific attention to the achievement of deep decarbonization in regions with insufficient economic development. Moreover, the complex impacts of climate change mitigation on energy system, environment and economic development remain unclear in Northwest China. Here we construct a comprehensive evaluation model system to evaluate the effects of different climate mitigation pathways in Qinghai, Ningxia, Gansu and Xinjiang provinces. Results show that the four provinces need to vigorously increase the share of electricity that consumed in final energy to 53.1–60.0% and 52.9–62.0% for 2 °C and 1.5 °C target, respectively, and reduce total energy demand to 11.6–44.4 Mtoe and 8.2–34.1 Mtoe in 2050. Meanwhile, the CO 2 emissions for their energy systems will reach peak by 2025 at lower values. Moreover, the synergies of CO 2 reduction are most conducive to abating SO 2 pollution and also contributing to decreasing PM 2.5 concentrations. Additionally, the GDP losses in 2050 fluctuate from 5.0 to 21.7 billion USD in the 2 °C scenario to 11.5–52.7 billion USD in the 1.5 °C scenario. Our study provides practical guidance on achieving carbon reductions in less developed regions of China and lays foundations to promote decarbonization of energy systems in other provinces. • Realizing climate goals requires low-carbon energy systems led by electricity. • Energy-related carbon emissions in Northwest China will peak by 2025. • More ambitious climate and clean air policies are needed for air quality improvement. • Economic loss shows an upward trend in the future under climate targets. [ABSTRACT FROM AUTHOR]